无磁钻铤不锈钢激光熔覆层的微观组织与腐蚀磨损特性

doi:10.11902/1005.4537.2025.284

中国腐蚀与防护学报

2026, Vol. 46

Issue (1): 175-185 CSTR: 32134.14.1005.4537.2025.284 DOI: 10.11902/1005.4537.2025.284

增材制造与腐蚀专题

本期目录 | 过刊浏览

无磁钻铤不锈钢激光熔覆层的微观组织与腐蚀磨损特性

纪云瀚¹, 王勤英¹^,²(

), 郑杰¹, 李怡璇¹, 西宇辰¹, 董立谨¹, 张杨飞³, 白树林³

^1.西南石油大学新能源与材料学院成都 610500
^2.四川省页岩气高效开采先进材料制备技术工程研究中心成都 610500
^3.北京大学材料科学与工程学院北京 100871

Microstructure and Tribocorrosion Behavior of Laser Cladding Coating of a Non-magnetic Drill Collar Stainless Steel

JI Yunhan¹, WANG Qinying¹^,²(

), ZHENG Jie¹, LI Yixuan¹, XI Yuchen¹, DONG Lijin¹, ZHANG Yangfei³, BAI Shulin³

^1.School of New Energy and Materials, Southwest Petroleum University, Chengdu 610500, China
^2.Sichuan Provincial Engineering Research Center of Advanced Materials Manufacturing Technology for Shale Gas High-efficient Exploitation, Chengdu 610500, China
^3.School of Materials Science and Engineering, Peking University, Beijing 100871, China

引用本文:

纪云瀚, 王勤英, 郑杰, 李怡璇, 西宇辰, 董立谨, 张杨飞, 白树林. 无磁钻铤不锈钢激光熔覆层的微观组织与腐蚀磨损特性[J]. 中国腐蚀与防护学报, 2026, 46(1): 175-185.
Yunhan JI, Qinying WANG, Jie ZHENG, Yixuan LI, Yuchen XI, Lijin DONG, Yangfei ZHANG, Shulin BAI. Microstructure and Tribocorrosion Behavior of Laser Cladding Coating of a Non-magnetic Drill Collar Stainless Steel[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(1): 175-185.

全文: PDF(25032 KB) HTML

摘要:

无磁钻铤是定向钻井中的关键部件，失效会严重威胁钻井安全，造成巨大经济损失。为提升其服役寿命，本文采用激光熔覆技术在无磁钻铤常用钢P550不锈钢表面制备了同质熔覆层，并对比分析了基体与熔覆层的腐蚀磨损行为。结果表明，激光熔覆不仅使熔覆层晶粒尺寸从42.85 μm显著细化至10.37 μm，还促使N元素在晶界处富集；使熔覆层在静态下的钝化区较基体拓宽了2.7倍，在动态磨损中，其动电位极化曲线也表现出持续的钝化特征，电化学稳定性提升。同时，由于熔覆层再钝化能力良好，且磨损表面生成富Fe²⁺保护性氧化层，其磨损体积损失低于基体。

关键词 ：无磁钻铤不锈钢, 激光熔覆, 腐蚀磨损

Abstract：

Non-magnetic drill collars are critical components in directional drilling, and their failure can severely compromise drilling safety, leading to significant economic losses. To enhance their service life, a laser cladding coating on the surface of P550 stainless steel, which is commonly used for non-magnetic drill collars was made via laser cladding technique with powders of the same composition of P550 stainless steel as filler material. The results indicate that the laser cladding presents significantly refined the grain size of 10.37 μm, in contrast to 42.85 μm of the substrate steel, meanwhile the cladding process also promots the enrichment of N at the grain boundaries. Consequently, the passivation zone of the cladding coating was broadened by 2.7 times compared to the substrate when immersion in 3.5% (mass fraction) NaCl solotion. During dynamic wear processits potentiodynamic polarization curve also exhibited the continuous passivation characteristics of the cladding, demonstrating its enhanced electrochemical stability. Furthermore, owing to the excellent re-passivation capability of the cladding coating and the formation of an Fe²⁺-rich oxide scale on the worn surface, its wear volume loss was lower than that of the substrate.

