|
|
STUDY OF THE SULFUR-CONTAINING AMINO'S STRUCTURE AND CORROSION INHIBITION MECHANISM IN H2SO4 |
GONG Min, ZHANG Yu, ZHENG Xingwen, FENG Min, ZHANG Guohu, YANG Lin |
Material and Chemical Engineering Department, Sichuan University of Science & Engineering, Zigong 643000 |
|
|
Abstract Electrochemical testing, and quantum chemistry calculations were used to study the corrosion inhibition mechanism of L-methionine, L-cystine, L-cysteine in 1 mol/L sulfuric acid system. The results of linear polarization, Tafel extrapolation and EIS showed that inhibition efficiency of L-methionine and cysteine increased with the increase of the concentration among 0.0001 mol/L~0.1 mol/L. And these three amino acids adsorption in carbon steel is provided by the amino acids to provide electronic, air-rail track, two coordination bonds to bonding.
|
Received: 19 July 2010
|
|
Corresponding Authors:
ZHANG Yu
E-mail: zygrxx@163.com
|
[1] Zheng X W. Study on Sulfuric Acid Pickling Inhibitor Extracted from Bamboo Leaves [D]. Zigong: Sichuan University of Science and Engineering, 2009. 5 (郑兴文. 从竹叶中提取硫酸酸洗缓蚀剂的研究 [D]. 自贡:四川理工学院,2009: 5)[2] Gong M, Yu Z X, Chen L. Theory of Metal Corrosion and Corrosion Control [M]. Beijing: Chemical Industry Press, 2009: 1 (龚敏, 余祖孝, 陈琳. 金属腐蚀理论及腐蚀控制 [M]. 北京:化学工业出版社, 2009: 1)[3] Cao C N, Zhang J Q. Introduction to Electrochemical Impedance Spectra [M]. Beijing: Science Press, 2002: 1-2 (曹楚南, 张鉴清. 电化学阻抗谱导论 [M]. 北京: 科学出版社, 2002: 1-2)[4] Zhang D Q, Gao L X, Zhou G D. Molecular design and synergistic effect of morpholinium type volatile corrosion inhibitor [J]. J. Chin. Soc. Corros. Prot.,2006, 26(2): 120-124 (张大全,高立新,周国定. 吗啉衍生物气相缓蚀剂的分子设计和缓蚀协同作用研究 [J]. 中国腐蚀与防护学报, 2006, 26(2): 120-124)[5] Zhang S G. A quantum chemistry study for sweet compounds: aspartame and its analogues [J]. J. Binzhou Teachers College, 2003, 19(2): 32-35 (张士国. 甜味化合物天冬氨酰苯丙氧酰甲酯及其类似物的量子化学研究 [J]. 滨州师专学报, 2003, 19(2): 32-35)[6] Zhang S G,Yang P. The molecular structure and corrosion inhibitor efficiency of some cyclic nitrogen compounds: An DFT study [J]. J. Chin.Soc. Corros. Prot 2004, 24(4): 240-244 (张士国,杨频. 用量子化学密度泛函理论研究环状含氮化合物分子结构与缓蚀性能的关系 [J]. 中国腐蚀与防护学报, 2004, 24(4): 240-244)[7] Zhao W, Xia M Z, Lei W, et al. Quantum chemistry studies of organophosphorus corrosion inhibitors [J]. J. Chin. Soc. Corros. Prot., 2002, 22(4): 217-220 (赵维, 夏明珠, 雷武等. 有机磷缓蚀剂分子结构与缓蚀性能的量子化学研究 [J]. 中国腐蚀与防护学报, 2002, 22(4): 217-220)[8] Xia M Z,Zhao W,Lei W,et al. Quantum chemistry studies of organophosphorus corrosion inhibitors [J]. Corros. Sci. Prot. Technol.,2002, 14(6): 311-314 (夏明珠,赵维,雷武等. 含P有机缓蚀剂缓蚀性能的量子化学研究 [J]. 腐蚀科学与防护技术,2002, 14(6): 311-314)[9] Gomez B, Likhanova N V, Dominguez-Aguilar M A, et al. Quantum chemical study of the inhibitive properties of -pyridyl-azoles [J]. Phys. Chem. B, 2006, 110: 8928-8934[10] Zhu Y C, Wang L, Xu Y, et al. Study on electrochemical corrosion of copper by IR spectroelectrochemistry and quantum chemistry methods [J]. Corros. Sci. Prot. Technol.,2009, 21(3): 233-235 (朱永春,王琳,徐雁等. 铜的电化学腐蚀过程的红外光谱电化学及量子化学方法研究 [J]. 腐蚀科学与防护技术,2009, 21(3): 233-235) |
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|