镍基单晶高温合金<strong>N5</strong>及其纳米晶涂层的短期热腐蚀行为研究

doi:10.11902/1005.4537.2025.104

中国腐蚀与防护学报

2026, Vol. 46

Issue (1): 252-260 CSTR: 32134.14.1005.4537.2025.104 DOI: 10.11902/1005.4537.2025.104

研究报告

本期目录 | 过刊浏览

镍基单晶高温合金N5及其纳米晶涂层的短期热腐蚀行为研究

杨潇文, 陈泽浩, 杨莎莎, 王群昌, 王金龙(

), 陈明辉, 王福会

东北大学腐蚀与防护中心沈阳 110819

Short-term Hot Corrosion Behavior of Nickel-based Single Crystal Superalloy N5 and its Nanocrystalline Coating

YANG Xiaowen, CHEN Zehao, YANG Shasha, WANG Qunchang, WANG Jinlong(

), CHEN Minghui, WANG Fuhui

State Key Laboratory of Digital Steel, Northeastern University, Shenyang 110819, China

引用本文:

杨潇文, 陈泽浩, 杨莎莎, 王群昌, 王金龙, 陈明辉, 王福会. 镍基单晶高温合金N5及其纳米晶涂层的短期热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2026, 46(1): 252-260.
Xiaowen YANG, Zehao CHEN, Shasha YANG, Qunchang WANG, Jinlong WANG, Minghui CHEN, Fuhui WANG. Short-term Hot Corrosion Behavior of Nickel-based Single Crystal Superalloy N5 and its Nanocrystalline Coating[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(1): 252-260.

全文: PDF(19618 KB) HTML

摘要:

采用磁控溅射技术在高温合金N5表面制备与其化学成分相同的纳米晶涂层，并添加0.5% (质量分数) Y对涂层进行成分调控，研究其在850 ℃、75%Na₂SO₄ + 25%K₂SO₄和900 ℃、75%Na₂SO₄ + 25%NaCl (均为质量分数)两种熔盐环境下的短期热腐蚀行为。结果表明，N5合金在两种熔盐下均表现出较差的耐腐蚀性。纳米晶涂层在熔融硫酸盐中表现出优异的耐腐蚀性能，但在含NaCl环境中对耐腐蚀性能的提升并不明显。腐蚀5 h后，涂层表面氧化膜剥落，涂层发生内腐蚀。添加活性元素Y未对其在含NaCl环境中的耐蚀性能起到有效改善作用，进一步对纳米晶涂层在1000 ℃预氧化20 h能显著提高其耐腐蚀性能，一定厚度的预制氧化膜能有效阻挡熔盐渗透，降低腐蚀速率。

关键词 ：高温合金, 纳米晶涂层, 热腐蚀, 预氧化, 腐蚀行为

Abstract：

The nanocrystalline coatings of Ni-based single crystal superalloy N5 with and without addition of 0.5%(mass fraction) Y were prepared on the superalloy N5 by magnetron sputtering technology, and then their short-term hot corrosion behavior was studied beneath deposit films of 75%Na₂SO₄ + 25% K₂SO₄ at 850 ^oC, and 75%Na₂SO₄ + 25%NaCl (in mass fraction) at 900 ^oC in air. The results showed that the bare N5 exhibited poor corrosion resistance. Although, the N5 alloy with nanocrystalline coatings showed excellent corrosion resistance to the mixed salts, but, the enhanced corrosion resistance to the NaCl containing salts was not obvious for the N5 nanocrystalline coating and the Y-modified ones. Besides, scale spallation and internal corrosion occurred for the coatings after 5 h corrosion test. The corrosion resistance of nanocrystalline coatings can be significantly improved by proper pre-oxidation at 1000 ^oC for 20 h, the pre-formed oxide scale was able to suppress the attack of the molten salts to certain extent and thus delay the corrosion.

Key words： superalloy nanocrystalline coating hot corrosion pre-oxidation corrosion behavior

收稿日期: 2025-03-30 32134.14.1005.4537.2025.104

ZTFLH:

TG174

通讯作者: 王金龙，E-mail：Wangjinlong@mail.neu.edu.cn，研究方向为高温腐蚀与防护

作者简介: 杨潇文，男，1996年生，博士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	杨潇文
	陈泽浩
	杨莎莎
	王群昌
	王金龙
	陈明辉
	王福会
44.8K

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2025.104 或 https://www.jcscp.org/CN/Y2026/V46/I1/252

图1 沉积态纳米晶(SN)涂层的断面、截面形貌和相组成

表1 图1b中蓝色数字标示区域WDS结果 (mass fraction / %)

