304不锈钢双极板表面TiN涂层的腐蚀和导电行为研究

doi:10.11902/1005.4537.2016.149

中国腐蚀与防护学报

2017, Vol. 37

Issue (1): 63-68 DOI: 10.11902/1005.4537.2016.149

研究报告

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304不锈钢双极板表面TiN涂层的腐蚀和导电行为研究

沈杰¹,刘卫²,王铁钢³,潘太军^1,²(

)

1 常州大学材料科学与工程学院江苏省材料表面技术重点实验室常州 213164
2 中国科学院上海应用物理研究所上海 201800
3 天津职业技术师范大学天津市高速切削与精密加工重点实验室天津 300222

Corrosion and Conductivity Behavior of TiN Coating on 304 Stainless Steel Bipolar Plates

Jie SHEN¹,Wei LIU²,Tiegang WANG³,Taijun PAN^1,²(

)

1 School of Material Science and Engineering, Jiangsu Key Laboratory of Material Surface Technology, Changzhou University, Changzhou 213164, China
2 Shanghai Institute of Applied Physics, Chinese Academy of Science, Shanghai 201800, China
3 Tianjin Key Laboratory of High Speed Cutting and Precision Processing, Tianjin University of Technology and Education, Tianjin 300222, China

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摘要:

采用等离子喷涂技术在304不锈钢表面沉积TiN涂层,研究其在燃料电池环境中的腐蚀和导电性能。采用XRD和SEM对涂层组织结构和微观形貌进行了表征,通过动电位极化曲线、电化学阻抗谱技术比较了涂层与基体在模拟电池环境中 (0.3 mol/L H₂SO₄+2 mg/L HF) 的耐蚀性,并测定了接触电阻。结果表明：涂层的自腐蚀电位显著高于基体的,且腐蚀电流密度下降近1个数量级,这与所制备厚约20 μm涂层的均匀致密性有关。在360 h浸泡过程中,涂层的开路电位显著高于基体,稳定性良好,虽阻抗随时间有所降低,但仍维持较高值,涂层能够对基体提供有效保护。在138 Ncm^-2压力下,TiN涂层的接触电阻为50 mΩcm^-2,低于基体的,表现出更优越的导电性能。

关键词 ： 304不锈钢双极板, 等离子喷涂, TiN涂层, 耐蚀性

Abstract：

TiN coating was prepared on the surface of 304 stainless steel by plasma spraying technology. The microstructure and phase composition of the coating was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The corrosion performance of the 304 stainless steel without and with TiN coating was assessed by the potentiodynamic polarization and electrochemical impedance in the simulated proton exchange membrane fuel cell solutions containing 0.3 mol/L H₂SO₄ plus 2 mg/L HF. Moreover, electrical conductivity of them was also compared. The results indicated that TiN coating significantly increased the free corrosion potential of the steel and induced a decrease of the corresponding corrosion current density by one order of magnitude, which is attributed to the presence of the continuous and compact coating of about 20 μm in thickness. During the whole period of 360 h immersion, the open circuit potential of the coating was obviously higher than that of the bare substrate, suggesting the excellent stability of coating. The impedance of the coating decreased slightly with immersion time but still remained in high level, suggesting that the TiN coating could provide the effective protection for the substrate. The interface contact resistance of the TiN coating was about 50 mΩcm^-2 by an applied load of 138 Ncm^-2, obviously smaller than that of the bare 304 stainless steel, exhibiting better conductivity.

Key words： 30 stainless steel bipolar plate plasma spraying TiN coating corrosion resistance

收稿日期: 2016-09-09

基金资助:国家自然科学基金项目 (51101023和51301181),江苏省产学研项目 (BY2016029-07),常州市科技项目(CF20140004) 和天津市应用基础与前沿技术研究计划重点项目 (15JCZDJC39700)

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引用本文:

沈杰,刘卫,王铁钢,潘太军. 304不锈钢双极板表面TiN涂层的腐蚀和导电行为研究[J]. 中国腐蚀与防护学报, 2017, 37(1): 63-68.
Jie SHEN, Wei LIU, Tiegang WANG, Taijun PAN. Corrosion and Conductivity Behavior of TiN Coating on 304 Stainless Steel Bipolar Plates. Journal of Chinese Society for Corrosion and protection, 2017, 37(1): 63-68.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2016.149 或 https://www.jcscp.org/CN/Y2017/V37/I1/63

图1 等离子喷涂TiN涂层的XRD谱

图2 等离子喷涂TiN涂层的截面微观形貌

图3 TiN涂层与304不锈钢基体在模拟PEMFC环境中的极化曲线

表1 拟合获得的动电位极化曲线电化学参数

图4 TiN涂层与304不锈钢基体在模拟PEMFC环境中的开路电位-时间曲线

图5 304不锈钢基体在模拟PEMFC环境中浸泡不同时间的电化学阻抗谱

图6 304不锈钢和TiN涂层拟合电化学阻抗谱的等效电路图

表2 304不锈钢基体在模拟PEMFC环境中电化学阻抗谱参数拟合结果

图7 TiN涂层在模拟PEMFC环境中浸泡不同时间的电化学阻抗谱

表3 TiN涂层在模拟PEMFC环境中电化学阻抗谱参数拟合结果

图8 304不锈钢基体与TiN涂层的接触电阻随压力的变化

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