铝合金霉菌腐蚀研究进展

doi:10.11902/1005.4537.2020.034

中国腐蚀与防护学报

2021, Vol. 41

Issue (1): 13-21 DOI: 10.11902/1005.4537.2020.034

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铝合金霉菌腐蚀研究进展

张雨轩, 陈翠颖, 刘宏伟(

), 李伟华

中山大学化学工程与技术学院海洋科学与工程广东省实验室珠海 519082

Research Progress on Mildew Induced Corrosion of Al-alloy

ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei(

), LI Weihua

Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519082, China

全文: PDF(5589 KB) HTML

摘要:

结合近年来铝合金霉菌腐蚀机制与防护领域研究成果，介绍了代表性霉菌的种类及影响霉菌活性的主要因素，重点总结和讨论了铝合金霉菌腐蚀机制，主要包括酸蚀机制、浓差电池机制、以及其他可能存在直接电子传递机制和霉菌铝合金直接界面作用机制。霉菌通过新陈代谢可以产生大量的有机酸，能够显著地降低介质和生物膜内的pH，从而导致酸蚀引发局部腐蚀。霉菌在铝合金表面形成的生物膜是诱发氧浓差电池产生的原因之一，铝合金霉菌腐蚀过程中潜在的直接电子传递及铝合金和霉菌的直接界面作用也是导致铝合金局部腐蚀的重要原因之一。最后介绍了目前常用的铝合金霉菌腐蚀控制方法，展望了未来铝合金霉菌腐蚀的研究重点，为铝合金霉菌腐蚀研究提供参考。

关键词 ：铝合金, 霉菌, 酸蚀, 微生物腐蚀

Abstract：

Recent years, the corrosion of Al-alloy turned to be a serious issue, which directly influence the safe operation of engineering facilities made of Al-alloy. Based on the recent research results related to the mildew induced corrosion of Al-alloy, the representative species of mildew as well as the main factors close to the mildew activity were illustrated. Meanwhile, the relevant corrosion mechanisms were emphatically discussed, including acid corrosion, oxygen concentration cell, the possible direct electron transfer as well as the direct interfacial interaction between Al-alloy and mildew. Mildew can produce large amount of organic acids through metabolism, causing the decline of the pH values in test solution and biofilm, then leading to localized corrosion. As analyzed, the potential direct electron transfer and interfacial interaction between Al-alloy and mildew can be one of important causes, leading to the localized corrosion. Furthermore, the common control methods for mildew induced corrosion of Al-alloy were also reviewed. Finally, the future research focus of Al-alloy corrosion in the presence of mildew was also prospected.

Key words： Al-alloy mildew acid corrosion microbiologically influenced corrosion

收稿日期: 2020-01-05

ZTFLH:

O646

基金资助:国家自然科学基金(51901253);广东省自然科学基金(2019A1515011135);中央高校基本科研业务费专项(19lgzd18);深水油气管线关键技术与装备北京市重点实验室开放课题(BIPT201904)

通讯作者: 刘宏伟 E-mail: liuhw35@mail.sysu.edu.cn

Corresponding author: LIU Hongwei E-mail: liuhw35@mail.sysu.edu.cn

作者简介: 张雨轩，男，1996年生，硕士生

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引用本文:

张雨轩, 陈翠颖, 刘宏伟, 李伟华. 铝合金霉菌腐蚀研究进展[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
Yuxuan ZHANG, Cuiying CHEN, Hongwei LIU, Weihua LI. Research Progress on Mildew Induced Corrosion of Al-alloy. Journal of Chinese Society for Corrosion and protection, 2021, 41(1): 13-21.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.034 或 https://www.jcscp.org/CN/Y2021/V41/I1/13

图1 曲霉菌落结构形貌、微观结构及其孢子的微观形貌[18]

表1 部分代表性霉菌的生长温度范围

图2 铝合金表面霉菌生物膜形貌，铝合金在3.5%NaCl溶液中腐蚀测试18 d后的腐蚀形貌及其腐蚀坑深度的变化[29]

图3 好氧条件下6061铝合金霉菌局部腐蚀机制[31]

图4 铝合金点蚀机制示意图[35]

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