图2 N5合金及纳米晶涂层在熔融混合硫酸盐中热腐蚀后的动力学曲线

图3 N5合金及SN涂层在熔融混合硫酸盐中热腐蚀60 h后的表面XRD图谱

图4 N5合金及SN涂层在熔融混合硫酸盐中热腐蚀60 h后的微观表面形貌及对应的EDS成分分析结果

图5 N5合金及SN涂层在熔融混合硫酸盐中热腐蚀60 h后的截面形貌及对应的EDS线扫描图像

图6 N5合金及SN涂层热腐蚀5 h后的XRD图谱

图7 N5合金及SN涂层热腐蚀5 h后的微观形貌

表2 图7和11中各点EDS结果 (atomic fraction / %)

图8 Y改性的纳米晶涂层在1000 ℃预氧化1和20 h后的微观截面

图9 SNY涂层热腐蚀后的宏观照片

图10 SNY涂层热腐蚀后的XRD图谱

图11 SNY及其预氧化的涂层热腐蚀后的微观形貌

[1]	Eliaz N, Shemesh G, Latanision R M. Hot corrosion in gas turbine components [J]. Eng. Fail. Anal., 2002, 9: 31 doi: 10.1016/S1350-6307(00)00035-2
[2]	Hu S S, Finklea H, Liu X B. A review on molten sulfate salts induced hot corrosion [J]. J. Mater. Sci. Technol., 2021, 90: 243 doi: 10.1016/j.jmst.2021.03.013
[3]	Zhang J L, Fu G Y, Ning L K, et al. Hot corrosion behavior of a nickel based single crystal high temperature alloy subjected to different heat treatments [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 1625
[3]	张金龙, 付广艳, 宁礼奎等. 两种热处理状态的镍基单晶高温合金在900 ℃下(Na₂SO₄ + NaCl)混合盐中热腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2024, 44: 1625 doi: 10.11902/1005.4537.2024.027
[4]	Shang J, Gu Y, Zhao J, et al. Corrosion behavior in molten salts at 850 ^oC and its effect on mechanical properties of Hastelloy X alloy fabricated by additive manufacturing [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 671
[4]	尚进, 古岩, 赵京等. 增材制造Hastelloy X合金在850 ℃混合硫酸盐中热腐蚀行为及其对力学性能的影响 [J]. 中国腐蚀与防护学报, 2023, 43: 671
[5]	Montero X, Ishida A, Meißner T M, et al. Effect of surface treatment and crystal orientation on hot corrosion of a Ni-based single-crystal superalloy [J]. Corros. Sci., 2020, 166: 108472 doi: 10.1016/j.corsci.2020.108472
[6]	Song P, Liu M F, Jiang X W, et al. Influence of alloying elements on hot corrosion resistance of nickel-based single crystal superalloys coated with Na₂SO₄ salt at 900 ^oC [J]. Mater. Des., 2021, 197: 109197 doi: 10.1016/j.matdes.2020.109197
[7]	Gurrappa I. Hot corrosion behavior of CM 247 LC alloy in Na₂SO₄ and NaCl environments [J]. Oxid. Met., 1999, 51: 353 doi: 10.1023/A:1018831025272
[8]	Cui T C, Leng W C, Zhou D P, et al. Improved hot corrosion resistance of Al-gradient NiSiAlY coatings at 750 ^oC by pre-oxidation [J]. Surf. Coat. Technol., 2021, 417: 127187 doi: 10.1016/j.surfcoat.2021.127187
[9]	Sun Y, Li Z B, Ma L W, et al. Research progress on corrosion failure of high-temperature coatings in aero-engines [J]. Therm. Spray Technol., 2024, 16(2): 1 doi: 10.1007/s11666-007-9016-9
[9]	孙毅, 李宗宝, 马菱薇等. 航空发动机高温涂层腐蚀失效研究进展 [J]. 热喷涂技术, 2024, 16(2): 1
[10]	Wang K, Zou L X, Guo L, et al. High-temperature corrosion and protection of thermal barrier coatings for aeroengines and gas turbines [J]. J. Chin. Soc. Corros. Prot., 2025, 45: 1
[10]	王昆, 邹兰欣, 郭磊等. 航空发动机及燃气轮机热障涂层高温腐蚀与防护 [J]. 中国腐蚀与防护学报, 2025, 45: 1
[11]	Li F G, Yang L, Zhou Y C. Study advances of high temperature coating for aeroengine to resist marine atmospheric corrosion [J]. Therm. Spray Technol., 2019, 11(4): 1
[11]	李发国, 杨丽, 周益春. 航空发动机高温涂层耐海洋大气腐蚀研究进展 [J]. 热喷涂技术, 2019, 11(4): 1
[12]	Fu Q F, Yang X L, Liu K M. Current status of research and prospect of high temperature materials for aeroengine [J]. Heat Treat. Technol. Equip., 2018, 39(3): 69
[12]	付青峰, 杨细莲, 刘克明. 航空发动机高温材料的研究现状及展望 [J]. 热处理技术与装备, 2018, 39(3): 69
[13]	Li M, Cheng Y X. Progress in research on high temperature protective coatings for aero-engines [J]. Chin. Surf. Eng., 2012, 25(1): 16
