UNDERFILM CORROSION OF METALS AND FAILUREOF ORGANIC COATINGS IN ATMOSPHERE

J Chin Soc Corr Pro

2002, Vol. 22

Issue (4): 249-256 DOI:

Review

Current Issue | Archive | Adv Search

UNDERFILM CORROSION OF METALS AND FAILUREOF ORGANIC COATINGS IN ATMOSPHERE

Yongxiang Xv;Chuanwei Yan

北京航空材料研究所

Download:

PDF(286KB)
Export: BibTeX | EndNote (RIS)

Abstract Underfilm corrosion of metals and failure of or gani c coatings in atmosphere are of great interesting and practical meaning.Weatheri ng and underfilm corrosion are the two most important factors which cause failur e of organic coatings.The mechanism of weathering is generally considered to be radical reaction initiated by photon while the mechanism of underfilm corrosion, to be electrochemical reaction.The factors affecting the corrosion and failure i nclude property of the coating,air pollutant,contamination of soluble salts on m etal substrate,surface condition and treating of substrate,and so on.The researc hing approaches are mainly electrochemical methods including DC and AC methods,a nd spectroscopy.Of the electrochemical methods,the electrochemical impedance spe ctroscopy (EIS) is the most important and widely used,and the Kelvin scanning pr obe is a new and promising method.Spectroscopy includes infrared spectroscopy an d Raman spectroscopy.Nowadays it is common to use these methods coordinately and to carry out in situ on-line measurements.The present paper reviews the above a spects.

Key words: coating atmosphere corrosion

Received: 01 November 2000

ZTFLH:

TG174.4

Corresponding Authors: Yongxiang Xv

	Service

	E-mail this article
	Add to citation manager
	E-mail Alert
	RSS
	（）
	Articles by authors
	Yongxiang Xv
	Chuanwei Yan

Cite this article:

Yongxiang Xv; Chuanwei Yan. UNDERFILM CORROSION OF METALS AND FAILUREOF ORGANIC COATINGS IN ATMOSPHERE. J Chin Soc Corr Pro, 2002, 22(4): 249-256 .

URL:

