IN-SITU  IMPEDANCE INVESTIGATION OF 304 STAINLESS STEEL BETWEEN PIT GROWTH AND REPASSIVATION STATE

J Chin Soc Corr Pro

2011, Vol. 31

Issue (2): 130-134 DOI:

Research Articles

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IN-SITU IMPEDANCE INVESTIGATION OF 304 STAINLESS STEEL BETWEEN PIT GROWTH AND REPASSIVATION STATE

ZHANG Shenghan, TAN Yu, LIANG Kexin

School of Environmental Science and Engineering, North China Electric Power University, Baoding 071003

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Abstract Pitting corrosion investigations of 304 stainless steel in 0.1 mol/L sodium chloride borate buffer solution have been investigated by dynamic electrochemical impedance spectroscopy (DEIS). The electric equivalent circuit of the classic double-layer structure has been proposed to evaluate the changes of EIS data. According to the fitting results, the outer-layer of passive film of 304 stainless steel is highly destroyed during pitting process and can not return to the original condition. However, during repassivation process the inner-layer can be repassivated entirely. An active controlled model of film breakdown was proposed to analysis the film between the pit initiation and repassivation states.

Key words: stainless steel DEIS pitting corrosion passive films

Received: 07 September 2010

ZTFLH:

TG174.36

Corresponding Authors: TAN Yu E-mail: lucifertan@163.com

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ZHANG Shenghan, TAN Yu, LIANG Kexin. IN-SITU IMPEDANCE INVESTIGATION OF 304 STAINLESS STEEL BETWEEN PIT GROWTH AND REPASSIVATION STATE. J Chin Soc Corr Pro, 2011, 31(2): 130-134.

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2011/V31/I2/130

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