Inhibition Action of Machilus yunnanensis Leaves Extract on Corrosion of Al-plate in HCl Medium

doi:10.11902/1005.4537.2023.234

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (3): 601-611 DOI: 10.11902/1005.4537.2023.234

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Inhibition Action of Machilus yunnanensis Leaves Extract on Corrosion of Al-plate in HCl Medium

WEI Gaofei, DENG Shuduan, SHAO Dandan, XU Juan, LI Xianghong(

)

Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

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WEI Gaofei, DENG Shuduan, SHAO Dandan, XU Juan, LI Xianghong. Inhibition Action of Machilus yunnanensis Leaves Extract on Corrosion of Al-plate in HCl Medium. Journal of Chinese Society for Corrosion and protection, 2024, 44(3): 601-611.

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Abstract

The inhibition action of Machilus yunnanensis leaves extract (MYLE) on Al-plate in 1.0 mol·L^-1 HCl solution were studied by means of mass loss method, electrochemical tests, inductively coupled plasma optical emission spectrometer (ICP-OES), metallographic microscope, scanning electron microscope (SEM) and contact angle measurements. The results show that the maximum inhibition efficiency of 1000 mg·L^-1 MYLE at 20^oC can reach as high as 93.5%. The inhibition efficiency increases with the increase of MYLE concentration, while the higher the temperature, the weaker the inhibition performance. The adsorption of MYLE on Al surface is mainly based on chemisorption, which conforms to Langmuir isotherm at lower temperatures and Freundlich isotherm at higher temperatures. The corrosion kinetic reaction of Al in HCl solutions without or with MYLE is in accordance with Arrhenius formula and transition state theory equation. In the presence of MYLE, the relevant apparent activation energy (E_a), pre-exponential factor (A), apparent activation enthalpy (ΔH_a) and apparent activation entropy (ΔS_a) are all increased. MYLE is a mixed inhibitor through “geometric blocking effect”. Nyquist diagram is mainly composed of a capacitive reactance arc in high frequency region and an inductive reactance arc in low frequency region. With the increase of MYLE concentration, both the charge transfer resistance and inductance resistance increase. After the addition of MYLE, the concentration of Al³⁺ in HCl solutions is significantly dropped, and SEM morphology further confirms that MYLE can efficiently slow down the corrosion degree of Al-plate.

Key words: Machilus yunnanensis leaves HCl inhibition adsorption Al

Received: 27 July 2023 32134.14.1005.4537.2023.234

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52161016);Fundamental Research Project for Postgraduates in Yunnan Provincial Department of Education(2022Y566);Research Project for Distinguished Young Scholars in Yunnan Province(202001AV07-0008);Joint Key Project of Agricultural Fundamental Research in Yunnan Province(202101BD070001-017);Special Project of "Top Young Talents" of Yunnan Ten Thousand Talents Plan(51900109)

Corresponding Authors: LI Xianghong, E-mail: xianghong-li@163.com

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.234 OR https://www.jcscp.org/EN/Y2024/V44/I3/601

Fig.1 Extraction flow diagram of MYLE

Fig.2 Surface morphologies of Al samples before (a) and after immersion in 1.0 mol·L^-1 HCl (b) and 1.0 mol·L^-1 HCl + 1000 mg·L^-1 MYLE (c)

Fig.3 Variations of corrosion rate (a) and inhibition efficiency (b) with MYLE concentration for Al in 1.0 mol·L^-1 HCl

Fig.4 Adsorption isotherms of MYLE on Al surface in HCl solution at different temperatures: (a) Langmuir, (b) Freundlich

Table 1 Linear regression parameters and adsorption equi librium constant

Fig.5 Fitted straight line of lnK versus 1/T in 1.0 mol·L^-1 HCl

Fig.6 Fitted straight lines: (a) lnv-1/T, (b) ln(v/T)-1/T

Fig.7 Variation curves of corrosion kinetic parameters with MYLE concentration in 1.0 mol·L^-1 HCl

Fig.8 PDP curves for Al in 1.0 mol·L^-1 HCl solutions without and with different concentrations of MYLE at 20^oC

Table 3 PDP parameters of Al in 1.0 mol·L^-1 HCl solutions containing different concentrations of MYLE at 20^oC

Fig.9 Nyquist plots (a), R(QR(LR)) fitting circuit diagrams (b), Bode phase angles (c) and Bode moduli (d) of Al in 1.0 mol·L^-1 HCl solutions containing different concentrations of MYLE at 20^oC

Table 4 EIS parameters of Al in 1.0 mol·L^-1 HCl solutions containing different concentrations of MYLE at 20^oC

Fig.10 SEM surface morphologies (a-c) and contact angles (d) of Al before (a) and after immersion for 2 h in the solutions of 1.0 mol·L^-1 HCl (b) and 1.0 mol·L^-1 HCl + 1000 mg·L^-1 MYLE (c)

Fig.11 Variations of Al³⁺ concentration and corrosion inhibition with MYLE concentration

Fig.12 Schematic diagrams of corrosion mechanism (a) and inhibition mechanism (b)

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