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中国腐蚀与防护学报  2008, Vol. 28 Issue (4): 246-250     
  研究报告 本期目录 | 过刊浏览 |
成分和组织影响钢CO2腐蚀的研究进展
孙建波;柳伟;路民旭
北京科技大学 材料科学与工程学院 腐蚀与防护中心
Effect of Alloying Elements and Microstructure on Steel Corrosion Behavior in CO2 Environments
;;minxv Lu
北京科技大学 材料科学与工程学院 腐蚀与防护中心
全文: PDF(1060 KB)  
摘要: 综述了成分和组织对钢CO2腐蚀的影响机理,讨论了腐蚀产物膜的形态、结构和保护性能与钢的成分和组织的关系,分析了钢CO2腐蚀的电化学研究现状,指出了进一步研究的难点和主要方向。
关键词 CO2腐蚀合金元素组织    
Abstract:The effect of chemical composites and microstructure on CO2 corrosion of steels was reviewed. The relations of morphology, microstructure and protection property of CO2 corrosion scale to chemical composites and microstructure were discussed. The present research situation of CO2 corrosion electrochemistry was also analyzed. Then the difficulty and main direction for further research were pointed out.
Key wordsCO2 corrosion    steel    microstructure    alloying elements
收稿日期: 2006-09-26     
ZTFLH:  TG174.1  
通讯作者: 孙建波     E-mail: dr.sunjianbo@gmail.com;sunjianbo@china.com.cn

引用本文:

孙建波; 柳伟; 路民旭 . 成分和组织影响钢CO2腐蚀的研究进展[J]. 中国腐蚀与防护学报, 2008, 28(4): 246-250 .
Minxv Lu. Effect of Alloying Elements and Microstructure on Steel Corrosion Behavior in CO2 Environments. J Chin Soc Corr Pro, 2008, 28(4): 246-250 .

链接本文:

