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Journal of Chinese Society for Corrosion and protection  2012, Vol. 32 Issue (5): 397-402    DOI:
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EFFECT OF UREA ON MICROBIAL CORROSION BEHAVIOR OF Q235 STEEL IN SOIL
LI Ximing1, ZHANG Chunyan2, ZHU Hui3, SUN Cheng1, XU Jin1, XIAN Jun3, WANG Wenbin3, YU Changkun1
1. State Key Laboratory for Corrosion and Protection, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016
2. Kalamayi Zhixin Co. Ltd, Kalamayi 834002
3. Oil-gas Storage and Transportation Company of Xinjiang Oilfield, Kalamayi 834002
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Abstract  

The effect of urea (0.05 mass %) on the microbial corrosion of Q235 steel in soil with humidity at 10 % was investigated by electrochemical impendence spectroscopy(EIS), polarization curve, scanning electron microscopy (SEM) and EDX. The results showed that urea accelerated carbon steel corrosion in soil with SRB yet prevented the corrosion of steel in sterile soil. The results of EIS showed that in inoculated soil only one time constant appeared in primary experimental period, two time constants appeared after 5 d and corrosion product formed on the steel surface. Warburg impedance was found at the later stage, which indicated that the process was controlled by concentration polarization. Sulfur element was detected in corrosion product of carbon steel in soil with SRB by EDX, which confirmed the effects of SRB on the corrosion.

Key words:  Q235 steel      urea      EIS      SRB     
Received:  26 September 2011     
ZTFLH:  TG172.4  
Fund: 

National Natural Science Foundation of China;National Natural Science Foundation of China;National RD Infrastructure and Facility Development Program of China

Corresponding Authors:  SUN Cheng     E-mail:  chengsun@imr.ac.cn

Cite this article: 

LI Ximing, ZHANG Chunyan, ZHU Hui, SUN Cheng, XU Jin, XIAN Jun, WANG Wenbin, YU Changkun. EFFECT OF UREA ON MICROBIAL CORROSION BEHAVIOR OF Q235 STEEL IN SOIL. Journal of Chinese Society for Corrosion and protection, 2012, 32(5): 397-402.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2012/V32/I5/397

[1] Booth G H, Cooper A W,Cooper P M. Criteria of soil aggressiveness towards buried metal II.Assessment of various soils [J]. Br. Corros. J., 1967, 2: 109-113

[2] Li C B. Surveying techniques for underground pipelines and soil corrosivity evaluation method[J]. Soils, 1998, 12(4): 205-208

    (李成保.地下管线腐蚀的勘测技术与土壤腐蚀性的评价方法[J]. 土壤, 1998, 12(4):205-208)

[3] Wang W H, Shen S M, Yu X C. Review on research methods of soil corrosion for buried pipeline steels [J]. J. Nanjing Univ.Technol. (Nat. Sci. Ed.), 2008, 30(4): 105-110

    (王文和, 沈士明, 於孝春. 埋地管道钢土壤腐蚀研究方法进展 [J].南京工业大学学报(自然科学版), 2008, 30(4): 105-110)

[4] Wang G Y. Corrosion and Protection in Nature Environment [M]. Beijing: Chemical Industry Press, 1997

    (王光雍.自然环境的腐蚀与防护[M]. 北京: 化学工业出版社, 1997)

[5] Wang Q. Corrosion and protection of underground pipelines [M]. Xining: The People$^{\prime}$s Press of Qinghai, 1984

    (王强. 地下金属管道的腐蚀与阴极保护[M]. 西宁: 青海人民出版社, 1984)

[6] Sun C, Xu J, Wang F H. Effect of sulfate reducing bacteria on corrosion of stainless steel 1Cr18Ni9Ti in soils containing chloride ions [J]. Mater. Chem. Phys., 2011, 126: 330-336

[7] Zhang L J. The Selected Information of the National Soil Corrosion Test Networks and Stations (2nd)[M]. Shanghai: Shanghai Jiao Tong University Press, 1992

