Si含量对四元Fe-20Ni-20Cr-ySi合金在900℃下氧化行为的影响

doi:10.11902/1005.4537.2023.037

中国腐蚀与防护学报

2024, Vol. 44

Issue (1): 100-106 CSTR: 32134.14.1005.4537.2023.037 DOI: 10.11902/1005.4537.2023.037

研究报告

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Si含量对四元Fe-20Ni-20Cr-ySi合金在900℃下氧化行为的影响

冯抗抗, 任延杰(

), 吕云蕾, 周梦妮, 陈荐, 牛焱(

)

长沙理工大学能源与动力工程学院长沙 410076

Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900^oC

FENG Kangkang, REN Yanjie(

), LV Yunlei, ZHOU Mengni, CHEN Jian, NIU Yan(

)

Department of Energy and Power Engineering, Changsha University of Science and Technology, Changsha 410076, China

引用本文:

冯抗抗, 任延杰, 吕云蕾, 周梦妮, 陈荐, 牛焱. Si含量对四元Fe-20Ni-20Cr-ySi合金在900℃下氧化行为的影响[J]. 中国腐蚀与防护学报, 2024, 44(1): 100-106.
Kangkang FENG, Yanjie REN, Yunlei LV, Mengni ZHOU, Jian CHEN, Yan NIU. Effect of Si Content on Oxidation Behavior of Quaternary Fe-20Ni-20Cr- ySi Alloys in Oxygen at 900^oC[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 100-106.

全文: PDF(8052 KB) HTML

摘要:

研究了Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5，质量分数，%)合金在纯氧中900℃下的氧化行为。三元Fe-20Ni-20Cr合金在氧化后表面生成了复杂的氧化膜，氧化膜对合金保护作用较差。Si含量从1%增加至3%，发生了Si从内氧化到外氧化的转变，添加Si显著提高了Fe-20Ni-20Cr合金的抗氧化性能。其中，Fe-20Ni-20Cr-3Si和Fe-20Ni-20Cr-5Si均在Cr₂O₃层/合金界面形成了连续的非晶态SiO₂层，阻止了Fe、Ni和Cr的向外和氧的向内扩散的作用。4种合金中，Fe-20Ni-20Cr-3Si具有最优的抗氧化性能。

关键词 ： Fe-Ni-Cr-Si合金, 硅, 高温氧化, 氧化动力学

Abstract：

The oxidation behavior of Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, mass fraction, %) alloys were studied in 1 atm O₂ at 900^oC for 24 h. After oxidation, Fe-20Ni-20Cr alloy without Si addition formed a complex oxide scale on the surface with poor protectiveness. When the Si content increased from 1% to 3%, a transition from internal to external oxidation of Si occurred. Therefore, additions of Si can significantly improve the oxidation resistance of the austenitic Fe-20Ni-20Cr alloy. Both Fe-20Ni-20Cr-3Si and Fe-20Ni-20Cr-5Si formed an amorphous SiO₂ layer on the Cr₂O₃/alloy interface, and this continuous amorphous SiO₂ layer provided an effective barrier to prevent the outward diffusion of Fe, Ni and Cr, as well as the inward migration of oxygen. A comparison of the oxidation behavior of alloys with different Si contents indicated that Fe-20Ni-20Cr-3Si has the most excellent oxidation resistance properties.

Key words： Fe-Ni-Cr-Si alloy silicon high temperature oxidation oxidation kinetics

收稿日期: 2023-02-19 32134.14.1005.4537.2023.037

ZTFLH:

TG172

基金资助:国家自然科学基金(52171066)

通讯作者: 任延杰，E-mail: yjren@csust.edu.cn，研究方向为动力设备的腐蚀与防护领域的研究
牛焱，E-mail: yniu@csust.edu.cn，研究方向为金属的高温腐蚀与防护研究

Corresponding author: REN Yanjie, E-mail: yjren@csust.edu.cn
NIU Yan, yniu@csust.edu.cn

作者简介: 冯抗抗，男，1996年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2023.037 或 https://www.jcscp.org/CN/Y2024/V44/I1/100

表1 Fe-20Ni-20Cr-ySi (y=0, 1, 3,5, %)合金的设计成分和由ICP光谱技术测得的实际成分

图1 Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, %)合金在900℃下1 atm O2中氧化24 h的动力学曲线

表2 Fe-20Ni-20Cr-ySi (y = 0, 1, 3, 5, %)合金在900℃下1 atm O2 中氧化动力学拟合的抛物线速率常数

图2 Fe-20Ni-20Cr合金在900℃下1 atm O2中氧化24 h的SEM/BEI截面形貌和相应的EDS元素分布

图3 Fe-20Ni-20Cr-1Si合金在900℃下1atm O2中氧化24 h的SEM/BEI截面形貌和相应的EDS元素分布

图4 Fe-20Ni-20Cr-3Si合金在900℃下1 atm O2中氧化24 h的SEM/BEI截面形貌和相应的EDS元素分布

图5 Fe-20Ni-20Cr-5Si合金在900℃下1 atm O2中氧化24 h的 SEM/BEI截面形貌

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