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Journal of Chinese Society for Corrosion and protection  2021, Vol. 41 Issue (6): 748-756    DOI: 10.11902/1005.4537.2020.167
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Research Progress of Biocides for Microbiologically Influenced Corrosion
HE Yongjun1, ZHANG Tiansui2, WANG Haitao3, ZHANG Fei2, LI Guangfang2, LIU Hongfang2()
1.SINOPEC Sales Co. Ltd. , (South China), Guangzhou 510000, China
2.Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, Hubei Key Laboratory of Material Chemistry and Service Failure, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
3.China Special Equipment Inspection and Research Institute (CSEI), Beijing 100029, China
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Abstract  

Based on the research and application of biocides in recently years, the research progress of quaternary ammonium salts biocides, guanidine biocides, heterocyclic biocides and compounds biocides used in the prevention and control of microbiologically influenced corrosion (MIC) in oil and gas fields is reviewed. The MIC induced by fungus and algae as well as the research progress of corresponding biocides are introduced. On this basis, this article summarizes the application, challenges and future development trends of biocides, providing references for the research of microbial corrosion protection and rational use of biocides.

Key words:  biocides      microbiologically influenced corrosion      bacteria      fungus      alga     
Received:  23 September 2020     
ZTFLH:  S482.2  
Fund: National Key Research and Development Program(2017YFC0805000);Project of SINOPEC(319008-8)
Corresponding Authors:  LIU Hongfang     E-mail:  liuhf@hust.edu.cn
About author:  LIU Hongfang, E-mail: liuhf@hust.edu.cn

Cite this article: 

HE Yongjun, ZHANG Tiansui, WANG Haitao, ZHANG Fei, LI Guangfang, LIU Hongfang. Research Progress of Biocides for Microbiologically Influenced Corrosion. Journal of Chinese Society for Corrosion and protection, 2021, 41(6): 748-756.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2020.167     OR     https://www.jcscp.org/EN/Y2021/V41/I6/748

Fig.1  Schematic presentation for synthesis of quaternary ammonium polyethyleneimine nanoparticles[38,39] (a), surface modified silica nanoparticles[40] (b) and macromonomers synthesized by a sol-gel chemical route (c)[43]
Fig.2  Synthesis of polyhexamethylene guanidine molybdate[47]
Heterocyclic type of bactericidesCommorly used bactericidesUses and advantages
Ternary and quaternary heterocyclic compounds

Ethylene, Eopxiconazole,

Temocillin, Penicillin

Ternary heterocyclic compounds are often the key intermediates for the preparation of heterocyclic biocides. Temocillin and penicillin are beta amide heterocyclic fungicides with high fungicidal activity
Five-membered heterocyclic compounds

Thiazoles

Thiabendazole,

Etridiazole

Ethaboxam

Thiazole biocides possess a wide range of applications. In addition to inhibiting microbial corrosion, it can also be used to control harmful microorganisms in farmland

Furan

Fuberidazole, Fenfuram

Furalaxyl

Furan biocides have a wide range of biological activities, which can be used for sterilization, insecticidal and so on

Azole

Pyrrolnitrin, Fenpiclonil

Fludioxonil

Pyrrole biocides are derived from natural product nitropyrrolidins, among which imidazole methyl pyrrole compounds have the most prominent fungicidal activity

Oxazoles

Ibotenic acid, Hymexazol

Famoxadone, Glyodin

Imazalil, Oxpoconazole

Oxazoles biocides have good broad spectrum, bactericidal and permeability
Pyrazoles

Pyrazophos, Furametpyr

Pyraclostrobin

Pyrazole fungicide is a new type of heterocyclic biocides, which evolved from pyraclon

Triazoles[51]

Luotrimazole, Imazalil Bayleton[52]

Diniconazole, Triadimenol

Triazole biocides have excellent bactericidal properties and broad spectrum, and are the most widely used fungicides[51]
Six-member hetero-cyclic compoundsPyrimidines

Ferimzone, Mepanipyrim

Cyprodinil, Pyrimethanil

Pyrimidines are widely distributed and can be derived from a variety of natural extracts
PyridinesFiuazinam, Sodium pyrithione, FluopicofideThe research and application of six membered cyclic pyridine fungicides are few, they are potential fungicides
BenzimidazolesBenomyl, CarbendazimBenzimidazole biocides have the advantages of broad spectrum and low toxicity
Table 1  Some conventional heterocyclic bactericides
Fig.3  Equilibrium adsorption configurations simulated for SPT on Fe(110) surface in aqueous solution: side view (a), top view (b)[53]
Fig.4  Surface images of biofilm-covered coupons under light microscope at 200X after 5 d incubation for 0 mg/L (a), 3 mg/L (b), 10 mg/L (c) and 30 mg/L (d) BKC concentrations[68]
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