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中国腐蚀与防护学报  2025, Vol. 45 Issue (2): 249-260     CSTR: 32134.14.1005.4537.2024.193      DOI: 10.11902/1005.4537.2024.193
  临氢关键材料服役行为研究专刊 本期目录 | 过刊浏览 |
掺氢天然气管线钢氢渗透行为研究进展
王慧玲1,2, 明洪亮1,2(), 王俭秋1,2,3, 韩恩厚3
1.中国科学技术大学材料科学与工程学院 沈阳 110016
2.中国科学院金属研究所 沈阳 110016
3.广东腐蚀科学与技术创新研究院 广州 510530
Research Progress on Hydrogen Permeation Behavior of Hydrogen-doped Natural Gas Pipeline Steel
WANG Huiling1,2, MING Hongliang1,2(), WANG Jianqiu1,2,3, HAN En-Hou3
1.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China
2.Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3.Institute of Corrosion Science and Technology, Guangzhou 510530, China
引用本文:

王慧玲, 明洪亮, 王俭秋, 韩恩厚. 掺氢天然气管线钢氢渗透行为研究进展[J]. 中国腐蚀与防护学报, 2025, 45(2): 249-260.
Huiling WANG, Hongliang MING, Jianqiu WANG, En-Hou HAN. Research Progress on Hydrogen Permeation Behavior of Hydrogen-doped Natural Gas Pipeline Steel[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(2): 249-260.

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摘要: 

当前绿色低碳能源发展迫在眉睫，氢能作为低碳能源受到了广泛关注。利用在役的天然气管线钢长距离输氢是当前最经济、最有效的方式，但管线钢在临氢环境中易发生的氢渗透及其引起的氢损伤，严重影响管道的安全运行。因此，研究掺氢天然气管线钢的氢渗透行为具有重要的意义。目前，管线钢氢渗透行为的研究方法主要包括电化学氢渗透和气相氢渗透。本文简述了不同氢渗透方法中氢的渗透过程以及氢渗透行为的影响因素，并介绍了计算氢渗透参数的模型及方法。
关键词 ： 管线钢,  电化学氢渗透,  气相氢渗透,  氢渗透曲线    
Abstract：

The development of green and low-carbon energy is imminent at present, and the hydrogen has been widely concerned as a low-carbon energy. At the present, it is the most economical and effective way to use the natural gas pipeline steel in service for long-distance hydrogen transport, but the pipeline steel is susceptible to hydrogen permeation, and hydrogen damage may invariably be caused by hydrogen permeation in the hydrogen-containing environment, which seriously affects the safe operation of the pipeline. Therefore, it is of great significance to study the hydrogen permeation behavior of pipeline steel used for transporting hydrogen-doped natural gas. The research methods of hydrogen permeation behavior of pipeline steel mainly include electrochemical hydrogen permeation and gaseous hydrogen permeation now. Herein, the similarities and differences in the hydrogen permeation processes and the factors affecting the hydrogen permeation behavior of pipeline steels caused by different hydrogen permeation methods are briefly described. The models and methods for calculating hydrogen permeation parameters are also introduced.
Key words： pipeline steel    electrochemical hydrogen permeation    gaseous hydrogen permeation    hydrogen permeation curve
收稿日期: 2024-07-01      32134.14.1005.4537.2024.193
ZTFLH:  TG172  
基金资助:国家重点研发计划(2021YFB4001601);中国科学院青年创新促进会资助(2022187)
通讯作者: 明洪亮，E-mail：hlming12s@imr.ac.cn，研究方向为材料力学化学交互作用
Corresponding author: MING Hongliang, E-mail: hlming12s@imr.ac.cn
作者简介: 王慧玲，女，1999年生，博士生
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https://www.jcscp.org/CN/10.11902/1005.4537.2024.193      或      https://www.jcscp.org/CN/Y2025/V45/I2/249

图1  电化学氢渗透装置示意图
图2  金属中电化学氢渗透过程示意图[12]
图3  钢中的氢陷阱位置示意图[17]
图4  气相氢渗透装置示意图
图5  体心立方α-Fe不同晶面的原子排列及吸附位点[33,35,36]
Adsorbed gasTopShort bridgeLong bridgeThree-fold
CO-1.89-1.64-1.82-1.83
H2-0.47-0.82-1.04-1.33
表1  CO和H2在Fe(110)面不同位点的吸附能(eV)[46]
MaterialHydrogen pressure or hydrogen blending ratioi∞DeffC0
X52[49]2.5%, 12.5%, 25%, 50% (total pressure: 4 MPa)IncreaseAlmost constantIncrease
X65[18]1 MPa, 5 MPa, 10 MPaIncreaseIncreaseIncrease
X80[48]3%, 5%, 10%, 15%, 20% (total pressure: 10 MPa)IncreaseAlmost constantIncrease
X80[47]2 MPa, 5 MPa, 8 MPa (total pressure: 12 MPa)IncreaseIncreaseIncrease
表2  不同管线钢的气相氢渗透参数在氢压或掺氢比增加时的变化趋势
图6  氢渗透曲线示意图
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