Key words： non-magnetic drill collar stainless steel laser cladding tribocorrosion

收稿日期: 2025-09-08 32134.14.1005.4537.2025.284

ZTFLH:

TG178

基金资助:国家自然科学基金(52174007);四川省科技厅项目(2025YFHZ0050)

通讯作者: 王勤英，E-mail：wangqy0401@swpu.edu.cn，研究方向为表面处理及防腐

作者简介: 纪云瀚，男，2000年生，硕士生
王勤英，1987年生，2015年毕业于北京大学，获博士学位，后于加拿大阿尔伯塔大学从事博士后工作。现就职于西南石油大学，教授，博士生导师。长期从事油气田材料腐蚀与防护及油气装备激光增材修复研究。针对极端油气开发钻采装备/工具失效难题，研发了高耐蚀耐磨激光增材强化/修复层材料体系与技术，揭示了极端油气钻采工况下强化/修复层服役行为及机制，创建了强化/修复层服役寿命预测模型与分析方法，形成了油气装备激光增材强化/修复全流程工艺，在油气及油服企业应用成效显著。主持国家自然科学基金面上、青年基金项目等纵向项目10余项，以第一或通讯作者在Corros. Sci.、Wear 等期刊发表论文45篇(含ESI 高被引论文1 篇)，出版英文专著1部，授权发明专利12 件(含PCT专利1 件)，登记软件著作权5件。牵头获中国腐蚀与防护学会杰出青年学术成就奖、中国石油和化工自动化行业科技进步二等奖、四川省科技进步三等奖等各类科技奖励8 项。先后入选澳大利亚“奋进”学者、中国科协“青年人才托举工程”、四川省学术和技术带头人后备人选，担任《中国腐蚀与防护学报》青年编委。

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图1 P550不锈钢粉末的形貌、粒径分布及激光熔覆示意图