[13]	李民, 程玉贤. 航空发动机用高温防护涂层研究进展 [J]. 中国表面工程, 2012, 25(1): 16
[14]	Zhang L D, Long X Q. High-temperature oxidative corrosion and prevention of aeroengine [J]. Total Corros. Control, 2002, 16(3): 3
[14]	张良栋, 隆小庆. 航空发动机高温氧化腐蚀与保护 [J]. 全面腐蚀控制, 2002, 16(3): 3
[15]	Lou H Y, Wang F H, Xia B J, et al. High-temperature oxidation resistance of sputtered micro-grain superalloy K38G [J]. Oxid. Met., 1992, 38: 299 doi: 10.1007/BF00666917
[16]	Lou H Y, Tang Y J, Sun X F, et al. Oxidation behavior of sputtered microcrystalline coating of superalloy K17F at high temperature [J]. Mater. Sci. Eng., 1996, 207A: 121
[17]	Shi L, Xin L, Wang F H, et al. Oxidation behavior of sputtered DD98M nanocrystalline coating at 1000 ^oC [J]. Oxid. Met., 2016, 86: 263 doi: 10.1007/s11085-016-9635-y
[18]	Chen G, Lou H. Oxidation behavior of sputtered Ni-Cr-Al-Ti nanocrystalline coating [J]. Surf. Coat. Technol., 2000, 123: 92 doi: 10.1016/S0257-8972(99)00470-3
[19]	Wang J L, Chen M H, Zhu S L, et al. Ta effect on oxidation of a nickel-based single-crystal superalloy and its sputtered nanocrystalline coating at 900-1100 ^oC [J]. Appl. Surf. Sci., 2015, 345: 194 doi: 10.1016/j.apsusc.2015.03.157
[20]	Wang J L, Chen M H, Yang L L, et al. Nanocrystalline coatings on superalloys against high temperature oxidation: A review [J]. Corros. Commun., 2021, 1: 58
[21]	Simons E L, Browning G V, Liebhafsky H A. Sodium sulfate in gas turbines [J]. Corrosion, 1955, 11: 17
[22]	Stringer J. High-temperature corrosion of superalloys [J]. Mater. Sci. Technol., 1987, 3: 482 doi: 10.1080/02670836.1987.11782259
[23]	Geng S, Wang F, Zhu S, et al. Hot-corrosion resistance of a sputtered K38G nanocrystalline coating in molten sulfate at 900 ^oC [J]. Oxid. Met., 2002, 57: 549 doi: 10.1023/A:1015356522798
[24]	Wang H Y, Zuo D W, Chen G, et al. Hot corrosion behaviour of low Al NiCoCrAlY cladded coatings reinforced by nano-particles on a Ni-base super alloy [J]. Corros. Sci., 2010, 52: 3561 doi: 10.1016/j.corsci.2010.07.011
[25]	Singh H, Puri D, Prakash S, et al. Hot corrosion of a plasma sprayed Ni₃Al coating on a Ni‐base superalloy [J]. Mater. Corros., 2007, 58: 857
[26]	Yang L L, Chen M H, Wang J L, et al. Diffusion of Ta and its influence on oxidation behavior of nanocrystalline coatings with different Ta, Y and Al contents [J]. Corros. Sci., 2017, 126: 344 doi: 10.1016/j.corsci.2017.07.017
[27]	Chen L C, Zhang C, Yang Z G. Effect of pre-oxidation on the hot corrosion of CoNiCrAlYRe alloy [J]. Corros. Sci., 2011, 53: 374 doi: 10.1016/j.corsci.2010.09.045
[28]	Wang L, Liu C Y, Han Z Y, et al. Hot corrosion behavior and evaluation of turbine components and materials used for gas turbine engine [J]. J. Chin. Soc. Corros. Prot., 2011, 31: 399
[28]	王理, 刘春阳, 韩振宇等. 燃气轮机涡轮零部件及材料热腐蚀行为与评价方法研究 [J]. 中国腐蚀与防护学报, 2011, 31: 399
[29]	Wu D L, Zhang H Y, Wei H, et al. Hot corrosion behavior of four modified aluminide coatings on DZ38G alloy [J]. J. Chin. Soc. Corros. Prot., 2014, 34: 502
[29]	吴多利, 张洪宇, 韦华等. 4种改性的铝化物涂层对DZ38G合金热腐蚀性能的影响 [J]. 中国腐蚀与防护学报, 2014, 34: 502 doi: 10.11902/1005.4537.2013.232
[30]	Gesmundo F, Viani F, Niu Y, et al. The transition from the formation of mixed scales to the selective oxidation of the most-reactive component in the corrosion of single and two-phase binary alloys [J]. Oxid. Met., 1993, 40: 373 doi: 10.1007/BF00664498

