Effect of Hydrogen on Crevice Corrosion Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution

doi:10.11902/1005.4537.2024.069

Journal of Chinese Society for Corrosion and protection

2025, Vol. 45

Issue (2): 431-437 DOI: 10.11902/1005.4537.2024.069

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Effect of Hydrogen on Crevice Corrosion Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution

TANG Yixin¹, ZHANG Fei², CUI Zhongyu¹, CUI Hongzhi¹, LI Yizhou¹(

)

^1.Institute of Materials Science and Engineering, Ocean University of China, Qingdao 266100, China
^2.China Nuclear Power Operation Technology Corporation, Wuhan 430074, China

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TANG Yixin, ZHANG Fei, CUI Zhongyu, CUI Hongzhi, LI Yizhou. Effect of Hydrogen on Crevice Corrosion Behavior of 2205 Duplex Stainless Steel in 3.5%NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2025, 45(2): 431-437.

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Abstract

The effect of cathodically hydrogen charging on the crevice corrosion behavior of 2205 duplex stainless steel in 3.5%NaCl solution was investigated by means of measurements of potentiodynamic polarization, Mott-Schottky, and potentiostatic polarization, as well as scanning electron microscopy (SEM) and confocal laser microscopy (CLSM). The results show that the defect density of the passive film on the surface of 2205 duplex stainless steel increases, and the pitting potential decreases significantly with the increased hydrogen charging time. This results in the decrease of the critical crevice corrosion potential and the increased crevice corrosion susceptibility. The pitting corrosion and the striped corrosion inside the crevice is observed for the specimen without hydrogen charging. However, for the specimen with hydrogen charging, the grooved corrosion at the crevice mouth is observed at the high polarized potential, and the pitting corrosion inside crevice founded at the low polarized potential.

Key words: 2205 duplex stainless steel cathodic polarization potentiostatic polarization crevice corrosion

Received: 05 March 2024 32134.14.1005.4537.2024.069

TG174

Fund: National Natural Science Foundation of China(51901217)

Corresponding Authors: LI Yizhou, E-mail: liyizhou@ouc.edu.cn

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	TANG Yixin
	ZHANG Fei
	CUI Zhongyu
	CUI Hongzhi
	LI Yizhou

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.069 OR https://www.jcscp.org/EN/Y2025/V45/I2/431

Fig.1 Metallurgical microstructure of 2205 duplex stain-less steel

Fig.2 Schematic diagram of crevice corrosion test device (a), and cross-sectional view (b) and fixation (c) of specimen

Fig.3 Potentiodynamic polarization curves of 2205 duplex stainless steel in 3.5%NaCl solution after hydrogen charging for different time (a), and their corresponding pitting breakdown potentials (E_bp) and passivation current densities (I_p) (b)

Fig.4 Mott-Schottky plots of the passive films formed on 2205 duplex stainless steel in 3.5%NaCl solution after hydrogen charging for different time: (a) Mott-Schottky plots, (b) carrier density

Fig.5 Potentiostatic polarization curves of 2205 duplex stainless steel after hydrogen charging in 3.5%NaCl solution under different polarization potentials for 0 h (a), 2 h (b) and 6 h (c), and corresponding critical potentials of crevice corrosion (d)

Fig.6 Surface morphologies (a, d, g) and corrosion zone profiles (b, c, e, f, h, i) of uncharged 2205 duplex stainless steel after polarization in 3.5%NaCl solution at the constant potentials of 450 mV (a-c), 500 mV (d-f), 1000 mV (g-i)

Fig.7 Surface morphologies (a, d, g) and corrosion zone profiles (b, c, e, f, h, i) of 2205 duplex stainless steel with 2 h hydrogen charging after polarization in 3.5%NaCl solution for 4 h at the potentials of -300 mV (a-c), -150 mV (d-f), 0 V (g-i)

Fig.8 Surface morphologies (a, d, g) and corrosion zone profiles (b, e, h) of 2205 duplex stainless steel with 6 h hydrogen charging after polarization in 3.5%NaCl solution for 4 h at the potentials of 0 V (a-c), -300 mV (d-f), -450 mV (g-i)

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