|
|
Atmospheric Corrosion Behavior of Mg-alloys AZ31B and AZ91D in Simulated Low Temperature Environments |
WU Yang1, AN Yiqiang2, WANG Liwei1, CUI Zhongyu2( ) |
1. College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 266071, China 2. School of Materials Science and Engineering, Ocean University of China, Qingdao 266404, China |
|
Cite this article:
WU Yang, AN Yiqiang, WANG Liwei, CUI Zhongyu. Atmospheric Corrosion Behavior of Mg-alloys AZ31B and AZ91D in Simulated Low Temperature Environments. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 1001-1010.
|
Abstract The atmospheric corrosion behavior of Mg-alloys AZ31B and AZ91D at alternating low temperatures was investigated via laboratory simulation i.e. a high/low temperature dry-humid alternating test chamber. The corrosion rate of the two alloys was positively correlated with temperature as the results acquired by the mass loss measurement. The morphology analysis showed that the two alloys exhibited obvious localized corrosion in the low temperature environment. Combined with corrosion rate and morphology observation (SEM, CLSM), it was found that AZ31B Mg-alloy was more seriously corroded than AZ91D Mg-alloy at the same temperature, but AZ91D Mg-alloy showed obvious pitting characteristics. The average pitting density and depth of AZ91D Mg-alloy were larger than that of AZ31B Mg-alloy, but the corresponding average pitting volume was smaller. FTIR and EDS analysis showed that Mg(OH)2, MgO and carbonates were the main components of the corrosion products formed at 15-25oC, while the content of MgOin the corrosion products was higher at lower alternating temperatures (from -5oC to -15°C and -5oC to -25°C). EDS results suggested that Aland Cl were present in the area where AZ91D Mg-alloy pitting was serious. It was considered that the destruction of the oxide scale by Cl- had an important influence on the pitting corrosion of AZ91D Mg-alloy.
|
Received: 12 January 2024
32134.14.1005.4537.2024.019
|
|
Fund: Shandong Provincial Excellent Youth Science Foundation(ZR2022YQ44);Basic Research Operating Expenses of the Central Universities(202241012);Basic Research Operating Expenses of the Central Universities(202262011);National Natural Science Foundation(52201098) |
Corresponding Authors:
CUI Zhongyu, E-mail: cuizhongyu@ouc.edu.cn
|
[1] |
Liu Z Q, He X X, Qi K, et al. Galvanic corrosion behavior for galvanic couple of AZ91D Mg-alloy/2002 Al-alloy in 0.5 mg/L NaCl solution [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 1016
|
|
刘泽琪, 何潇潇, 祁 康 等. AZ91D镁合金和2002铝合金在0.5 mg/L NaCl溶液中的电偶腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2022, 42: 1016
doi: 10.11902/1005.4537.2021.355
|
[2] |
Jia Y Z, Zhao M J, Cheng S J, et al. Corrosion behavior of Mg-Zn-Y-Nd alloy in simulated body fluid [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 463
|
|
郏义征, 赵明君, 程世婧 等. 模拟人体体液中镁合金的腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2019, 39: 463
doi: 10.11902/1005.4537.2019.050
|
[3] |
Yu H R, Zhang W L, Cui Z Y. Difference in corrosion behavior of four Mg-alloys in Cl--NH4 +-NO3 - containing solution [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 553
|
|
于浩冉, 张文丽, 崔中雨. 4种镁合金在Cl--NH4 +-NO3 -溶液体系中的腐蚀行为差异研究 [J]. 中国腐蚀与防护学报, 2020, 40: 553
doi: 10.11902/1005.4537.2019.250
|
[4] |
Merino M, Pardo A, Arrabal R, et al. Influence of chloride ion concentration and temperature on the corrosion of Mg–Al alloys in salt fog [J]. Corros. Sci., 2010, 52: 1696
|
[5] |
Lebozec N, Jonsson M, Thierry D. Atmospheric corrosion of magnesium alloys: influence of temperature, relative humidity, and chloride deposition [J]. Corrosion, 2004, 60: 356
|
[6] |