https://www.jcscp.org/CN/      或      https://www.jcscp.org/CN/Y2008/V28/I4/246

[1]Schmitt G.Fundamental Aspects of CO2 Corrosion[A].In:HauslerR H,Giddard H P,eds.Advances in CO2 Corrosion[C].Hous-ton,Texas:NACE,1984,1:10
[2]Kermani M B,Morshed A.Carbon dioxide corrosion in oil and gasproduction-A compendium[J].Corrosion,2003,59(8):659-683
[3]Zhang X Y,Di C,Lei L C.CO2 Corrosion and Control[M].Bei-jng:Chemical Industry Press,2000:15-17(张学元,邸超,雷良才.二氧化碳腐蚀与控制[M].北京:化学工业出版社,2000:15-17)
[4]Lu M X,Bai Z Q,Zhao X W,et al.Actuality and typical casesfor corrosion in the process of extraction,gathering,storage andtransmission for oil and gas[J].Corros.Prot.,2002,23(3):105-113(路民旭,白真权,赵新伟等.油气采集储运中的腐蚀现状及典型案例[J].腐蚀与防护,2002,23(3):105-113)
[5]Lu M X.New investigation and application development of hightemperature and pressure CO2 corrosion in multiphase media[A].4th National Corrosion Congress[C].Beijing:Chinese Society forCorrosion and Protection,2003:40-57(路民旭.高温高压CO2多相介质腐蚀研究及应用的新进展[A].第四届全国腐蚀大会论文集[C].北京:中国腐蚀与防护学会,2003:40-57)
[6]Crolet J L,Bonies M R.A tentative method for predicting the cor-rosivity of wells in new CO2 fields[A].Corrosion/85[C].Boston,Massachusetts:NACE.1985,27
[7]Dugstad A,Hemmer H,Seiersten M.Effect of steel microstructureupon corrosion rate and protective iron carbonate film formation[A].Corrosion/2000[C].Houston,Texas:NACE,2000,24
[8]Gulbrandsen E,Nyborg R.Effect of steel microstructure and com-position on inhibition of CO2 corrosion[A].Corrosion/2000[C].Houston,Texas:NACE,2000,23
[9]Gulbrandsen E,Nesic S,Stangeland A,et al.Effect of precorro-sion on the performance of inhibitors for CO2 corrosion of carbonsteel[A].Corrosion/98[C].Houston Texas:NACE,1998,13
[10]Mora-Mendoza J L,Turgoose S.Fe3C influence on the corrosionrate of mild steel in aqueous CO2 systems under turbulent flowconditions[J].Corros.Sci.,2002,44(6):1223-1246
[11]Al-Hassan S,Mishra B,Olson D L,et al.Effect of microstruc-ture on corrosion of steels in aqueous solutions containing carbondioxide[J].Corrosion,1998,54(6):480-491
[12]Lu M X,Zhang G A,Chang W,et al.Effect of microstructureand composition on CO2 corrosion[J].J.Chin.Corros.Eng.,2005,19(3):309-318(路民旭,张国安,常炜等.微观组织和合金成分对CO2腐蚀行为的影响规律[J].防蚀工程,2005,19(3):309-318)
[13]Ikeda A,Ueda M,Mukai S.CO2 corrosion behavior and mecha-nism of carbon steel and alloy steel[A].Corrosion/83[C].Hous-ton,Texas:NACE,1983,45
[14]Nice P I,Takabe H,Ueda M.The development and implementa-tion of a new alloyed steel for oil and gas production wells[A].Corrosion/2000[C].Houston,Texas:NACE,2000,154
[15]Takabe H,Ueda M.The formation behavior of corrosion protec-tive films of low Cr bearing steels in CO2 environments[A].Corro-sion′01[C].NACE International,Houston,TX,2001,66
[16]Zhang G A,Lu M X,Wu Y S.Morphology and microstructure ofCO2 corrosion scales[J].Chin.J.Mater.Res.,2005,19(5):537-548(张国安,路民旭,吴荫顺.CO2腐蚀产物膜的微观形貌和结构特征[J].材料研究学报,2005,19(5):537-548)
[17]Nice P I,Veda M.The effect of microstructure and Cr alloyingcontent to the corrosion resistance of low-alloy steel well tubing inseawater injection service[A].Corrosion/98[C].Houston,Texas:NACE,1998,3
[18]Kermani M B,Gonzales J C,Turconi G L,et al.Development ofsuperior corrosion resistance 3%Cr steels for downhole applica-tions[A].Corrosion/2003[C].Houston,Texas:NACE,2003,116
[19]Kermani M B,Gonzales J C,Linne C,et al.Development of lowcarbon Cr-Mo steels with exceptional corrosion resistance for oil-field applications[A].Corrosion/2001[C].Houston,Texas:NACE,2001,65
[20]Pletcher D,Sidorin D,Hedges B.A comparison of the corrosionof carbon and 13%chromium steels in oilfield brines containingacetate[A].Corrosion/2005[C].Houston,Texas:NACE,2005,05301
[21]Kimura M,Miyata Y,Sakata K,et al.Corrosion resistance ofmartensitic stainless steel OCTG in high temperature and high CO2environment[A].Corrosion/2004[C].New Orleans,Louisiana:NACE,2004,04118
[22]Kermani M B,Gonzales J C,Turconi G L,et al.In-field corro-sion performance of 3%Cr steels in sweet and sour downhole pro-duction and water injection[A].Corrosion/2004[C].New Or-leans,Louisiana:NACE,2004,04111
[23]Pigliacampo L,Gonzales J C,Turconi G L,et al.Window of ap-plication and operational track record of low carbon 3Cr steeltubular[A].Corrosion/2006[C].San Diego,California:NACE,2006,06133
[24]Chen C F.Research on electrochemical behavior and corrosionscale characteristics of CO2 corrosion for tubing and casing steel[D].Xi'an:Northwestern Polytechnical University,2002(陈长风.油套管钢CO2腐蚀电化学行为和腐蚀产物膜特性研究[D].西安:西北工业大学,2002)
[25]Sugiyama M,Hara T,Asahi H.Roles of copper and nickel in13%Cr stainless steel for improvement of wet carbon dioxide cor-rosion resistance[J].Corrosion,2001,57(9):777-786
[26]Clover D,Kinsella B,Pejcic B,et al.The influence of mi-crostructure on the corrosion rate of various carbon steels[J].J.Appl.Electrochem.,2005,35(2):139-149
