Effect of Temperature on Erosion-corrosion Behavior of B10 Cu-Ni Alloy Pipe

doi:10.11902/1005.4537.2022.387

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (6): 1329-1338 DOI: 10.11902/1005.4537.2022.387

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Effect of Temperature on Erosion-corrosion Behavior of B10 Cu-Ni Alloy Pipe

WANG Xiao¹, LI Ming¹, LIU Feng²(

), WANG Zhongping¹, LI Xiangbo², LI Ningwang¹

^1.CRRC Qingdao Sifang Co., Ltd., Qingdao 266111, China
^2.State Key Laboratory for Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266237, China

Cite this article:

WANG Xiao, LI Ming, LIU Feng, WANG Zhongping, LI Xiangbo, LI Ningwang. Effect of Temperature on Erosion-corrosion Behavior of B10 Cu-Ni Alloy Pipe. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1329-1338.

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Abstract

The corrosion behavior of B10 Cu-Ni alloy pipe in natural seawater at different temperatures was investigated via pipe flow test device capable of in-situ measurement designed independently by means of electrochemical impedance spectroscope (EIS) and other electrochemical methods, and the corrosion morphology and corrosion products composition were analyzed by scanning electron microscope (SEM) and X-ray photoelectron spectroscope (XPS). The results indicated that the corrosion product film on the surface of B10 pipe became denser with the decrease of temperature in the range of 10-50 ℃, leading to the increase of corrosion resistance of the film and the decrease of corrosion rate of the alloy. The corrosion behavior of B10 pipe in seawater would change with time and temperature. At 10, 25 and 35 ℃, the corrosion rate of B10 pipe gradually decreased with the extension of time, and the corrosion products were mainly Cu₂O, NiO and FeOOH, resulting in a better protective effect to the matrix. At 50 ℃, the corrosion products on the surface of B10 pipe were CuO, Ni and FeO, which presented poor protective effect to the substrate.

Key words: 90/10 copper-nickel pipe erosion-corrosion temperature real-time electrochemical testing corrosion product film

Received: 07 December 2022 32134.14.1005.4537.2022.387

ZTFLH:

TG174

Corresponding Authors: LIU Feng, E-mail: liufeng279@126.com

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	WANG Xiao
	LI Ming
	LIU Feng
	WANG Zhongping
	LI Xiangbo
	LI Ningwang

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.387 OR https://www.jcscp.org/EN/Y2023/V43/I6/1329

Fig.1 Schematic diagram of the loop test device

Fig.2 Surface morphologies of B10 pipe after erosion-corrosion at 10 ^oC (a-c), 25 ^oC (d-f), 35 ^oC (g-i) and 50 ^oC (j-l) for 1 d (a, d, g, j), 7 d (b, e, h, k) and 30 d (c, f, i, l)

Fig.3 Atomic fraction of O, Cu, Ni and Fe in the corrosion product films formed on B10 pipe after erosion-corrosion at 10 ℃ (a) and 50 ℃ (b) for 1 and 30 d

Fig.4 XPS fine peaks of Cu2p (a, d), Ni2p (b, e) and Fe2p (c, f) on the surfaces of B10 pipe after erosion-corrosion at 10 ℃ for 1 d (a-c) and 30 d (d-f)

Table 1 Fitting results of XPS fine peaks of B10 pipe after erosion-corrosion in seawater at 10 ℃ for 1 d and 30 d

Fig.5 XPS fine peaks of Cu2p (a, d), Ni2p (b, e) and Fe2p (c, f) on the surfaces of B10 pipe after erosion-corrosion at 50 ℃ for 1 d (a-c) and 30 d (d-f)

Table 2 Fitting results of XPS fine peaks of B10 pipe after erosion-corrosion in seawater at 50 ℃ for 1 and 30 d

Fig.6 Nyquist (a-d) and Bode (e-h) plots of B10 pipe after erosion-corrosion for different time at 10 ℃ (a, e), 25 ℃ (b, f), 35 ℃ (c, g) and 50 ℃ (d, h)

Fig.7 Equivalent circuit model for fitting EIS data of B10 pipe

Table 3 Fitting data of EIS of B10 pipe after erosion-corrosion at different temperatures for different time

Fig.8 Variations of R_ct (a) and R_f (b) of B10 pipe with time

Fig.9 OCP of B10 pipe after erosion-corrosion at different temperatures for different time

Fig.10 Schematic illustrations of corrosion processes of B10 pipe in the early days (a, d), mid-term (b, e) and late (c, f) of erosion-corrosion in seawater at 10 ℃ (a-c) and 50 ℃ (d-f)

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