四元MAX相(Cr2/3Ti1/3)3AlC2 在高温空气以及水蒸气气氛中的氧化行为研究

doi:10.11902/1005.4537.2022.407

中国腐蚀与防护学报

2023, Vol. 43

Issue (6): 1284-1292 CSTR: 32134.14.1005.4537.2022.407 DOI: 10.11902/1005.4537.2022.407

研究报告

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四元MAX相(Cr_2/3Ti_1/3)₃AlC₂ 在高温空气以及水蒸气气氛中的氧化行为研究

任岩¹(

), 张鑫涛²^,³, 盖欣¹, 徐敬军², 张伟¹, 陈勇¹, 李美栓²

^1.中国核动力研究设计院反应堆燃料及材料重点实验室成都 610213
^2.中国科学院金属研究所沈阳材料科学国家研究中心沈阳 110016
^3.中国科学技术大学材料科学与工程学院沈阳 110016

High Temperature Oxidation Behavior of Quaternary (Cr_2/3Ti_1/3)₃AlC₂ MAX Ceramic in Air and Steam

REN Yan¹(

), ZHANG Xintao²^,³, GAI Xin¹, XU Jingjun², ZHANG Wei¹, CHEN Yong¹, LI Meishuan²

^1.Science and Technology on Reactor Fuel and Materials Laboratory, Nuclear Power Institute of China, Chengdu 610213, China
^2.Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
^3.School of Materials Science and Engineering, University of Science and Technology of China, Shenyang 110016, China

引用本文:

任岩, 张鑫涛, 盖欣, 徐敬军, 张伟, 陈勇, 李美栓. 四元MAX相(Cr_2/3Ti_1/3)₃AlC₂ 在高温空气以及水蒸气气氛中的氧化行为研究[J]. 中国腐蚀与防护学报, 2023, 43(6): 1284-1292.
Yan REN, Xintao ZHANG, Xin GAI, Jingjun XU, Wei ZHANG, Yong CHEN, Meishuan LI. High Temperature Oxidation Behavior of Quaternary (Cr_2/3Ti_1/3)₃AlC₂ MAX Ceramic in Air and Steam[J]. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1284-1292.

全文: PDF(18418 KB) HTML

摘要:

采用恒温氧化法研究了四元MAX相(Cr_2/3Ti_1/3)₃AlC₂在高温空气以及水蒸气气氛中的氧化行为。(Cr_2/3Ti_1/3)₃AlC₂在800~1200 ℃下空气中以及1000~1200 ℃下水蒸气中氧化后表面均形成包含Al₂O₃、TiO₂和Cr₂O₃的氧化膜，使其具有良好的抗高温氧化性能。(Cr_2/3Ti_1/3)₃AlC₂在1200 ℃下空气/水蒸气中氧化生成由外到内分别为富Ti层、富Cr层和富Al层的氧化膜，该氧化膜的形成与(Cr_2/3Ti_1/3)₃AlC₂中元素的选择性氧化和扩散有关。研究结果表明，(Cr_2/3Ti_1/3)₃AlC₂在高温空气/水蒸气中均表现出良好的抗氧化性能。

关键词 ： MAX相, 高温氧化, 核反应堆

Abstract：

The oxidation behavior of quaternary (Cr_2/3Ti_1/3)₃AlC₂ MAX ceramic at high temperatures in air and steam was investigated by isothermal oxidation test. The good oxidation resistance of (Cr_2/3Ti_1/3)₃AlC₂ at 800-1200 ℃ in air and at 1000-1200 ℃ in steam may be ascribed to the oxide scale with Al₂O₃, TiO₂ and Cr₂O₃ formed on the surface of (Cr_2/3Ti_1/3)₃AlC₂ during oxidation. An oxide scale with external Ti-rich layer, intermediate Cr-rich layer and internal Al-rich layer was formed on the surface of (Cr_2/3Ti_1/3)₃AlC₂ during oxidation at 1200 ℃ in air/steam. The structure of the oxide scale was affected by the selective oxidation and diffusion of elements in (Cr_2/3Ti_1/3)₃AlC₂. The results indicate that (Cr_2/3Ti_1/3)₃AlC₂ exhibit good oxidation resistance in high temperature air/steam.

Key words： MAX phase high temperature oxidation nuclear reactor

收稿日期: 2022-12-23 32134.14.1005.4537.2022.407

ZTFLH:

TB321

基金资助:国防科技重点实验室基金-稳定支持(6142A06030107)

通讯作者: 任岩，E-mail: yren2021@qq.com，研究方向为高温结构材料及防护涂层

Corresponding author: REN Yan, E-mail: yren2021@qq.com

作者简介: 任岩，男，1993年生，博士，助理研究员

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https://www.jcscp.org/CN/10.11902/1005.4537.2022.407 或 https://www.jcscp.org/CN/Y2023/V43/I6/1284

图1 (Cr2/3Ti1/3)3AlC2的表面宏观照片，XRD谱图和表面微观形貌

图2 (Cr2/3Ti1/3)3AlC2在800、1000和1200 ℃下空气中氧化后的表面宏观照片

图3 (Cr2/3Ti1/3)3AlC2在800、1000和1200 ℃下空气中氧化后的表面X射线衍射谱图

图4 (Cr2/3Ti1/3)3AlC2在800，1000和1200 ℃下空气中氧化后的表面微观形貌

图5 (Cr2/3Ti1/3)3AlC2在800 ℃下空气中氧化后的截面微观形貌及元素分布

图6 (Cr2/3Ti1/3)3AlC2在1000 ℃下空气中氧化后的截面微观形貌及元素分布

图7 (Cr2/3Ti1/3)3AlC2在1200 ℃下空气中氧化后的截面微观形貌及元素分布

图8 (Cr2/3Ti1/3)3AlC2在1000和1200 ℃下水蒸气中的氧化动力学曲线

图9 (Cr2/3Ti1/3)3AlC2在1000和1200 ℃下水蒸气中氧化后的表面宏观照片

图10 (Cr2/3Ti1/3)3AlC2在1000和1200 ℃下水蒸气中氧化后的表面X射线衍射谱图

图11 (Cr2/3Ti1/3)3AlC2在1000和1200 ℃下水蒸气中氧化后的表面微观形貌

表1 水蒸气中氧化后表面能谱分析结果 (atomic fraction / %)

图12 (Cr2/3Ti1/3)3AlC2在1000 ℃下水蒸气中氧化后的截面微观形貌及元素分布

图13 (Cr2/3Ti1/3)3AlC2在1200 ℃下水蒸气中氧化后的截面微观形貌及元素分布

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