https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2002/V22/I4/249

[1]NguyenTN ,HubbardJB ,McFaddenGB .Amathematicalmodelforthecathodicblisteringoforganiccoatingsonsteelimmersedinelectrolytes[J].J.Coat.Tech.,1991,63(794):43-52.
[2]WangGY .CorrosionandProtectionofEntironment[M ].Beijing:ChemicalIndustryPress,1997.(王光雍等.自然环境的腐蚀与防护[M ].北京:化学工业出版社,1997.)
[3]HoffmannK ,StratmannM .Thedelaminationoforganiccoatingsfromrustysteelsubstrates[J].Corros.Sci.,1993,34(10):1625-1645.
[4]KoehlerEL .Theinfluenceofcontaminantsonthefailureofprotec tiveorganiccoatingsonsteel[J].Corrosion,1977,33(6):209-217.
[5]ArmstrongRD ,JohnsonBW .Aninvestigationintothecathodicdelaminationofunpigmentedchlorinatedrubberfilms[J].Corros.Sci.,1991,32(3):303-312.
[6]ArmstrongRD ,JohnsonBW ,WrightJD .Aninvestigationintothecathodicdelaminationofepoxy-polyamineprotectivecoatings[J].ElectrochemicaActa,1991,36(13):1915-1923.
[7]LeidheiserHJr,WangW ,IgetoftL .Themechanismfortheca thodicdelaminationoforganiccoatingsfromametalsurface[J].Prog.Org.Coatings,1983,11:19-40.
[8]ArmstrongRD ,JenkinsATA ,JohnsonBW .AninvestigationintotheUVbreakdownofthermosetpolyestercoatingsusingimpedancespectroscopy[J].Corros.Sci.,1995,37(10):1615-1625.
[9]HalliwellSM .Rap.Rev.Rev.5,Report53[C],1992.
[10]RabekJF .MechanismsofPhotophysicalProgressesandPhoto chemicalReactionsinPolymers[M ].JohnWilerandSons,1987.
[11]MckellarJF ,AllenNS .PhotochemistryofManMadePolymers[M].AppliedSciencePublishersLtd.,1979.
[12]PappasSP .Weatheringofcoatingsformulationandevaluation[J].Prog.Org.Coatings,1989,17:107-114.
[13]OosterbroekM ,LarmmersRJ ,VanderVenLGJ ,PereraDY .Crackformationandstressdevelopmentinanorganiccoating[J].J .Coat.Tech.1991,63(799):55-60.
[14]RitterJJ,KrugerJ.CorrosionControlbyOrganicCoatings[M ].EditedbyLeidheiserJrH .Houston:Texas,Natl.Assocn.Corro sionEngrs.,1981.
[15]PourbaixM .AtlasofElectrochemicalEquilibriainAqueousSolu tions[M ].London:PergamonPress,1966.
[16]KoehlerEL .Themechanismofcathodicdisbondmentofprotectiveorganiccoatings-aqueousdisplacementatelevatedpH[J].Corro sion,1984,40(1):5-8.
[17]NemethZ ,ErdeiL ,KolicsA .Anewapproachtostudyingiontransportincorrosionprotectivecoatingsusinganinsituradio tracermethod[J].Corros.Sci.,1995,37(7):1163-1166
[18]LambrevVG ,RodinNN ,KoftyukVA .Applicationofthemethodofneutronactivationforstudyingcorrosionprocessesandprotectiveabilityofpaintcoatings[J].Prog.Org.Coat.,1997,30:1-8.
[19]KairaitisAJ.Moistureabsorptioncapacityofpaintfilmsanindica tionoftheircorrosionprotectivecapability[J].CorrosionAustrala sia,1989,14(2):13.
[20]LaiCX .Mechanismofdelaminationofprotectivefilminitiatedbywaterandpreventionmeasure[J].Corros.Sci.Prote.Technol.,1992,4(2):127-134.(赖春晓.水引起保护涂膜剥离的机理及防止方法[J].腐蚀科学与防护技术,1992,4(2):127-134)
[21]DavisGD ,ShawBA ,ArahCO ,etal.EffectofSO2 depositiononpaintedsteelsurfaces[J].SurfaceandInterfaceAnalysis,1990,15:107-112.
