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中国腐蚀与防护学报  2005, Vol. 25 Issue (6): 344-350     
  研究报告 本期目录 | 过刊浏览 |
搪瓷/NiCrAlY复合涂层的抗高温氧化及热腐蚀行为
田秀娟;王福会;李庆芬
腐蚀与防护国家重点实验室
High Temperature Oxidation and Hot Corrosion Behavior of Enamel/Sputtered NiCrAlY Composite Coating
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腐蚀与防护国家重点实验室
全文: PDF(378 KB)  
摘要: 研究了溅射NiCrAlY及搪瓷/NiCrAlY复合涂层在900℃空气氧化及850℃75mass%Na2SO4+25mass%K2SO4和75mass% Na2SO4+ 25mass%NaCl的热腐蚀行为。结果表明:溅射NiCrAlY涂层900℃表面生成了单一的氧化铝膜,具有良好的抗氧化性能。而搪瓷复合涂层进一步提高了NiCrAlY层的抗氧化性能。 850℃两种盐的热腐蚀表明,基体合金没有出现内氧化及内硫化现象,搪瓷层的成分也没有显著变化,表现出优异的抗热腐蚀性能。
关键词 溅射搪瓷/NiCrAlY复合涂层热腐蚀    
Abstract:High temperature oxidation and hot corrosion behavior of sputtered NiCrAlY and enamel/NiCrAlY composite coating have been studied. The results indicated that at 900℃ an Al2O3 scale formed on the sputtered NiCrAlY coating, which offered good protectiveness. The coating with enamel overlayers greatly improved the oxidation behavior of NiCrAlY coating. No obvious oxidation scale was formed at the boundary of coating and enamel. At 850℃, the coating with enamel overlayers exhibited more excellent hot corrosion resistance in the molten salt than sputtered NiCrAlY coating. Neither internal sulfidation nor oxidation occurred on the samples with the enamel coating and the composition of the enamels changed little.
Key wordssputter    enamel/NiCrAlY composite coating    hot corrosion
收稿日期: 2004-09-01     
ZTFLH:  TG146.2  
通讯作者: 田秀娟      E-mail: txj79@sohu.com

引用本文:

田秀娟; 王福会; 李庆芬 . 搪瓷/NiCrAlY复合涂层的抗高温氧化及热腐蚀行为[J]. 中国腐蚀与防护学报, 2005, 25(6): 344-350 .

链接本文:

https://www.jcscp.org/CN/Y2005/V25/I6/344

[1]Whittle D P.Alloys for Gas Turbines,High Temperature[M].Lon-don:Appl.Sci.Pub.,1978,109
[2]Felix P.Deposition and Corrosion in Gas Turbines[M].Hart A B,Culter J B,eds.London:Appl.Sci.Pub.,1972,331
[3]Gurrappa I.Identification of hot corrosion resistant MCrAlY basedbond coatings for gas turbine engine applications[J].Surf.Coat.Tech.,2001,139:272
[4]Wolfe D,Singh J.Functionally gradient ceramic/metallic coatingsfor gas turbine components by high-energy beams for high-tem-perature application[J].Mater.Sci.,1998,33:3677-3692
[5]Xie D B.The corrosion behaviors of MCrAlY and enamel/MCrAlYcomposite coatings[D].Shenyang:Doctoral Dissertation,The Chi-nese Academy of Sciences,IMR,2003(谢冬柏.MCrAlY及搪瓷/MCrAlY复合涂层的腐蚀行为研究[D].沈阳:中国科学院金属研究所博士论文,2003)
[6]Goebel J A,Pettit F S.Na2SO4-induced accelerated oxidation(hotcorrosion)of nickel[J].Metall.Trans.,1970,1:1943-1954
[7]Goebel J A,Pettit F S,Goward G W.Mechanisms for the hot cor-rosion of nickel-base alloys[J].Metall.Trans.,1973,4:261-278
[8]Lou H Y,Wang F H,Xia B,Zhang L.Oxide formation of K38G su-peralloy and its sputtered micrograined coating[J].Surf.Coat.Tech.,1994,63:105-114
[9]Zhang Y S.Dissolution behavior of metal oxides in fused Na2SO4[J].J.Chin.Soc.Corros.Prot.,1989,9:121-129
[10]Shao G X,Gou W B,Wen R C.Enamel[M].Beijing:The LightIndustry Press,1983(邵规贤,艹勾文彬,闻瑞昌等.搪瓷学[M].北京:北京轻工业出版社,1983)
[11]Ishitsuka T.Nose solubility study on protective oxide films inmolten chlorides created by refuse incineration environment[J].Mater.Corr.,2000,51:177-181
[12]Otsuka N,Kudo T.Hot Corrosion of Commercial Tube Steel Mate-rials in a Japanese Waste Incinerator Environment,High Tempera-ture Corrosion of Advanced Materials and Protective Coatings[M].Saidto Y,Onay B,Maruyama T,Ed.Amsterdam,TheNetherlands:Elsevier Science Publisher,1992,205
[13]Tang Zhaolin,Wang Fuhui,Wu Weitao.Effect of a sputtered TiAl-Cr coating on oxidation resistance of TiAl intermetallics[J].Oxid.Met.,1999,51(3/4):235-241
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