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Journal of Chinese Society for Corrosion and protection  2022, Vol. 42 Issue (1): 16-24    DOI: 10.11902/1005.4537.2021.021
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Research Progress on Anti-corrosion Coatings of Layered Double Hydroxides
LIU Shuhui, LIU Bin(), XU Dawei, LIU Yu, CHEN Fanwei, LIU Siqi
Beijing Key Laboratory of Electrochemical Processes and Technology of Materials, College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
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Abstract  

Layered double hydroxide (LDHs) is a type of layered compound composed of positively charged metal hydroxides and negatively charged anions. LDHs has the unique advantages of ion exchange, adjustable structure, good thermal stability and low manufacturing cost, therefore, it is an important class of inorganic nanocontainer material, and has a wide range of applications in the fields of flame retardancy, catalysis, water treatment, drug sustained release, etc. In recent years, LDHs has been proven to be able to load corrosion inhibitors and release them into the environment through ion exchange, which has become a major research hotspot in the field of anti-corrosion coatings. In this article, the anti-corrosion mechanism, influencing factors of LDHs materials, the research progress of various types of LDHs anti-corrosion coatings were summarized. At the same time, problems and solutions related with the application process were also analyzed. On the other hand, the relevant progress of LDHs anti-corrosion coatings in terms of multi-functionalization and compounding was summarized and prospected.

Key words:  layered double hydroxide (LDHs)      anti-corrosion      coating     
Received:  29 January 2021     
ZTFLH:  TG174  
Fund: Fundamental Research Funds for the Central Universities of China(buctrc201730)
Corresponding Authors:  LIU Bin     E-mail:  liubindr@163.com
About author:  LIU Bin, E-mail: liubindr@163.com

Cite this article: 

LIU Shuhui, LIU Bin, XU Dawei, LIU Yu, CHEN Fanwei, LIU Siqi. Research Progress on Anti-corrosion Coatings of Layered Double Hydroxides. Journal of Chinese Society for Corrosion and protection, 2022, 42(1): 16-24.

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https://www.jcscp.org/EN/10.11902/1005.4537.2021.021     OR     https://www.jcscp.org/EN/Y2022/V42/I1/16

Fig.1  Schematic diagram of the ion exchange mechanism of LDH[16]
Fig.2  Schematic representation of anodized layer sealed with LDH loaded with inhibitor[28]
ProcessStep 1Step 2Step 3Step 4
FP1Al(NO3)3Mg(NO3)2NaOHNa2CO3
FP2Al(NO3)3Na2CO3NaOHMg(NO3)2
FP3Mg(NO3)2Na2CO3NaOHAl(NO3)3
FP4Na2CO3Mg(NO3)2Al(NO3)3NaOH
Table 1  Four types of feeding process[38]
Fig.3  Surface morphologies and water contact angles of LDHs coatings with different feeding processes ofFP1 (a), FP2 (b), FP3 (c) and FP4 (d)[38]
Fig.4  Schematic representation of the protective mechan-ism of super-hydrophobic coating[46]
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