[22]SimendingerWH ,BalikCM .Solubility,diffusivity,andchemicalreactivityofsulfurdioxidewithanalkydpaint[J].J .Coat.Tech nol.,1992,64(812):37-43.
[23]HochGM .LocalizedCorrosion[A].Staehleetal.ed.NACE[C],1974.
[24]VanLooM ,LaidermanDD ,BruhnRR .Filiformcorrosion[J].Corrosion,1953,9:277-283
[25]MorcilloM ,Solublesalts:theireffectsonprematuredegradationofanticorrosivepaints[J].Prog.Org.Coat.1999,36:137-147.
[26]MorcilloM .ProceedingsoftheEUROCOAT’98,UATCM/AETEPA ,Barcelona.Spain,1998,Vol.II:617-637.
[27]RuizJL ,HernandezLS ,MorcilloM .Proceedingsofthefirstcon gresonacionaldettratamientosdesuprficies[A].AIMME[C],Va lencia,1992.23.
[28]MorcilloM ,SimancasJ ,FierroJLG ,etal.Accelerateddegrada tionofachlorinatedrubberpaintsystemappliedoverrustedsteel[J].Prog.Org.Coatings,1993,21:315.
[29]MorcilloM ,RodriguezFJ ,BastidasJM .Theinfluenceofchlo rides,sulphatesandnitratesatthecoating-steelinterfaceonun derfilmcorrosion[J].Prog.Org.Coatings,1997,31:245-353.
[30]BastidasJM ,MorcilloM ,RodriguezFJ .Mildsteelcorrosioninsalinesolutions.comparisonbetweenbulksolutionsandsteel-coatinginterfacialsolutions[J].J .Coat.Technol.1998,70(882):61-66.
[31]MorcilloM .Atmosphericcorrosioninibero-America:TheMI CATproject[A].ASTM -STP1293[C].Philadelphia:ASTM ,1995:257-275.
[32]MorcilloM ,SimancasJ.Proceedingsofthe97PEC’,TheHague,March,1997,12.
[33]YanCW ,GaoTZ ,ShiZM ,LinHC ,CaoCN .Laboratoryofef fectofNaClonatmosphericcorrosionofzincinaircontainingSO2[J].ActaMetallurgicaSinica,2000,36(3):272-274.(严川伟,高天柱,史志明,林海潮,曹楚南.NaCl对含SO2环境中Zn大气腐蚀的影响[J].金属学报,2000,36(3):272-274)
[34]TannerAR .Iron(II)sulphateinrust[J].Chem.Ind.,1964,6:1027-1028.
[35]SchwartzH .Untersuchungentuberdiewirkungdeseisen(II)-sulfatesbeimatmospharischenrostenundbeimunterrostenvonanstrichen[J].WerkstoffeundKorrosion,1965,16:93-103.
[36]HintonBR ,CharltonP .Theinfluenceofsubstratesurfacefinishandcontaminationonthecathodicdelaminationofanepoxy-polyamidecoatingfromsteel[J].CorrosionAustralasia,1989,14(2):18-21.
[37]FisherTW ,IezziRA ,MarditchJM .Societyofautomotiveengi neersAnn.Meeting,1980:800149.
[38]IezziRA ,LeidheiserH .Surfacecharacteristicsofcold-rolledsteelastheyaffectpaintperformance[J].CorrosionNACE ,1981,37:28-38.
[39]LeroyV .Metallurgicalapplicationsofsurfaceanalyticaltechniques[J].MaterialSci.&Eng.,1980,42:289-307.
[40]WakanoS ,UsukiT ,NishihalaM ,FujinoH .Effectofsurfaceseg regationduringannealingandsurfaceoxidefilmson phosphatecoatingofcoldrolledsteelsheet[J].Tetsu-to-Hagane,1980,66:945-952.
[41]BrunoM .Perfetti.Substratefactorsaffectingtheperformanceoforganiccoatingsonsteelsheetsurface[J].J .Coat.Technol.,1991,63(795):43-50.
[42]ZhangJQ ,CaoCN .Studyandevaluationonorganiccoatingsbyelectrochemicalimpedancespectroscopy[J].CorrosionandProtec tion,1998,19(3):99-104.(张鉴清,曹楚南.电化学阻抗谱方法研究评价有机涂层[J].腐蚀与防护,1998,19(3):99-104)
[43]ZhangJQ ,CaoCN .AnalyticalsystemofEISdata[J].Corros.Sci.Prote.Technol.,1990,2(3):9-15.(张鉴清,曹楚南.交流阻抗数据分析系统[J].腐蚀科学与防护技术,1990,2(3):9-15)
