Effect of Liquid Film Thickness on Corrosion Behavior of Solid Slippery Surface under Thin Liquid Film

doi:10.11902/1005.4537.2022.289

Journal of Chinese Society for Corrosion and protection

2023, Vol. 43

Issue (4): 862-870 DOI: 10.11902/1005.4537.2022.289

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Effect of Liquid Film Thickness on Corrosion Behavior of Solid Slippery Surface under Thin Liquid Film

REN Huangwei¹, LIAO Bokai², CUI Linjing¹, XIANG Tengfei¹^,³(

)

^1.School of Civil Engineering, Anhui University of Technology, Ma'anshan 243002, China
^2.School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
^3.Key Laboratory of Green Fabrication and Surface Technology of Advanced Metal Materials, Ministry of Education, Ma'anshan 243002, China

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Abstract

A stable solid slippery surface (SSS) was fabricated by constructing micro-nano structure on the surface of low carbon steel via electrodeposition method and then lubricant was infused. The corrosion behavior of SSS and the changes of surface morphology and composition after corrosion test under liquid films of different thicknesses (500, 250, 100 and 50 μm) was characterized by means of electrochemical tests, scanning electron microscopy (SEM) and X-ray diffractometer (XRD) etc. The results showed that in the early stage of thin liquid film corrosion, as the thickness of the thin liquid film decreases, the corrosion behavior of SSS shows small differences, and the SSS showed the largest corrosion resistance when the thickness of thin liquid film was 100 μm. After immersion for 1 d, the limited diffusion current density is 4.899×10^-6 A·cm^-2 (at -1.4 V), and the fitted impedance value reaches 1.54×10⁵ Ω·cm². Even after soaking for 7 d, it still exhibited an impedance value of 6.98×10⁴ Ω·cm², and it was hard to detect the formation of corrosion products, demonstrated its excellent stability and corrosion resistance.

Key words: solid slippery surface electrochemical test thin liquid film corrosion behavior wettability

Received: 19 September 2022 32134.14.1005.4537.2022.289

ZTFLH:

TG174

Fund: National Natural Science Foundation of China(52201056);Key Project of Natural Science Foundation of Anhui Provincial Department of Education(KJ2021A0377)

Corresponding Authors: XIANG Tengfei, E-mail: xiangtf@ahut.edu.cn

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Cite this article:

REN Huangwei, LIAO Bokai, CUI Linjing, XIANG Tengfei. Effect of Liquid Film Thickness on Corrosion Behavior of Solid Slippery Surface under Thin Liquid Film. Journal of Chinese Society for Corrosion and protection, 2023, 43(4): 862-870.

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https://www.jcscp.org/EN/10.11902/1005.4537.2022.289 OR https://www.jcscp.org/EN/Y2023/V43/I4/862

Fig.1 Schematic diagram of preparation process of the solid slippery surface (SSS)

Fig.2 Diagram of thin liquid film test device

Fig.3 Morphology of superhydrophobic surface (a) and SSS (c), CA of superhydrophobic surface (b) and SSS (d), sliding behavior of the SSS (e) and the coating section thickness and energy spectrum scanning results (f)

Fig.4 Cathodic polarization curves of SSS at different soaking time under 500 μm (a), 250 μm (b), 100 μm (c) and 50 μm (d) liquid film thicknesses and -1.4 V ultimatet diffusion current of different liquid film thicknesses at 1 d (e) and different soaking time under 100 μm liquid film thickness (f)

Fig.5 Nyquist (a, c, e, g) and Bode-phase plots (b, d, f, h) of the SSS with different soaking times at 500 μm (a, b), 250 μm (c, d), 100 μm (e, f) and 50 μm (g, h) liquid film thicknesses

Fig.6 Equivalent circuit diagram of the SSS at 500, 250, 100 μm (a) and 50 μm (b) liquid film thicknesses

Table 1 Electrochemical parameters of the SSS with different soaking times at different liquid film thicknesses

Fig.7 CA and SA of the SSS after corrosion under different liquid film thicknesses (a) and time-delayed sliding image of the SSS with a liquid film thickness of 100 μm (b)

Fig.8 Surface morphology of corroded samples at 500 μm (a, e), 250 μm (b, f), 100 μm (c, g) and 50 μm (d, h) liquid film thicknesses.

Table 2 Distribution and content of elements on sample surface after corrosion at different liquid film thicknesses

Fig.9 XRD patterns of corroded samples with different liquid film thicknesses

Fig.10 Anti-corrosion mechanism schematic diagram of the SSS

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