图2 P550不锈钢基体与熔覆层经10%草酸溶液电解腐蚀后的光学显微组织

图3 P550不锈钢基体与熔覆层的XRD图谱和P550不锈钢熔覆层横截面的SEM形貌

表1 图3b中P550不锈钢熔覆层标记位置1和2的EDS元素含量结果

图4 P550不锈钢基体与熔覆层在不同电化学状态下的磨损表面三维轮廓

图5 P550不锈钢基体与熔覆层在不同电化学状态下的磨痕截面平均深度分布及摩擦系数

图6 OCP下P550不锈钢熔覆层与基体的磨损表面SEM形貌及元素分布图

图7 阴极保护电位条件下P550不锈钢熔覆层与基体的磨损表面SEM形貌及元素分布

图8 P550不锈钢基体与熔覆层在静态和腐蚀磨损中的动电位极化曲线及开路电位

表2 P550不锈钢基体与熔覆层在腐蚀磨损过程中的动电位极化曲线拟合结果

图9 OCP条件下P550不锈钢熔覆层与基体磨损表面的Fe 2p、Cr 2p和Mn 2p高分辨XPS光谱

图10 根据XPS图谱计算获得的元素价态组成

表3 P550不锈钢基体与熔覆层腐蚀磨损后各体积损失分量表

图11 P550不锈钢基体与熔覆层腐蚀磨损后各体积损失分量占比柱状图

[1]	Saller G, Aigner H. High nitrogen alloyed steels for nonmagnetic drill collars. Standard steel grades and latest developments [J]. Mater. Manuf. Process., 2004, 19: 41 doi: 10.1081/AMP-120027497
[2]	Maher M, Iraola-Arregui I, Ben Youcef H, et al. The synergistic effect of wear-corrosion in stainless steels: a review [J]. Mater. Today Proc., 2022, 51: 1975
[3]	Sun F H, Ren Y J, Song W Q. Research status and progress of laser clad coatings on 42CrMo steel [J] J. Chin. Soc. Corros. Prot., 2025, 45: 849
[3]	孙方红, 任延杰, 宋文卿. 42CrMo钢表面激光熔覆涂层的研究现状及进展 [J]. 中国腐蚀与防护学报, 2025, 45: 849 doi: 10.11902/1005.4537.2024.378
[4]	Song Y H, Wang Q Y, Xie Y F, et al. Microstructure and tribocorrosion mechanism of laser additive manufacturing IN625 coating [J]. Wear, 2025, 564-565: 205727 doi: 10.1016/j.wear.2024.205727
[5]	Yang C L, Lu Y L, Kong D J. Laser cladded Ni625-xCr₃C₂ coatings: microstructure, tribocorrosion and electrochemical properties [J]. Surf. Coat. Technol., 2024, 478: 130487 doi: 10.1016/j.surfcoat.2024.130487
[6]	Sun W T, Huang X H, Zhang J, et al. The roles of microstructural anisotropy in tribo-corrosion performance of one certain laser cladding Fe-based alloy [J]. Friction, 2023, 11: 1673 doi: 10.1007/s40544-022-0682-x
[7]	Cui B, Zhou P Q, Lv Y. Research progress in and defect improvement measures for laser cladding [J]. Materials, 2025, 18: 3206 doi: 10.3390/ma18133206
[8]	Nishimoto K, Mori H. Hot cracking susceptibility in laser weld metal of high nitrogen stainless steels [J]. Sci. Technol. Adv. Mater., 2004, 5: 231 doi: 10.1016/j.stam.2003.10.006
[9]	Yu C J, Zhang D B, Liu Z G, et al. Study on nitrogen pores, microstructure, and mechanical properties of nickel-free high-nitrogen stainless steel fabricated via LDED regulated by heat input [J]. Virtual Phys. Prototyp., 2025, 20: e2445711 doi: 10.1080/17452759.2024.2445711
[10]	Bermingham M J, StJohn D H, Krynen J, et al. Promoting the columnar to equiaxed transition and grain refinement of titanium alloys during additive manufacturing [J]. Acta Mater., 2019, 168: 261 doi: 10.1016/j.actamat.2019.02.020
[11]	Kurz W, Bezençon C, Gäumann M. Columnar to equiaxed transition in solidification processing [J]. Sci. Technol. Adv. Mater., 2001, 2: 185 doi: 10.1016/S1468-6996(01)00047-X
[12]	Liu G M, Liu Y Y, Cheng Y W, et al. The intergranular corrosion susceptibility of metastable austenitic Cr-Mn-Ni-N-Cu high-strength stainless steel under various heat treatments [J]. Materials, 2019, 12: 1385 doi: 10.3390/ma12091385
[13]	Bratsch S G. Standard electrode potentials and temperature coefficients in water at 298.15 K [J]. J. Phys. Chem. Ref. Data, 1989, 18: 1 doi: 10.1063/1.555839
[14]	Zhang B, Wang J, Wu B, et al. Quasi-in-situ ex-polarized TEM observation on dissolution of MnS inclusions and metastable pitting of austenitic stainless steel [J]. Corros. Sci., 2015, 100: 295 doi: 10.1016/j.corsci.2015.08.009
[15]	Park I J, Lee S M, Kang M, et al. Pitting corrosion behavior in advanced high strength steels [J]. J. Alloy. Compd., 2015, 619: 205 doi: 10.1016/j.jallcom.2014.08.243
[16]	Szummer A, Janik-Czachor M. Corrosion behaviour of low-manganese stainless steels [J]. Corros. Sci., 1993, 35: 317 doi: 10.1016/0010-938X(93)90163-B
[17]	Sun Y, Rana V. Tribocorrosion behaviour of AISI 304 stainless steel in 0.5M NaCl solution [J]. Mater. Chem. Phys., 2011, 129: 138 doi: 10.1016/j.matchemphys.2011.03.063
[18]	Zemlik M, Białobrzeska B, Stachowicz M, et al. The influence of grain size on the abrasive wear resistance of hardox 500 Steel [J]. Appl. Sci., 2024, 14: 11490 doi: 10.3390/app142411490
[19]	Yang S P, Huang S Y, Li G, et al. Interaction behavior of wear and corrosion of highstrength marine steels for polar navigation vessels [J] J. Chin. Soc. Corros. Prot., 2025, 45: 894
[19]	杨淞普, 黄诗雨, 李刚等. 极地航行船舶用高强钢的磨损腐蚀交互作用机制 [J]. 中国腐蚀与防护学报, 2025, 45: 894 doi: 10.11902/1005.4537.2024.298
