Effect of Nitrogen Doping on Corrosion Inhibition Performance of Carbon Nanoparticles

doi:10.11902/1005.4537.2021.001

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (1): 85-92 DOI: 10.11902/1005.4537.2021.001

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Effect of Nitrogen Doping on Corrosion Inhibition Performance of Carbon Nanoparticles

WANG Jing, WANG Siyan, ZHANG Chong, WANG Wentao, CAO Xing, FAN Ning, XU Hongyan(

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School of Materials Science and Engineering, North University of China, Taiyuan 030051, China

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Abstract

Nitrogen-free carbon nanoparticles (CNPs) were prepared by thermal decomposition method with citric acid as carbon source. While nitrogen-doped carbon nanoparticles (N-CNPs) were prepared by thermal decomposition method with citric acid as carbon source and urea as nitrogen source. The above nano-particles were characterized by means of atomic force microscope, infrared spectroscope and Raman spectroscope, and their corrosion inhibition performance for Q235 steel in 1 mol/L HCl solution was comparatively studied by mass loss method, electrochemical means and laser confocal scanning microscope. The results showed that the two carbon nanoparticles belonged to mixed-type corrosion inhibitors, the corrosion inhibition efficiency of N-free carbon nanoparticles was 37.5%, and the corrosion inhibition efficiency of the carbon nanoparticles was significantly improved after being doped with N. The corrosion inhibition efficiency of N-CNPs reached 90.96%.

Key words: carbon nanoparticle corrosion inhibitor electrochemical Q235 steel

Received: 04 January 2021

ZTFLH:

TG174.42

Fund: Natural Science Foundation of Shanxi Province(201901D111175)

Corresponding Authors: XU Hongyan E-mail: xuhongyan@nuc.edu.cn

About author: XU Hongyan, E-mail: xuhongyan@nuc.edu.cn

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	Jing WANG
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	Wentao WANG
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	Hongyan XU

Cite this article:

WANG Jing, WANG Siyan, ZHANG Chong, WANG Wentao, CAO Xing, FAN Ning, XU Hongyan. Effect of Nitrogen Doping on Corrosion Inhibition Performance of Carbon Nanoparticles. Journal of Chinese Society for Corrosion and protection, 2022, 42(1): 85-92.

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https://www.jcscp.org/EN/10.11902/1005.4537.2021.001 OR https://www.jcscp.org/EN/Y2022/V42/I1/85

Fig.1 AFM 2D images (a, c) and height curves (b, d) of CNPs (a, b) and N-CNPs (c, d)

Fig.2 FT-IR spectra of CNPs and N-CNPs

Fig.3 Raman spectrum of N-CNPs

Fig.4 Corrosion rates (a) and corrosion inhibition efficiencies (b) of Q235 steel in 1 mol/L HCl solutions containing 0, 10, 25 and 50 mg/L CNPs, and N-CNPs

Table 1 Comparison of the inhibition efficiencies of N-CNPs and other reported corrosion inhibitors for Q235 steel in 1 mol/L HCl solution

Fig.5 Potential polarization curves (a) and corresponding Evans polarization plots (b) for Q235 steel in 1 mol/L HCl solutions without and with 50 mg/L CNPs or 50 mg/L N-CNPs

Table 2 Fitting parameters of polarization curves of Q235 steel in 1 mol/L HCl solutions without and with 50 mg/L CNPs or 50 mg/L N-CNPs

Fig.6 Nyquist plots (a) and equivalent circuit diagrams (b, c) for Q235 steel in 1 mol/L HCl solutions without (b) and with (c) 50 mg/L CNPs or 50 mg/L N-CNPs

Fig.7 LSCM images of Q235 steel before (a) and after immersion for 24 h in 1 mol/L HCl solutions without (b) and with 50 mg/L CNPs (c) and 50 mg/L N-CNP (d) ((a) R_a=0.047 μm, (b), R_a=1.328 μm, (c) R_a=0.930 μm, (d) R_a=0.335 μm)

Concentration / mg·L^-1	L₁ / H	R_s / Ω·cm²	Q_dl / F·cm^-2	n₁	R_ct / Ω·cm²	L₂ / H	R_L / Ω·cm²	χ²	Inhibition efficiency
1 mol/L HCl	7.934 $×$ 10^-7	1.861	8.095 $×$ 10^-4	0.914	85.2	---	---	2.87 $×$ 10^-4	---
50 mg/L CNPs	6.652 $×$ 10^-7	1.731	2.341 $×$ 10^-4	0.902	202.8	139.3	15.95	4.09 $×$ 10^-4	56.5%
50 mg/L N-CNPs	6.409 $×$ 10^-7	1.700	8.974 $×$ 10^-5	0.888	660.3	300.2	30.3	6.43 $×$ 10^-4	87.10%

Table 3 Fitting parameters of EIS of Q235 steel in 1 mol/L HCl solutions without and with 50 mg/L CNPs or N-CNPs

Fig.8 Langmuir adsorption isotherms of Q235 steel in 1 mol/L HCl solutions containing CNPs (a) and N-CNPs (b)

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