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The Study of Inhibitive Corrosion Mechanism of Ce-ion and La-ion for Carbon Steel In NaCl Solution |
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钢铁研究总院 |
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Abstract The effect of Ce-ion and La-ion inhibiting the corrosion of steel in NaCl solution has been investigated by salt water droplet test, corrosion production micro-analysis and electrochemistry test. The potential-pH diagram of RE-H2O was also used to investigate the chemical stability of various kinds of RE compound. The results showed that oxide and hydrate of RE deposited in the cathodal area where the pH value was relatively high and inhibited the corrosion of steel by blocking the transmission of O2 and electron between the cathodal area and solution. The potential-pH diagram and thermodynamics calculation showed the compound of Ce was more stable than compound of la in theacid solution and suggested that the ability of inhibition corrosion of Ce-ion is better than that of la-ion.
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Received: 27 October 2005
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[1]Hinton B R W,Arnott D R,Ryan N E.The inhibition of aluminumalloy corrosion by cerium cations[J].Meter.Forum,1984,7(4):211-217 [2]Hinton B R W.Ceriumconversion coating for the corrosion protectionof aluminum[J].Mater.Forum,1986,9(3):162-173 [3]Arnott D R.Cationic film forming inhibitors for the corrosion protec-tion of AA7075 aluminum alloy in chloride solutions[J].Mater.Per-formance,1987,26(8):42-47 [4]Arnott D R.Cationic film forming inhibitors for the protection ofAA7075 aluminum alloy against corrosion in aqueous chloride solu-tions[J].Corrosion,1989,45(1):12-19 [5]Goldie B P F,McCarroll J J.Inhibiting metal corrosion in aqueoussystems[P].Australian Patent,AU-32947/84,1984 [6]Liu B S.Cerium conversion coating on Al and its alloys[J].Mater.Prot.,1992,25(5):16-19(刘伯生.铝及铝合金上铈转化膜的研究[J].材料保护,1992,25(5):16-19) [7]Li J Q,Lu C Y,Gao LS,et al.Corrosion resistant film of cerium richcoating on aluminium alloys[J].J.Univ.Sci..Technol.Beijing,1995,17(6):584-589(李久青,卢翠英,高陆生等.铝合金表面稀土铈耐蚀膜[J].北京科技大学学报,1995,17(6):584-589) [8]Yu X W,Zhou D R,Yin Z D,et al.Rare earth metal conversion coat-ing on aluminum[J].Chin.J.Nonferr.Metals.,1999,9(1):73-78(于兴文,周德瑞,尹钟大等.铝合金表面三价稀土钝化膜的研究[J].中国有色金属学报,1999,9(1):73-78) [9]Fang J L,Wang J K,Liu Q,et al.XPS and AES studies of a rareearths conversion coating on carbon steel[J].J.Chin.Soc.RareEarths,2001,12(1):38-41(方景礼,王济奎,刘琴等.碳钢表面稀土转化膜的XPS和AES研究[J].中国稀土学报,2001,12(1):38-41) [10]Li G Q,Li D,Li J Q,et al.Cerium conversion coatings formed onanodized aluminum by cathodic electrolysis[J].J.Chin.Soc.Cor-ros.Prot.,2001,21(3):150-156(李国强,李荻,李久青等.铝合金阳极氧化膜上阴极电解沉积的稀土铈转化膜[J].中国腐蚀与防护学报,2001,21(3):150-156) [11]Gu B S,Liu J H,Ji X C.Corrosion inhibition mechanism of cerium(Ⅲ)for aluminum alloy[J].J.Chin.Soc.Corros.Prot.,2006,26(1):53-58(顾宝珊,刘建华,纪小春.铈盐对铝合金的缓蚀机理研究[J].中国腐蚀与防护学报,2006,26(1):53-58) [12]Rajendran N,Nishimura T.Monitoring of pHand chloride ion with-in the rust of low alloy steels under atmospheric corrosion environ-ment[A].CSM,ISIJ,KIMM.Second International Conference onAdvanced Structural Steels[C].Shanghai:2004,425-428 [13]Liang Y J,Che Y C.Thermodynamics Data Handbook of Mineral[M].Shenyang:Northeastern University Press,1994(梁英教,车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1994) [14]Wu WC,Fong HQ,Wu KZ.Standard Data Handbook of ElectrodePotential[M].Beijing:Science Press,1991(吴维昌,冯洪清,吴开治.标准电极电位数据手册[M].北京:科学出版社,1991) [15]Yin Y J.Concise Handbook of Physical Chemistry[M].Beijing:Higher Education Press,1988(印永嘉.物理化学简明手册[M].北京:高等教育出版社,1988) [16]Yang D J,Shen Z S.Corrosion of Metal[M].Beijing:MetallurgicalIndustry Press,1999(杨德钧,沈卓身.金属腐蚀学[M].北京:冶金工业出版社,1999) |
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