电化学-电感耦合等离子体原子发射光谱联用技术及其在金属腐蚀研究中的应用

doi:10.11902/1005.4537.2022.265

中国腐蚀与防护学报

2023, Vol. 43

Issue (4): 847-854 CSTR: 32134.14.1005.4537.2022.265 DOI: 10.11902/1005.4537.2022.265

曹楚南科教基金优秀论文专栏

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电化学-电感耦合等离子体原子发射光谱联用技术及其在金属腐蚀研究中的应用

于英杰, 李瑛(

)

中国科学院金属研究所沈阳 110016

A Novel Technique of Electrochemical-inductively Coupled Plasma Atomic Emission Spectrometry and Its Application in Corrosion Research

YU Yingjie, LI Ying(

)

Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China

全文: PDF(2315 KB) HTML

摘要:

为了提高金属材料腐蚀理论研究的广度和深度，近年来，一种电化学-电感耦合等离子体原子发射光谱联用技术应运而生。在该技术中，电感耦合等离子体原子发射光谱仪被耦联到自制电化学流动池的下游，用以跟踪溶解在腐蚀溶液中的腐蚀产物的浓度瞬变，使实时测定金属电极元素溶解速率成为可能。本文简要介绍了该技术的工作原理和发展，并对目前该技术在金属腐蚀研究中的应用进行了总结，指出了该技术存在的问题和今后的发展方向。

关键词 ：元素分析, 电化学, 电感耦合等离子体原子发射光谱, 金属腐蚀

Abstract：

To improve breadth and depth of corrosion theory for metal materials, a combined technique of electrochemical-inductively coupled plasma atomic emission spectrometry (ICP-OES) was developed in recent years. In this technique, an inductively coupled plasma atomic emission spectrometer was coupled to the downstream of a home-built electrochemical flow cell to track the concentration transient of the corrosion products dissolved in the corrosion medium, so that the elemental dissolution rates of metal electrode could be determined in real time. The working principles and the development of this technology were introduced briefly and the applications of this technology in metal corrosion research were summarized at present. Finally, the existing problems and future directions for development of this technique were pointed out.

Key words： elemental analysis electrochemical ICP-OES metal corrosion

收稿日期: 2022-08-29 32134.14.1005.4537.2022.265

ZTFLH:

TG172

基金资助:国家自然科学基金(51871227);国家自然科学基金(51671198)

通讯作者: 李瑛，E-mail: liying@imr.ac.cn，研究方向为腐蚀电化学基础理论

Corresponding author: LI Ying, E-mail: liying@imr.ac.cn

作者简介: 于英杰，女，1987年生，博士，工程师，中国科学院金属研究所分析测试中心工程师。2006 年考入吉林大学高分子材料与工程专业，后赴美国佛罗里达州立大学攻读分析化学专业硕士学位，2012 年回国后入职中国科学院金属所分析测试中心，期间师从李瑛研究员在职攻读博士学位。现主要从事化学分析和腐蚀电化学方面的研究工作。发表学术论文10 余篇，申请和已授权专利5 项；建立企业标准1 项。获“金属研究所管理和支撑部门青年人才报告会一等奖”，2022 年获得曹楚南科教基金优秀论文奖。现任中文核心期刊《冶金分析》青年编委。

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引用本文:

于英杰, 李瑛. 电化学-电感耦合等离子体原子发射光谱联用技术及其在金属腐蚀研究中的应用[J]. 中国腐蚀与防护学报, 2023, 43(4): 847-854.
YU Yingjie, LI Ying. A Novel Technique of Electrochemical-inductively Coupled Plasma Atomic Emission Spectrometry and Its Application in Corrosion Research. Journal of Chinese Society for Corrosion and protection, 2023, 43(4): 847-854.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2022.265 或 https://www.jcscp.org/CN/Y2023/V43/I4/847

图1 电化学-电感耦合等离子体原子发射光谱的示意图[22]

图2 Ogle和Weber设计的电化学流动池示意图以及三维图[22]

图3 用于原位划伤实验的电化学流动池的示意图[25]

图4 新型电化学流动池示意图[26]

图5 磷酸盐转化涂层在0.1 mol/L NaOH溶液中的电化学-ICP-OES溶解曲线[38]

图6 在阴极恒电位 (-1.5 V vs. SCE) 下，AA6061合金在3% NaCl溶液中的元素溶解曲线，测试前预先对金属电极施加-1.8 V的电位进行预活化[30]

图7 纯镁的ICP-OES信号和电流信号与不同电位阶跃信号的曲线[31]

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