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| INFLUENCE OF SATURATED H$_2$S ON CORROSION BEHAVIOR OF 316L STAINLESS STEEL |
| TANG Junwen1, SHAO Yawei1, ZHANG Tao1, MENG Guozhe1,WANG Fuhui1,2 |
1. Corrosion and Protection Laboratory, Key Laboratory of Superlight Materials and Surface Technology Ministry of Education, Harbin Engineering University, Harbin 150001
2. State Key Laboratory for Corrosion and Protection, Institute of Metals Research, Chinese Academy of Sciences, Shenyang 110016 |
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Abstract The corrosion behavior of 316L stainless steel in H2S-HCl-H2O environment at 80℃ was investigated by potentiodynamic polarization curves, electrochemical impedance spectroscopy (EIS) and electrochemical noise (EN). The parameters derived from shot noise theory combined stochastic theory had been employed to analyze the corrosion mechanism of 316L stainless steel in H2S-HCl-H2O environment at 80℃. The polarization curves of 316L stainless steel indicated that there existed an obvious passivation characteristic without H2S, and active dissolution with saturated H2S. The corrosion process of 316L stainless steel was promoted greatly with addition of saturated H2S. An analysis of the electrochemical noise data based upon the combined stochastic theory and shot-noise theory showed that the characteristic frequency of corrosion of 316L stainless steel were increased and the development of corrosion of 316L stainless steel became much easy with addition of saturated H2S.
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Received: 04 January 2009
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Corresponding Authors:
SHAO Yawei
E-mail: ywshao@tom.com
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