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中国腐蚀与防护学报  2025, Vol. 45 Issue (1): 103-114     CSTR: 32134.14.1005.4537.2024.153      DOI: 10.11902/1005.4537.2024.153
  研究报告 本期目录 | 过刊浏览 |
静水压力对Cr/GLC叠层涂层腐蚀行为的影响
马宏宇1,2, 刘叡1, 崔宇2(), 柯培玲3, 刘莉1, 王福会1
1 东北大学腐蚀与防护中心 沈阳 110819
2 中国科学院金属研究所 师昌绪先进材料创新中心 沈阳 110016
3 中国科学院宁波材料技术与工程研究所公共技术中心 宁波 315201
Effect of Hydrostatic Pressure on Corrosion Behavior of Cr/GLC Laminated Coating
MA Hongyu1,2, LIU Rui1, CUI Yu2(), KE Peiling3, LIU Li1, WANG Fuhui1
1 Corrosion and Protection Center, Northeastern University, Shenyang 110819, China
2 Shi -changxu Innovation Center for Advanced Materials, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
3 Public Technology Center, Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, China
引用本文:

马宏宇, 刘叡, 崔宇, 柯培玲, 刘莉, 王福会. 静水压力对Cr/GLC叠层涂层腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(1): 103-114.
Hongyu MA, Rui LIU, Yu CUI, Peiling KE, Li LIU, Fuhui WANG. Effect of Hydrostatic Pressure on Corrosion Behavior of Cr/GLC Laminated Coating[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(1): 103-114.

全文: PDF(16109 KB)   HTML
摘要: 

以Cr/GLC叠层涂层为研究对象，通过原位电化学测试、扫描电子显微镜(SEM)和二次离子质谱(SIMS)等方法研究了3.5%NaCl溶液中0.1 MPa和15 MPa静水压力下涂层的腐蚀行为。结果表明，高静水压力加速了Cr/GLC叠层涂层腐蚀失效。静水压力显著增加Cr/GLC叠层涂层的腐蚀电流密度，促进涂层表面和涂层/金属基体界面Cl-吸附，降低涂层/金属基体界面结合力。
关键词 ： Cr/GLC叠层涂层,  静水压力,  电化学测试,  腐蚀    
Abstract：

The corrosion behavior of laminated coating chromium/graphite-like amorphous carbon (Cr/GLC) on 431 stainless steel in 3.5%NaCl solution by applied hydrostatic pressures ranging 0.1 MPa to 15 MPa was investigated by in-situ electrochemical measurements, scanning electron microscopy (SEM) and secondary ion mass spectrometry (SIMS). The results showed that high hydrostatic pressure may accelerate the corrosion failure of laminated coating Cr/GLC. Hydrostatic pressure significantly increases the corrosion current density of laminated coating Cr/GLC, promotes Cl- adsorption on the coating surface and inward to the coating/metal substrate interface, thereby decreases the interface bonding strength of coating/metal substrate.
Key words： Cr/GLC laminated coating    hydrostatic pressure    electrochemical measurement    corrosion
收稿日期: 2024-05-16      32134.14.1005.4537.2024.153
ZTFLH:  TG174  
基金资助:中国科学院A类战略性先导科技专项(XDA22010303)
通讯作者: 崔宇，E-mail：ycui@imr.ac.cn，研究方向为深海金属腐蚀防护
Corresponding author: CUI Yu, E-mail: ycui@imr.ac.cn
作者简介: 马宏宇，男，1996年生，博士生
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链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2024.153      或      https://www.jcscp.org/CN/Y2025/V45/I1/103