    (张良杰,全国土壤腐蚀试验网站资料选编(第二集) [M]. 上海: 上海交通大学出版社,1992)

[8] Sun C, Han E H. Effects of SRB on corrosion of Q235 steel during vaporation of water in soil [J]. J. Chin. Soc. Corros. Prot.,2005, 25(5): 307-311

    (孙成, 韩恩厚.土壤湿度变化对Q235钢的硫酸盐还原菌腐蚀影响[J]. 中国腐蚀与防护学报,2005, 25(5): 307-311)

[9] Liu W X, Sun C. Effects of different cathodic ions on the corrosion of carbon steel in soils [J]. Total Corros. Contr. 2006,20(6): 10-13

    (刘文霞, 孙成. 土壤中阴离子对碳钢腐蚀的影响[J].全面腐蚀控制,2006, 20(6): 10-13)

[10] Liu H F, Wang M F, Xu L M, et al. The role of Ca2+ on the microbiologically induced corrosion of carbon steel [J]. J.Chin. Soc. Corros. Prot., 2004, 24(1): 45-51

     (刘宏芳, 汪梅芳, 许立铭等. 钙离子对碳钢微生物腐蚀的影响[J]. 中国腐蚀与防护学报, 2004,24(1): 45-51)

[11] Ju X T, Zhang F S. Nitrate accumulation and its implication to environment in north China [J]. Ecology Environ.,2003, 12(1): 24-28

     (巨晓棠, 张福锁.中国北方土壤硝态氮的累积及其对环境的影响[J]. 生态环境, 2003, 12(1):24-28)

[12] Mozheiko F F, Potkina T N, Goncharik I. Effect of inhibitors on corrosion resistance of carbon steel in suspensed liquid combined fertilizer [J]. Rus. J. Appl. Chem., 2008, 81(9):1705-1709

[13] Li Y, Zhang T, Wang F H. Corrosion behavior of AZ91D magnesium alloy in hand sweat II. Inhibiting mechanism of urea on magnesium alloy AZ91D in hand sweat [J]. J. Chin. Soc. Corros.Prot., 2004, 24(6): 334-339

     (李瑛, 张涛, 王福会.AZ91D镁合金手汗腐蚀机理研究II. 手汗液中尿素对AZ91D腐蚀的缓蚀机制[J].中国腐蚀与防护学报, 2004, 24(6): 334-339)

[14] Li M C, Lin H C, Cao C N. Study of soil corrosion of carbon steel by electrochemical impendence spectroscopy (EIS) [J].J. Chin. Soc. Corros. Prot., 2000, 20(2): 111-117

     (李谋成,林海潮, 曹楚南. 碳钢在土壤中腐蚀的电化学阻抗谱特征[J].中国腐蚀与防护学报, 2000, 20(2): 111-117)

[15] Wang W. Surface analysis methods used in microbiologically induced corrosion study [J]. J. Chin. Soc. Corros.Prot., 2007, 27(1): 60-64

     (王伟.微生物腐蚀研究方法中的表面分析技术[J]. 中国腐蚀与防护学报, 2007,27(1): 60-64)

[16] Liu J, Fan H B, Xu H P, et al. Corrosion electrochemical behavior of carbon steel in microbiological medium [J].Electrochemistry, 2002, 8(2): 186-190

     (刘靖, 范洪波,徐海平等. 碳钢在微生物腐蚀介质中的腐蚀电化学行为[J], 电化学, 2002,8(2): 186-190)

[17] Cao C N. Principles of Corrosion Electrochemistry[M].Beijing: Chemical Industry Press, 2008

     (曹楚南.腐蚀电化学原理[M]. 北京: 化学工业出版社, 2008)

[18] Castaneda H, Benetton X D. SRB-biofilm influence in active corrosion sites formed at the steel-electrolyte interface when exposed to artificial seawater conditions[J]. Corros. Sci.,2008, 50: 1169-1183

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