[1]	戴念维, 窦欣懿, 刘华剑, 冷滨. 增材制造合金在核能领域应用中的腐蚀研究进展[J]. 中国腐蚀与防护学报, 2026, 46(1): 15-24.
[2]	周小包, 王子腾, 任延杰, 董少阳, 甘浪, 李聪. 激光粉末床熔融成形CoCrNi中熵合金的高温热腐蚀行为[J]. 中国腐蚀与防护学报, 2026, 46(1): 115-125.
[3]	叶俊, 罗鑫, 镇咸生, 李新平, 谢云, 彭晓. Inconel 718合金在750 ℃下不同气氛中的氧化与热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(6): 1528-1536.
[4]	彭望, 陈荐, 杨凌旭, 刘会军, 梁建平, 曾潮流. NaCl对347H和GH3539在熔融硝酸盐中热腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(6): 1610-1618.
[5]	白英雄, 王艳丽, 李相伟, 吴泽峰, 张书彦. 热处理对激光选区熔化GH4099镍基高温合金900 ℃下(75%Na₂SO₄ + 25%NaCl)热腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(6): 1709-1716.
[6]	蔡科涛, 季磊, 张震, 冯强, 邓伟林, 兰贵红, 何莎, 赵占勇, 白培康. Mg-Gd-Y-Zn-Zr合金在NaCl和Na₂SO₄ 溶液中腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(5): 1289-1299.
[7]	谷松伦, 张繁, 黄国胜, 姜丹, 董国君. 冷喷涂Cu-Ti伪合金防污材料的腐蚀行为[J]. 中国腐蚀与防护学报, 2025, 45(5): 1309-1319.
[8]	赵欣宇, 刘恩泽, 张功, 赵媛, 宁礼奎, 信昕, 贾丹, 刘伟华, 谭政. 不同温度下DD10合金钎焊接头热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(5): 1361-1370.
[9]	范世林, 杜娟, 杨少丹, 周延军, 宋克兴, 张国赏, 岳鹏飞, 杨冉, 王晓军. Cu-15Ni-8Sn合金在含S^2- 的3.5%NaCl溶液中的腐蚀行为[J]. 中国腐蚀与防护学报, 2025, 45(5): 1408-1416.
[10]	段敬民, 董勇, 缪东美, 杨玉婧, 毛凌波, 章争荣. 热处理工艺对Al_0.5CoCrFeNi高熵合金在不同介质下腐蚀行为及力学性能的影响[J]. 中国腐蚀与防护学报, 2025, 45(4): 983-994.
[11]	张珊珊, 刘元才, 徐铁伟, 杨发展. 成型方向及热处理对选区激光熔化Ti6Al4V合金腐蚀性能的影响[J]. 中国腐蚀与防护学报, 2025, 45(4): 995-1004.
[12]	翟熙伟, 刘士一, 王丽, 贾瑞灵, 张慧霞. 载荷对5383铝合金焊接接头电化学腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2025, 45(2): 515-522.
[13]	张勇康, 翟海民, 李旭强, 李文生. Fe基非晶涂层在Na₂SO₄ + K₂SO₄ 和Na₂SO₄ +NaCl混合盐中的热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(1): 92-102.
[14]	黄勤英, 李彧卓, 阳颖飞, 任盼, 王启伟. Pt改性共晶高熵合金AlCoCrFeNi_2.1 热腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(1): 115-126.
[15]	王粤, 耿树江, 王金龙, 王福会, 孙清云, 吴勇, 夏思瑶. K444合金表面CVD渗铝涂层耐高温95%Na₂SO₄ + 5%NaCl腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(1): 127-136.

Viewed

Full text

Abstract

Cited

Shared

Discussed