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Journal of Chinese Society for Corrosion and protection  2024, Vol. 44 Issue (4): 1001-1010    DOI: 10.11902/1005.4537.2024.019
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Atmospheric Corrosion Behavior of Mg-alloys AZ31B and AZ91D in Simulated Low Temperature Environments
WU Yang1, AN Yiqiang2, WANG Liwei1, CUI Zhongyu2()
1. College of Mechanical and Electrical Engineering, Qingdao University, Qingdao 266071, China
2. School of Materials Science and Engineering, Ocean University of China, Qingdao 266404, China
Cite this article: 

WU Yang, AN Yiqiang, WANG Liwei, CUI Zhongyu. Atmospheric Corrosion Behavior of Mg-alloys AZ31B and AZ91D in Simulated Low Temperature Environments. Journal of Chinese Society for Corrosion and protection, 2024, 44(4): 1001-1010.

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Abstract  

The atmospheric corrosion behavior of Mg-alloys AZ31B and AZ91D at alternating low temperatures was investigated via laboratory simulation i.e. a high/low temperature dry-humid alternating test chamber. The corrosion rate of the two alloys was positively correlated with temperature as the results acquired by the mass loss measurement. The morphology analysis showed that the two alloys exhibited obvious localized corrosion in the low temperature environment. Combined with corrosion rate and morphology observation (SEM, CLSM), it was found that AZ31B Mg-alloy was more seriously corroded than AZ91D Mg-alloy at the same temperature, but AZ91D Mg-alloy showed obvious pitting characteristics. The average pitting density and depth of AZ91D Mg-alloy were larger than that of AZ31B Mg-alloy, but the corresponding average pitting volume was smaller. FTIR and EDS analysis showed that Mg(OH)2, MgO and carbonates were the main components of the corrosion products formed at 15-25oC, while the content of MgOin the corrosion products was higher at lower alternating temperatures (from -5oC to -15°C and -5oC to -25°C). EDS results suggested that Aland Cl were present in the area where AZ91D Mg-alloy pitting was serious. It was considered that the destruction of the oxide scale by Cl- had an important influence on the pitting corrosion of AZ91D Mg-alloy.

Key words:  Mg-alloy      location corrosion      corrosion morphology      corrosion product      low temperature corrosion     
Received:  12 January 2024      32134.14.1005.4537.2024.019
ZTFLH:  TG172  
Fund: Shandong Provincial Excellent Youth Science Foundation(ZR2022YQ44);Basic Research Operating Expenses of the Central Universities(202241012);Basic Research Operating Expenses of the Central Universities(202262011);National Natural Science Foundation(52201098)
Corresponding Authors:  CUI Zhongyu, E-mail: cuizhongyu@ouc.edu.cn

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2024.019     OR     https://www.jcscp.org/EN/Y2024/V44/I4/1001

Fig.1  Variations of temperature and relative humidity inside the experimental box during the freezing-thawing experiment: (a) from 15oC to -25oC, (b) from -5oC to -15oC, (c) from -5oC to -25oC
Fig.2  Corrosion rate of AZ31B and AZ91D Mg-alloy under different alternating temperature conditions
Fig.3  Macroscopic morphology of AZ31B Mg-alloy under different alternating temperature conditions: (a) from 15oC to -25oC, (b) from -5oC to -15oC, (c) from -5oC to -25oC
Fig.4  Macroscopic morphology of AZ91D Mg-alloy under different alternating temperature conditions: (a) from 15oC to 25oC, (b) from -5oC to -15oC, (c) from -5oC to -25oC
Fig.5  SEM morphology before (a1-c1) and after (a2-c2) removing corrosion products of AZ31B Mg-alloy under different alternating temperature conditions: (a1, a2) from 15oC to 25oC, (b1, b2) from -5oC to -15oC, (c1, c2) from -5oC to -25oC
Fig.6  SEM morphology before (a1-c1) and after (a2-c2) removing corrosion products of AZ91D Mg-alloy under different alternating temperature conditions: (a1, a2) from 15oC to 25oC, (b1, b2) from -5oC to -15oC, (c1, c2) from -5oC to -25oC
Fig.7  CLSM morphology and pitting statistics results of AZ31B Mg-alloy under different alternating temperature conditions: (a1-a4) from 15oC to 25oC, (b1-b4) from -5oC to -15oC, (c1-c4) from -5oC to -25oC
Fig.8  CLSM morphology and pitting statistics results of AZ91D Mg-alloy under different alternating temperature conditions: (a1-a4) from 15oC to 25oC, (b1-b4) from -5oC to -15oC, (c1-c4) from -5oC to -25oC
Fig.9  FTIR pattern formed on the alloy surface under the alternating temperature of 15-25oC: (a) AZ31B Mg-alloy, (b) AZ91D Mg-alloy
Fig.10  Selected EDS points of AZ31B Mg-alloy under different alternating temperature conditions: (a1, a2) from 15oC to 25oC, (b1, b2) from -5oC to -15oC, (c1, c2) from -5oC to -25oC
ElementCOMgClNaAlAu
3.0439.8541.22---15.90
16.6828.7817.736.13--30.68
7.7125.7423.10---43.44
78.9711.982.17---6.89
3.0337.9630.3417.050.212.548.87
6.4942.5232.277.40--11.31
7.0743.8030.497.52-0.4010.71
Table 1  EDS analysis results of the corrosion products formed on AZ31B Mg-alloy under different conditions
Fig.11  Selected EDS points of AZ91D Mg-alloy under different alternating temperature conditions: (a1, a2) from 15oC to 25oC, (b1, b2) from -5oC to -15oC, (c1, c2) from -5oC to -25oC
ElementCOMgClNaAlAu
14.4913.7211.08-0.44-60.27
5.0613.6713.340.35-0.9166.67
3.9134.9826.5613.25-6.9014.41
3.1122.2027.3926.46-0.8420.00
2.0938.6940.855.90-3.858.61
8.6247.5026.984.62-3.688.60
7.4940.8939.464.42-0.906.86
10.7142.6527.1313.16-1.205.14
Table 2  EDS analysis results of the corrosion products formed on AZ91D Mg-alloy under different conditions
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