A Novel Technique of Electrochemical-inductively Coupled Plasma Atomic Emission Spectrometry and Its Application in Corrosion Research

doi:10.11902/1005.4537.2022.265

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (4): 847-854 DOI: 10.11902/1005.4537.2022.265

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A Novel Technique of Electrochemical-inductively Coupled Plasma Atomic Emission Spectrometry and Its Application in Corrosion Research

YU Yingjie, LI Ying(

)

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

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Abstract

To improve breadth and depth of corrosion theory for metal materials, a combined technique of electrochemical-inductively coupled plasma atomic emission spectrometry (ICP-OES) was developed in recent years. In this technique, an inductively coupled plasma atomic emission spectrometer was coupled to the downstream of a home-built electrochemical flow cell to track the concentration transient of the corrosion products dissolved in the corrosion medium, so that the elemental dissolution rates of metal electrode could be determined in real time. The working principles and the development of this technology were introduced briefly and the applications of this technology in metal corrosion research were summarized at present. Finally, the existing problems and future directions for development of this technique were pointed out.

Key words: elemental analysis electrochemical ICP-OES metal corrosion

Received: 29 August 2022 32134.14.1005.4537.2022.265

ZTFLH:

TG172

Fund: National Natural Science Foundation of China(51871227);National Natural Science Foundation of China(51671198)

Corresponding Authors: LI Ying, E-mail: liying@imr.ac.cn

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YU Yingjie, LI Ying. A Novel Technique of Electrochemical-inductively Coupled Plasma Atomic Emission Spectrometry and Its Application in Corrosion Research. Journal of Chinese Society for Corrosion and protection, 2023, 43(4): 847-854.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.265 OR https://www.jcscp.org/EN/Y2023/V43/I4/847

Fig.1 Schematic diagram of the electrochemical ICP-OES: (a) reaction system, (b) ICP-OES, (c) fast electronics^[22]

Fig.2 Schematic diagram (a) and 3D image (b) of the electrochemical flow cell designed by Ogle and Weber^[22]

Fig.3 Schematic diagram of the electrochemical flow cell used for in-situ scratch experiment^[25]

Fig.4 Schematic figure of the new electrochemical flow cell^[26]

Fig.5 Electrochemical ICP-OES dissolution profile of tri-cation phosphate conversion coating in 0.1 mol/L NaOH solution^[38]

Fig.6 Elemental dissolution profiles for AA6061 alloy in 3% NaCl during applied cathodic potential (-1.5 V vs. SCE) followed by pre-activation of the surface by -1.8 V^[30]

Fig.7 ICP-OES signal of pure Mg registered together with current signal and the different potential steps signal^[31]

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