图1  模拟深海环境系统[30]
图2  Cr/GLC叠层涂层的表面、截面形貌，生长缺陷和EDS结果
图3  0.1 MPa和 15 MPa压力下服役不同时间后Cr/GLC叠层涂层表面腐蚀形貌
图4  0.1 MPa和15 MPa服役不同时间后Cr/GLC叠层涂层的截面腐蚀形貌
图5  Cr/GLC叠层涂层在0.1 MPa和15 MPa压力下浸泡不同时间后的Bode图
Time / hRs / Ω·cm2Rf / Ω·cm2nfQf / F·cm-2Rdl / Ω·cm2ndlQdl / F·cm-2
0.514.175.32 × 1050.934.36 × 10-64.59 × 1060.929.28 × 10-7
413.975.52 × 1050.944.46 × 10-64.86 × 1060.919.38 × 10-7
813.637.37 × 1050.944.03 × 10-67.67 × 1060.929.54 × 10-7
1214.159.55 × 1050.944.08 × 10-61.05 × 1070.898.52 × 10-7
2414.731.18 × 1060.944.04 × 10-61.09 × 1070.906.71 × 10-7
3614.81.06 × 1060.954.27 × 10-66.51 × 1060.887.09 × 10-7
4812.568.64 × 1050.954.16 × 10-68.66 × 1060.866.73 × 10-7
7211.688.72 × 1050.954.25 × 10-69.13 × 1060.883.21 × 10-7
12010.497.99 × 1050.944.29 × 10-67.96 × 1060.786.42 × 10-7
15611.116.19 × 1050.924.55 × 10-66.37 × 1060.821.09 × 10-6
22813.315.46 × 1050.925.12 × 10-64.83 × 1060.811.19 × 10-6
27612.723.41 × 1050.925.60 × 10-61.22 × 1060.781.33 × 10-6
34810.925.51 × 1050.934.95 × 10-65.83 × 1060.846.98 × 10-7
48013.582.61 × 1050.925.60 × 10-61.08 × 1060.781.10 × 10-6
57612.25.37 × 1050.925.35 × 10-62.47 × 1060.731.04 × 10-6
61212.41.71 × 1050.925.75 × 10-61.01 × 1060.805.56 × 10-7
64813.311.38 × 1050.925.75 × 10-63.93 × 1050.731.09 × 10-6
72012.521.14 × 1050.915.82 × 10-63.60 × 1050.821.09 × 10-6
表1  0.1 MPa压力下Cr/GLC叠层涂层在3.5%NaCl溶液中浸泡不同时间的EIS拟合结果
Time / hRs / Ω·cm2Rf / Ω·cm2nfQf / F·cm-2Rdl / Ω·cm2ndlQdl / F·cm-2
29.485.29 × 1040.932.04×10-51.63 × 1050.838.29 × 10-6
69.405.21 × 1040.922.20×10-51.59 × 1050.778.09 × 10-6
810.495.35 × 1040.931.32×10-51.81 × 1050.783.84 × 10-6
109.415.28 × 1040.922.18×10-51.62 × 1050.811.28 × 10-5
248.504.54 × 1040.901.72×10-59.01 × 1040.752.81 × 10-5
309.425.00 × 1040.922.25×10-51.46 × 1050.812.58 × 10-5
489.344.07 × 1040.902.44×10-55.48 × 1040.788.09 × 10-6
969.273.94 × 1040.902.81×10-54.71 × 1040.793.36 × 10-5
1209.234.02 × 1040.892.95×10-55.42 × 1040.844.93 × 10-5
1329.078.85 × 1030.836.88×10-56.65 × 1040.931.49 × 10-4
1688.976.93 × 1020.781.65×10-48.47 × 1030.723.08 × 10-4
2408.986.11 × 1020.761.99×10-47.68 × 1030.732.93 × 10-4
3609.195.00 × 1020.772.02×10-45.58 × 1030.723.15 × 10-4
表2  15 MPa压力下Cr/GLC叠层涂层在3.5%NaCl溶液中浸泡不同时间的EIS拟合结果
图6  0.1 MPa和15 MPa下Cr/GLC叠层涂层和431不锈钢恒电位极化测试结果
图7  0.1和15 MPa压力下浸泡720 h后的Cr/GLC叠层涂层中元素沿深度分布
图8  0.1和15 MPa压力下Cr/GLC叠层涂层内Cr0.1 MPa/Cr15 MPa的峰强度比值
图9  431不锈钢基体上Cr/GLC叠层涂层在0.1 MPa压力下浸泡不同时间后的划痕形貌与摩擦力曲线
图10  431不锈钢基体上Cr/GLC叠层涂层在15 MPa压力下浸泡不同时间后划痕形貌与摩擦力曲线
图11  0.1 MPa和15 MPa压力下浸泡不同时间后Cr/GLC叠层涂层/431不锈钢基体体系界面结合力变化
图12  Cr/GLC叠层涂层的腐蚀失效机制示意图
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