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中国腐蚀与防护学报  2021, Vol. 41 Issue (1): 117-124    DOI: 10.11902/1005.4537.2020.035
  研究报告 本期目录 | 过刊浏览 |
镁合金表面超声滚压预处理对微弧氧化膜耐蚀性能的影响
魏征1,2, 马保吉1,2(), 李龙2, 刘潇枫1,2, 李慧3
1.西安工业大学机电工程学院 西安 710021
2.陕西省特种加工重点实验室 西安 710021
3.西安工业大学材料与化工学院 西安 710021
Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy
WEI Zheng1,2, MA Baoji1,2(), LI Long2, LIU Xiaofeng1,2, LI Hui3
1.School of Mechanical and Electrical Engineering, Xi'an Technological University, Xi'an 710021, China
2.Key Laboratory of Shaanxi Provincial Special Processing, Xi'an 710021, China
3.School of Materials Science and Chemical Engineering, Xi'an Technological University, Xi'an 710021, China
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摘要: 

镁合金基体首先进行超声滚压预处理后再进行微弧氧化镀膜,结合OM、SEM、EDS、XRD与电化学工作站 (模拟体液PBS) 对有无超声滚压处理的微弧氧化膜层性能进行测试分析,研究超声滚压处理对镁合金微弧氧化膜层性能的影响。结果表明:超声滚压处理后镁基体表面粗糙度降低、晶粒细化且硬度提升;与镁合金直接微弧氧化的膜层相比,超声滚压预处理之后再进行微弧氧化,膜层中的Si、P、Ca含量比例增大,膜层表面更为致密、光滑,大孔数量明显降低,表面孔隙率由31.7%降低至19.1%;从电化学测试结果看出,与直接微弧氧化的膜层相比超声滚压预处理后膜层的自腐蚀电位高出107 mV,腐蚀电流密度低了一个数量级,并且阻抗性能更优,镁合金超声滚压预处理可有效提升微弧氧化膜层在PBS溶液中的耐蚀性。

关键词 AZ31B镁合金超声滚压晶粒细化微弧氧化耐蚀    
Abstract

Though Mg-alloy can be used as a new generation of implant materials with good bio-compatibility and biodegradability, its corrosion rate should be reduced to an acceptable level for the application. For that, at the present, the most commonly measure is to apply a micro-arc oxidation coating on the alloy. However, the porosity of the micro-arc oxidation coating is too large, thereby corrosive species can easy migrate inward through the micro-pores, thus degrade its protective effect. Recently, some scholars have found that pretreatment of the metal matrix can increase the density of the micro-arc oxidation coating. So in this study, Mg-alloy was pretreated by ultrasonic rolling before the micro-arc oxidation. Then the prepared micro-arc oxide ceramic coatings on Mg-alloy with or without ultrasonic rolling treatment were comparatively assessed by means of OM, SEM, EDS, XRD, electrochemical workstation (simulated humoral PBS), to reveal the effect of ultrasonic rolling treatment on the properties of micro-arc oxide ceramic coating. Results show that: after ultrasonic rolling treatment, the treated Mg-alloy matrix presents lower surface roughness, finer grains and higher hardness. In comparison with the Micro-arc oxidation ceramic coating on the un-treated Mg-alloy, the element content of Si, P and Ca is increased in the coating on the pre-treated ones, correspondingly the surface was denser and smoother, and the number of macropores significantly decreased, namely, the surface porosity reduced from 31.7% to 19.1%. From electrochemical tests we can see that, the free corrosion potential was 107 mV higher, the corrosion current density was an order of magnitude lower, and the impedance is much higher for the micro-arc oxidation ceramic coating on Mg-alloy pre-treated by ultrasonic rolling. In conclusion, the pre-ultrasonic rolling treatment could effectively improve the corrosion resistance in PBS solution of the micro-arc oxidation ceramic coatings on Mg-alloy.

Key wordsAZ31B Mg-alloy    ultrasonic rolling    grain refinement    micro-arc oxidation    corrosion resistant
收稿日期: 2020-03-09     
ZTFLH:  TG174  
基金资助:陕西省重点研发计划(2018GY-120);陕西省特种加工重点实验室开放基金(2017SXTZKFJG02);陕西省教育厅重点;实验室科研计划(17JS056)
通讯作者: 马保吉     E-mail: mabaoji@xatu.edu.com
Corresponding author: MA Baoji     E-mail: mabaoji@xatu.edu.com
作者简介: 魏征,男,1994年生,硕士生

引用本文:

魏征, 马保吉, 李龙, 刘潇枫, 李慧. 镁合金表面超声滚压预处理对微弧氧化膜耐蚀性能的影响[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
Zheng WEI, Baoji MA, Long LI, Xiaofeng LIU, Hui LI. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy. Journal of Chinese Society for Corrosion and protection, 2021, 41(1): 117-124.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.035      或      https://www.jcscp.org/CN/Y2021/V41/I1/117

图1  超声滚压示意图
图2  超声滚压前后镁合金表面XRD谱
图3  超声滚压前后镁合金表面形貌
图4  超声滚压前后镁合金截面OM像
图5  超声滚压距表层不同深度TEM组织
图6  距表层不同深度截面显微硬度曲线
图7  UIRP+MAO与MAO膜层XRD谱图
图8  UIRP+MAO与MAO膜层表面SEM形貌、孔隙率分析和EDS分析
图9  UIRP+MAO与MAO膜层侧面形貌与元素分布图
图10  UIRP+MAO与MAO膜层极化性能分析
Fitting elementRs / Ω·cm2CPE1-T / F·cm2CPE1-PR1 / Ω·cm2CPE2-T / F·cm2CPE2-PR2 / Ω·cm2
UIRP+MAO8.5351.694×10-50.9503338.821.961×10-50.9623357636
MAO19.086.623×10-60.9126644.896.885×10-60.8489234634
表1  MAO与UIRP+MAO阻抗拟合结果
图11  UIRP+MAO与MAO膜层Nyquist图及拟合电路
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