Lindström R, Svensson J E, Johansson L G. The atmospheric corrosion of zinc in the presence of NaCl the influence of carbon dioxide and temperature [J]. J. Electrochem. Soc., 2000, 147: 1751
|
[7] |
Blücher D B, Svensson J E, Johansson L G. The NaCl-induced atmospheric corrosion of aluminum: the influence of carbon dioxide and temperature [J]. J. Electrochem. Soc., 2003, 150: B93
|
[8] |
Chen J, Wang J Q, Han E H, et al. Effect of temperature on initial corrosion of AZ91 magnesium alloy under cyclic wet–dry conditions [J]. Corros. Eng. Sci. Technol., 2011, 46: 277
|
[9] |
Esmaily M, Blücher D B, Svensson J E, et al. New insights into the corrosion of magnesium alloys—The role of aluminum [J]. Scr. Mater., 2016, 115: 91
|
[10] |
Liao J S, Hotta M, Motoda S I, et al. Atmospheric corrosion of two field-exposed AZ31B magnesium alloys with different grain size [J]. Corros. Sci., 2013, 71: 53
|
[11] |
Shi X Z, Cui Z Y, Li J, et al. Atmospheric corrosion of AZ31B magnesium alloy in the Antarctic low-temperature environment [J]. Acta Metall. Sin. (Engl. Lett.), 2023, 36: 1421
|
[12] |
Cui Z Y, Ge F, Wang X. Corrosion mechanism of materials in three typical harsh marine atmospheric environments [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 403
|
|
崔中雨, 葛 峰, 王 昕. 几种苛刻海洋大气环境下的海工材料腐蚀机制 [J]. 中国腐蚀与防护学报, 2022, 42: 403
doi: 10.11902/1005.4537.2021.165
|
[13] |
Cui Z Y, Li X G, Xiao K, et al. Atmospheric corrosion of field-exposed AZ31 magnesium in a tropical marine environment [J]. Corros. Sci., 2013, 76: 243
|
[14] |
Man C, Dong C F, Wang L, et al. Long-term corrosion kinetics and mechanism of magnesium alloy AZ31 exposed to a dry tropical desert environment [J]. Corros. Sci., 2020, 163: 108274
|
[15] |
Lindgren M, Panas I. Confinement dependence of electro-catalysts for hydrogen evolution from water splitting [J]. Beilstein J. Nanotechnol., 2014, 5: 195
|
[16] |
Arrabal R, Matykina E, Pardo A, et al. Corrosion behaviour of AZ91D and AM50 magnesium alloys with Nd and Gd additions in humid environments [J]. Corros. Sci., 2012, 55: 351
|
[17] |
Jönsson M, Persson D, Thierry D. Corrosion product formation during NaCl induced atmospheric corrosion of magnesium alloy AZ91D [J]. Corros. Sci., 2007, 49: 1540
|
[18] |
Luo C, Wu X, Song H Q, et al. Analysis of application requirements and research directions of magnesium alloys for aircraft engines serving in marine environment [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 787
|
|
骆 晨, 吴 雄, 宋汉强 等. 海洋环境服役飞机发动机镁合金使用要求和研究方向分析 [J]. 中国腐蚀与防护学报, 2023, 43: 787
|
[19] |
Li S X, Khan H A, Hihara L H, et al. Corrosion behavior of friction stir blind riveted Al/CFRP and Mg/CFRP joints exposed to a marine environment [J]. Corros. Sci., 2018, 132: 300
|
[20] |
Arthanari S, Ananth A, Boo J H, et al. Protective performance of plasma-enhanced chemical vapor-deposited ethyl cyclohexane coating on magnesium alloys [J]. J. Mater. Eng. Perform., 2019, 28: 1360
|
[21] |
Feliu S, Llorente I. Corrosion product layers on magnesium alloys AZ31 and AZ61: surface chemistry and protective ability [J]. Appl. Surf. Sci., 2015, 347: 736
|
[22] |
Nordlien J H, Ono S, Masuko N, et al. A TEM investigation of naturally formed oxide films on pure magnesium [J]. Corros. Sci., 1997, 39: 1397
|
[23] |
Cabrera N, Mott N F. Theory of the oxidation of metals [J]. Rep. Prog. Phys., 1949, 12: 163
|
[24] |
Song G L, Atrens A. Corrosion mechanisms of magnesium alloys [J]. Adv. Eng. Mater., 1999, 1: 11
|
[25] |
Frankel G S. Pitting corrosion of metals: a review of the critical factors [J]. J. Electrochem. Soc., 1998, 145: 2186
|
No Suggested Reading articles found! |
|
|
Viewed |
|
|
|
Full text
|
|
|
|
|
Abstract
|
|
|
|
|
Cited |
|
|
|
|
|
Shared |
|
|
|
|
|
Discussed |
|
|
|
|