[44]ZhangJQ ,CaoCN .EISdataanalysisforevaluationofprotectivepropertyoforganiccoatings[J].Corros.Sci.Prote.Technol.,1994,6(4):318-324.(张鉴清,曹楚南.评价有机涂层防护性能的EIS数据处理[J].腐蚀科学与防护技术,1994,6(4):318-324)
[45]SimpsonTC ,MoranPJ ,MoshierWC ,DavidGD ,ArahCD ,ZankleKI .Anelectrochemicalmonitorforthedetectionofcoatingdegradationinatmosphere[J].J .Electrochem.Soc.,1989,136:2761-2762.
[46]AmirudinA ,ThierryD .Electrochemicalsensorformonitoringat mosphericcorrosionofpolymercoatedmetal[J].Br.Corros.J.,1995,30(3):214-220.
[47]DeWittJHW .Proc.12thInt.CorrosionCong.[C].Houston:TX .,USA ,September1993:420.
[48]FrecheteE ,CompereC ,GhaleE .Evaluationofthecorrosionrisis tanceofpaintedsteelbyimpedancemeasurements[J].Corros.Sci.,1992,33:1067-1081.
[49]StratmannM ,StreckleH ,FeserR .Anewtechniqueabletomea suredirectlythedelaminationoforganicpolymer[J].Corros.Sci.,1991,32(4):467-470
[50]ZhouF ,HanW ,LongK ,HanWA .DeterminationofKelvinpo tentialbylinearregression[J].Corros.Sci.Prote.Technol.,1995,7(1):17-22.(邹峰,韩薇,龙康,韩文安.线性回归法进行Kelvin电位测试[J].腐蚀科学与防护技术,1995,7(1):17-22)
[51]StratmannM ,LengA ,FurbethW ,etal.ThescanningKelvinprobe;anewtechniquefortheinsituanalysisofthedelaminationoforganiccoatings[J].Prog.Org.Coat.,1996,27:216-267.
[52]MesserschmidtRG ,HarthcockMA ,Eds.InfraredMicrospec troscopyTheoryandPractice[M ].NewYork:MarcelDecker,Inc.,NY ,1988.
[53]KrishnanK .Proc.SPIE -Int.Soc.Opt.Eng.1986,665:252.
[54]HarthockMA ,LentzLA ,DavisBL ,KrishnanK .ApplicationsoftransmittanceandreflectanceMicro/FT -IRtopolymericmateri als[J].Appl.Spectrosc.,1986,40(2):210-214.
[55]DanielJSkrovanek.Fouriertransforminfraredspectroscopicstud iesofcoatingsdefects[J].J .Coat.Technol.,1989,61(769):31-37.
[56]LuTH .SurfaceenhancedRamanspectroscopyanditsapplicationinchemistry[J].Corros.Sci.Prote.Technol.,1995,7(2):102-107.(陆天虹.表面增强拉曼光谱及其在化学中的应用[J].腐蚀科学与防护技术,1995,7(2):102-107)
[57]YanCW ,YuJK ,LinHC ,CaoCN ,SongGL .ApplicationoflaserRamanspectroscopytotheresearchofmetalcorrosion[J].Corros.Sci.Protec.Technol.,1998,10(3):164-170.(严川伟,余家康,林海潮,曹楚南,宋光玲.激光拉曼光谱在金属腐蚀研究中的应用[J].腐蚀科学与防护技术,1998,10(3):164-170)
[58]BernardMC ,Hugot-LeGoffA ,PhillipsN .Insitustudyofthecorrosionofzinc-coatedsteelinthepresenceofchloride[J].J .Electrochem.Soc.,1995,142(7):2162-2167.
[59]BernardMC ,Hugot-LeGoffA ,PhillipsN .Insitustudyofthecorrosionofzinc-coatedsteelinthepresenceofchloride[J].J .Electrochem.Soc.,1995,142(7):2167-2173.
[60]LiY ,CaoCN ,LinHC .ApplicationofSTMtocorrosion-elec trochemicalresearch[J].Corros.Sci.Prote.Technol.,1998,10(5):284-289.(李瑛,曹楚南,林海潮.扫描隧道显微镜在腐蚀电化学研究中的应用[J].腐蚀科学与防护技术,1998,10(5):284-298)
[61]WuLS .Applicationofelectronicmicroscopetothecorrosionfield[J].CorrosionandProtection,1982,4:47-50.(吴连生.电子显微镜在腐蚀领域中的应用[J].腐蚀与防护,1982,4:47-50)
[62]ChangRQ .AbriefintroductionofM ssbauereffect[J].CorrosionandProtection,1983,6:40-43.(常汝勤.穆斯鲍尔效应简介[J].腐蚀与防护,1983,6;40-43)