[20]	Du J, Hu L L, Sun J, et al. Tribo-corrosion performance of 7075-T6 Al-alloy in 3.5%NaCl solution [J] J. Chin. Soc. Corros. Prot., 2025, 45: 803
[20]	杜晋, 胡林岚, 孙健等. 7075-T6铝合金在3.5%NaCl溶液中的摩擦腐蚀性能研究 [J]. 中国腐蚀与防护学报, 2025, 45: 803
[21]	Hardell J, Hernandez S, Mozgovoy S, et al. Effect of oxide layers and near surface transformations on friction and wear during tool steel and boron steel interaction at high temperatures [J]. Wear, 2015, 330-331: 223 doi: 10.1016/j.wear.2015.02.040
[22]	Yang X D, Li C W, Ye Z H, et al. Effects of tribo-film on wear resistance of additive manufactured cobalt-based alloys during the sliding process [J]. Surf. Coat. Technol., 2021, 427: 127784 doi: 10.1016/j.surfcoat.2021.127784
[23]	Ura-Bińczyk E. Effect of grain refinement on the corrosion resistance of 316L stainless steel [J]. Materials, 2021, 14: 7517 doi: 10.3390/ma14247517
[24]	Chen H, Bettayeb M, Maurice V, et al. Local passivation of metals at grain boundaries: In situ scanning tunneling microscopy study on copper [J]. Corros. Sci., 2016, 111: 659 doi: 10.1016/j.corsci.2016.04.013
[25]	Tian H Y, Wang J, Liu Z Q, et al. Effect of nitrogen on the corrosion resistance of 6Mo super austenitic stainless steel [J]. Metals, 2024, 14: 391 doi: 10.3390/met14040391
[26]	Ha H Y, Lee T H, Kim S J. Synergistic effect of Ni and N on improvement of pitting corrosion resistance of high nitrogen stainless steels [J]. Corros. Eng. Sci. Technol., 2014, 49: 82 doi: 10.1179/1743278213Y.0000000138
[27]	Gao F Y, Qiao Y X, Chen J, et al. Effect of nitrogen content on corrosion behavior of high-nitrogen austenitic stainless steel [J]. npj Mater. Degrad., 2023, 7: 75 doi: 10.1038/s41529-023-00394-x
[28]	Loable C, Viçosa I N, Mesquita T J, et al. Synergy between molybdenum and nitrogen on the pitting corrosion and passive film resistance of austenitic stainless steels as a pH-dependent effect [J]. Mater. Chem. Phys., 2017, 186: 237 doi: 10.1016/j.matchemphys.2016.10.049
[29]	Obadele B A, Andrews A, Shongwe M B, et al. Tribocorrosion behaviours of AISI 310 and AISI 316 austenitic stainless steels in 3.5%NaCl solution [J]. Mater. Chem. Phys., 2016, 171: 239 doi: 10.1016/j.matchemphys.2016.01.013
[30]	Huttunen-Saarivirta E, Kilpi L, Hakala T J, et al. Tribocorrosion study of martensitic and austenitic stainless steels in 0.01 M NaCl solution [J]. Tribol. Int., 2016, 95: 358 doi: 10.1016/j.triboint.2015.11.046
[31]	Wang J, Zhao P P, Wang C T, et al. Synergistic tribo-corrosion behavior of TC4 alloy in artificial seawater containing sulfur ions [J]. J. Chin. Soc. Corros. Prot., 2025, 45: 1764
[31]	王杰, 赵平平, 王春婷等. TC4钛合金在含S²-海水中的腐蚀磨损行为研究 [J]. 中国腐蚀与防护学报, 2025, 45: 1764
[32]	Zhang B B, Wang J Z, Liu H, et al. Tribocorrosion properties of AISI 1045 and AISI 2205 steels in seawater: Synergistic interactions of wear and corrosion [J]. Friction, 2021, 9: 929 doi: 10.1007/s40544-020-0376-1
[33]	Natarajan R, Palaniswamy N, Natesan M, et al. XPS analysis of passive film on stainless steel [J]. Open Corros. J., 2009, 2: 114 doi: 10.2174/1876503300902010114
[34]	Hermas A A. XPS analysis of the passive film formed on austenitic stainless steel coated with conductive polymer [J]. Corros. Sci., 2008, 50: 2498 doi: 10.1016/j.corsci.2008.06.019
[35]	Olsson C O A, Landolt D. Passive films on stainless steels—chemistry, structure and growth [J]. Electrochim. Acta, 2003, 48: 1093 doi: 10.1016/S0013-4686(02)00841-1
[36]	De Oliveira M M, Costa H L, Silva W M, et al. Effect of iron oxide debris on the reciprocating sliding wear of tool steels [J]. Wear, 2019, 426-427: 1065 doi: 10.1016/j.wear.2018.12.047
[37]	Zou J Y, Wang Z W, Ma Y L, et al. Tribocorrosion behavior and degradation mechanism of 316L stainless steel in alkaline solution: Effect of tribo-film [J]. Acta Metall. Sin. (Engl. Lett.), 2022, 35: 1365 doi: 10.1007/s40195-022-01374-x
[38]	Watson S W, Friedersdorf F J, Madsen B W, et al. Methods of measuring wear-corrosion synergism [J]. Wear, 1995, 181-183: 476 doi: 10.1016/0043-1648(94)07108-X
[39]	Cao F Y, Wang H Q, Ji Q, et al. Tribo-corrosion performance of atmospheric plasma sprayed FeCoCrNiMn high entropy alloy coatings [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 1529
[39]	曹甫洋, 王浩权, 季谦等. 大气等离子喷涂FeCoCrNiMn高熵合金涂层的耐海水腐蚀与磨损性能 [J]. 中国腐蚀与防护学报, 2024, 44: 1529 doi: 10.11902/1005.4537.2024.060

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