[27]Lopez,D A,Schreiner W H,De Sanchez S R,et al.The influ-ence of inhibitors molecular structure and steel microstructure oncorrosion layers in CO2 corrosion:An XPS and SEM characteriza-tion[J].Appl.Surf.Sci.,2004,236(1-4):77-97
[28]Palacios C A,Shadley J R.Characteristics of corrosion scales onsteels in a CO2-saturated NaCl brine[J].Corrosion,1991,47(2):122-127
[29]Crolet J L.Influence of a layer of undissolved cementite on therate of the CO2 corrosion of carbon steel[A].Corrosion/94[C].Houston,Texas:NACE,1994,4
[30]Joosten M W,Johnsen T,Dugstad A,et al.In situ observationof localized CO2 corrosion[A].Corrosion/94[C].Houston,Texas:NACE,1994,3
[31]Chitwood G B,Hilts R L.A case-history analysis of using plaincarbon&alloy steel for completion equipment in CO2 service[A].Corrosion/94[C].Houston,Texas:NACE,1994,20
[32]Kapusta S D,Canter S C.Corrosion control in CO2 enhanced oilrecovery[A].Corrosion/94[C].Houston,Texas:NACE,1994,10
[33]Ueda M,Takabe H.Effect of environmental factor and microstruc-ture on morphology of corrosion products in CO2 environments[A].Corrosion/99[C].Houston,Texas:NACE,1999,13
[34]Lopez D A,Schreinerb W H,de Sancheza S R,et al.The influ-ence of carbon steel microstructure on corrosion layers:An XPSand SEM characterization[J].Appl.Surf.Sci.,2003,207:69-85
[35]Crolet J L,Thevenot N,Nesic S.Role of conductive corrosionproducts in the protectiveness of corrosion layers[J].Corrosion,1998,54(3):194-203
[36]Heuer J K,Stubbins J F.Microstructure analysis of coupons ex-posed to carbon dioxide corrosion in multiphase flow[J].Corro-sion,1998,54(7):566-575
[37]Ueda M,Ikeda A.Effect of microstructure and Cr content insteel on CO2 corrosion[A].Corrosion/96[C].Houston,Texas:NACE,1996,13
[38]Paolinelli L D,Simison S N,Pérez T.The influence of Cr con-tent on the efficiency of inhibitor of C-Mn steel CO2 corrosion[A].Corrosion/2006[C].San Diego,California:NACE,2006,06369
[39]Kinsella B,Tan Y J,Bailey S.Electrochemical impedance spec-troscopy and surface characterization techniques to study carbondioxide corrosion product scales[J].Corrosion,1998,54(10):835-842
[40]Tan Y J,Bailey S,Kinsella B.An investigation of the formationand destruction of corrosion inhibitor films using electrochemicalimpedance spectroscopy(EIS)[J].Corros.Sci.,1996,38(9):1545-1561
[41]Li J,Sun D B,Yu H Y,et al.EIS characteristics of anodic dis-solution for P110 steel under CO2 environment[J].Electrochem-istry,2001,7(1):120-125(李静,孙冬柏,俞宏英等.CO2环境中P110钢阳极溶解过程EIS特征[J].电化学,2001,7(1):120-125)
[42]Chen C F,Lu M X,Zhao G X,et al.The EIS analysis of elec-trode reactions of CO2 corrosion of N80 steel[J].Acta Metall.Sin.,2002,38(7):770-774(陈长风,路民旭,赵国仙等.N80钢CO2腐蚀电极过程交流阻抗分析[J].金属学报,2002,38(7):770-774)
[43]Chen C F,Lu M X,Zhao G X,et al.Electrochemical character-istics of CO2 corrosion of well tube steels with corrosion scales[J].J.Chin.Soc.Corros.Prot.,2003,23(3):139-143(陈长风,路民旭,赵国仙等.腐蚀产物膜覆盖条件下油套管钢CO2腐蚀电化学特征[J].中国腐蚀与防护学报,2003,23(3):139-143)
[44]Lopez D A,Simison S N,de Sanchez S R.Inhibitors perfor-mance in CO2 corrosion,EIS studies on the interaction betweentheir molecular structure and steel microstructure[J].Corros.Sci.,2005,47(3):735-755
[45]William D,Roland D M,Alan J,Brian K.Harmonic analysis ofcarbon dioxide corrosion[J].Corros.Sci.,2002,44(6):1213-1221
[46]Yannick G,Pletcher D,Hedges B.Speciation and electrochem-istry of brines containing acetate ion and carbon dioxide[J].J.Electroanal.Chem.,2002,538-539:285-297
[47]Jiang X,Luo S Z,Zheng Y G,et al.Study on inhibitor proper-ties of quaternary alkynoxymethyl amine and imidazoline for N80seamless steel in 3%NaCl saturated by CO2[J].J.Chin.Soc.Corros.Prot.,2004,24(1):10-15(蒋秀,骆素珍,郑玉贵等.炔氧甲基季胺盐和咪唑啉对N80在饱和CO2的3%NaCl溶液中的缓蚀性能研究[J].中国腐蚀与防护学报,2004,24(1):10-15)
[48]Wang F P,Li X G.Influence of NaCl on corrosion behavior ofAPI P105 steel in CO2 saturated solution[J].J.Univ.Sci.Tech-nol.Beijing,2002,24(2):97-99(王凤平,李晓刚.API P105油管钢在含CO2溶液中的电化学腐蚀行为[J].北京科技大学学报,2002,24(2):97-99)
[49]Wang S H,George K,Nesic S.High pressure CO2 corrosionelectrochemistry and the effect of acetic acid[A].Corrosion/2004[C].Houston,Texas:NACE,2004,375
[50]Guo X P,Tomoe Y.Electrochemical behavior of carbon steel incarbon dioxide-saturated diglycolamine solutions[J].Corrosion,1998,54(11):931-939
[51]Guo X P,Tomoe Y.The effect of corrosion product layers on theanodic and cathodic reactions of carbon steel in CO2-saturatedMDEA solutions at 100℃[J].Corros.Sci.,1999,41(7):1391-1402
[52]Hong T,Shi H,Wand H,et al.EIS study of corrosion productfilm in pipelines[A].Corrosion/2000[C].Houston,Texas:NACE,2000,44
[53]Zhang G A.Investigation of the mechanical properties of the cor-rosion scales and the electrochemical behaviors of carbon dioxidecorrosion under high temperature and high pressure conditions[D].Beijing:University of Science and Technology Beijing,2006(张国安.高温高压CO2腐蚀产物膜力学性能及腐蚀电化学行为的研究[D].北京:北京科技大学,2006)
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