[1]	HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[2]	REN Yan, QIAN Yuhai, ZHANG Xintao, XU Jingjun, ZUO Jun, LI Meishuan. Effect of Thermal Shock on Mechanical Properties of Siliconized Graphite with ZrB₂-SiC-La₂O₃/SiC Coating[J]. 中国腐蚀与防护学报, 2021, 41(1): 29-35.
[3]	SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[4]	LIU Yang, WU Jinyi, YAN Xiaoyu, CHAI Ke. *Effect of Bacillus flexus* on Degradation of Polyurethane Varnish Coating in Marine Environment**[J]. 中国腐蚀与防护学报, 2021, 41(1): 36-42.
[5]	YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[6]	LI Congwei, DU Shuangming, ZENG Zhilin, LIU Eryong, WANG Feihu, MA Fuliang. Effect of Current Density on Microstructure, Wear and Corrosion Resistance of Electrodeposited Ni-Co-B Coating[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[7]	SUN Shuo, YANG Jie, QIAN Xinzhu, CHANG Renli. Preparation and Electrochemical Corrosion Behavior of Electroless Plated Ni-Cr-P Alloy Coating[J]. 中国腐蚀与防护学报, 2020, 40(3): 273-280.
[8]	CAO Jingyi, WANG Zhiqiao, LI Liang, MENG Fandi, LIU Li, WANG Fuhui. Failure Mechanism of Organic Coating with Modified Graphene Under Simulated Deep-sea Alternating Hydrostatic Pressure[J]. 中国腐蚀与防护学报, 2020, 40(2): 139-145.
[9]	SHI Chao,SHAO Yawei,XIONG Yi,LIU Guangming,YU Yuelong,YANG Zhiguang,XU Chuanqin. Influence of Silane Coupling Agent Modified Zinc Phosphate on Anticorrosion Property of Epoxy Coating[J]. 中国腐蚀与防护学报, 2020, 40(1): 38-44.
[10]	YANG Yinchu,FU Xiuqing,LIU Lin,MA Wenke,SHEN Moqi. Electrochemical Corrosion of Ni-P-BN(h)-Al₂O₃ Composite Coating Deposited by Spray Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(1): 57-62.
[11]	ZHAO Shuyan,TONG Xinhong,LIU Fuchun,WENG Jinyu,HAN En-Hou,LI Xiaohui,YANG Lin. Corrosion Resistance of Three Zinc-rich Epoxy Coatings[J]. 中国腐蚀与防护学报, 2019, 39(6): 563-570.
[12]	WANG Guirong,ZHENG Hongpeng,CAI Huayang,SHAO Yawei,WANG Yanqiu,MENG Guozhe,LIU Bin. Failure Process of Epoxy Coating Subjected Test of Alternating Immersion in Artificial Seawater and Dry in Air[J]. 中国腐蚀与防护学报, 2019, 39(6): 571-580.
[13]	YU Chuntang,YANG Yingfei,BAO Zebin,ZHU Shenglong. Research Progress in Preparation and Development of Excellent Bond Coats for Advanced Thermal Barrier Coatings[J]. 中国腐蚀与防护学报, 2019, 39(5): 395-403.
[14]	LI Fengjie,CHEN Minghui,ZHANG Zheming,WANG Shuo,WANG Fuhui. Preparation and Thermal Shock Behavior of a Metal-enamel High-temperature Protective Coating[J]. 中国腐蚀与防护学报, 2019, 39(5): 411-416.
[15]	WANG Qinying,PEI Rui,XI Yuchen. Erosion-corrosion Behavior of Laser-clad Ni-based Alloy Coating on Q235 Carbon Steel[J]. 中国腐蚀与防护学报, 2019, 39(5): 458-462.

No Suggested Reading articles found!

Viewed

Full text

Abstract

Cited

Shared

Discussed