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中国腐蚀与防护学报  2021, Vol. 41 Issue (4): 429-438    DOI: 10.11902/1005.4537.2020.133
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临海管道微生物腐蚀损伤机制与防护
李光泉1, 李广芳2, 王俊强3, 张天遂2, 张斐2, 蒋习民1, 刘宏芳2()
1.中石化石油工程技术服务有限公司 北京 100020
2.华中科技大学化学与化工学院 能量转换与存储材料化学教育部重点实验室 材料化学与服役实效湖北省重点实验室 武汉 430074
3.中国特种设备检测研究院 北京 100029
Microbiologically Influenced Corrosion Mechanism and Protection of Offshore Pipelines
LI Guangquan1, LI Guangfang2, WANG Junqiang3, ZHANG Tiansui2, ZHANG Fei2, JIANG Ximin1, LIU Hongfang2()
1.Sinopec Oilfield Service Corporation (SSC), Beijing 100020, China
2.Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
3.China Special Equipment Inspection and Research Institute (CSEI), Beijing 100029, China
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摘要: 

海洋油气管道作为大量、长距离输送油气资源最主要的方式，担负着海上油气集输的重要任务，也被称为海洋油气工程的“生命线”。然而海洋环境下的微生物腐蚀是造成海洋油气管道腐蚀损伤的重要原因之一。本文结合海洋油气输送管道的服役环境，综述了海洋环境下临海管道微生物腐蚀失效的研究进展，重点介绍了有代表性的硫酸盐还原菌和铁氧化菌在海洋环境下引起的微生物腐蚀规律和机理，并在此基础上总结了相应的海洋管道防护方法，为微生物腐蚀损伤的研究及控制提供参考。
关键词 ： 临海管道,  微生物腐蚀,  腐蚀防护    
Abstract：

As the most important method for massive and long haul transportation of oil and gas resources, offshore pipelines undertake the significant tasks of oil and gas gathering and transportation, namely the “lifeline” of offshore oil and gas engineering. However, microbiologically influenced corrosion in the marine environment is one of the important causes of corrosion damage to offshore pipelines. Based on the service environment of marine oil and gas pipelines, this paper reviews the research progress of microbiologically influenced corrosion failure of coastal pipelines in the marine environment, focusing on the regularity and mechanism of corrosion induced by sulfate reducing bacteria and iron oxidizing bacteria, which are representative bacteria for the corrosion occurrence in the marine environment. Also, the corresponding protection methods of pipelines are summarized, which provides reference for the research on microbiologically influenced corrosion damage and the corrosion control engineering of pipelines operated in marine environment.
Key words： offshore pipeline    microbiologically influenced corrosion    corrosion protection
收稿日期: 2020-07-26     
ZTFLH:  TG174  
基金资助:国家重点研发计划专项(2016YFC0802301)
通讯作者: 刘宏芳     E-mail: liuhf@hust.edu.cn
Corresponding author: LIU Hongfang     E-mail: liuhf@hust.edu.cn
作者简介: 李光泉，男，1963年生，教授级工程师
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引用本文:

李光泉, 李广芳, 王俊强, 张天遂, 张斐, 蒋习民, 刘宏芳. 临海管道微生物腐蚀损伤机制与防护[J]. 中国腐蚀与防护学报, 2021, 41(4): 429-438.
Guangquan LI, Guangfang LI, Junqiang WANG, Tiansui ZHANG, Fei ZHANG, Ximin JIANG, Hongfang LIU. Microbiologically Influenced Corrosion Mechanism and Protection of Offshore Pipelines. Journal of Chinese Society for Corrosion and protection, 2021, 41(4): 429-438.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.133      或      https://www.jcscp.org/CN/Y2021/V41/I4/429

图1  生物阴极催化硫酸盐还原机理图[28,29]
图2  SRB腐蚀金属过程中的电子转移方式[16]
图3  由Fe(OH)3沉淀形成的点蚀机理和IOB缝隙腐蚀机理示意图[36]
图4  SRB-IOB混合菌诱导金属点蚀机理示意图
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