Please wait a minute...
Journal of Chinese Society for Corrosion and protection  2018, Vol. 38 Issue (3): 283-288    DOI: 10.11902/1005.4537.2017.109
Current Issue | Archive | Adv Search |
Effect of Pulse Current on Micro-arc Oxidation Process for 1050 Al-alloy
Zhao YANG, Huiying SHI(), Bailing JIANG, Yanfeng GE, Jing ZHANG, Manyu ZHANG, Yan LI
Department of Material Science and Engineering, Xi'an University of Technology, Xi'an 710048, China
Download:  HTML  PDF(2000KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

The effect of pulse current on micro-arc oxidation (MAO) process for 1050 Al-alloy was investigated. The thickness and roughness, surface morphology and corrosion performance of the prepared MAO coatings were assessed by means of eddy current thickness gauge and roughness tester, scanning electron microscope (SEM) and potentiodynamic polarization measurement respectively. The energy consumption of MAO process was calculated based on voltage versus time curves. Results indicate that with the increasing pulse current from 100 to 800 A, the arcing time shorten from 360 s to 15 s, while the arcing voltage rose from 341 V to 887 V. The diameter of micropores of the coatings was enlarged but the quantity reduced. While thicker and coarser ceramic coatings were obtained on the Al-alloy but with degraded corrosion resistance. The energy consumption of arcing process decreased at first then raised, and which presented the minimum value of 18.3 kJ for a pulse current of 200 A. The energy consumption of MAO coating process presented approximately a linear growth with the increasing pulse current density.

Key words:  Al-alloy      micro-arc oxidation      pulse current      corrosion resistance      energy consumption     
Received:  05 July 2017     
ZTFLH:  TG174.4  
  TG179  
Fund: Supported by Natural Science Foundation of Shaanxi Province (2018JQ5179)

Cite this article: 

Zhao YANG, Huiying SHI, Bailing JIANG, Yanfeng GE, Jing ZHANG, Manyu ZHANG, Yan LI. Effect of Pulse Current on Micro-arc Oxidation Process for 1050 Al-alloy. Journal of Chinese Society for Corrosion and protection, 2018, 38(3): 283-288.

URL: 

https://www.jcscp.org/EN/10.11902/1005.4537.2017.109     OR     https://www.jcscp.org/EN/Y2018/V38/I3/283

Fig.1  Schematic diagram of electrical control parameters of power source
Fig.2  Effects of pulse current on arcing time and voltage during MAO of 1050 aluminum alloy
Fig.3  Voltage-time curves in MAO process at different pulse currents
ip / A Thickness / μm Roughness / μm
100 1.8 0.44
200 3.7 0.56
300 4.1 0.73
400 4.4 0.97
600 7.6 1.28
800 8.5 1.42
Table 1  Thickness and roughness of ceramic coatings formed on 1050 aluminum alloy during MAO at different pulse currents
Fig.4  Surface morphologies of 1050 aluminum alloy after MAO at different pulse currents: (a) 100 A, (b) 200 A, (c) 300 A, (d) 400 A, (e) 600 A, (f) 800 A
Fig.5  Cross-sectional morphologies of 1050 aluminum alloy after MAO at different pulse currents: (a) 200 A, (b) 400 A, (c) 800 A
Fig.6  Potentiodynamic polarization curves of bare and MAO treated 1050 aluminum alloy in 3.5%NaClsolution
ip / A ba / mv bc / mv Icorr / A·cm-2 Ecorr / V
Bare 5.1 2.9 1.37×10-6 -0.52
200 6.3 6.8 1.39×10-10 -0.42
400 6.5 7.0 1.22×10-10 -0.43
800 4.8 5.6 5.13×10-9 -0.44
Table 2  Fitting electrochemical parameters of potentiodynamic polarization curves for bare and MAO treated 1050 aluminum alloy in 3.5%NaCl solution
Fig.7  Energy consumptions of arcing and ceramic coating growing during MAO of 1050 aluminum alloy at different pulse currents
Fig.8  Energy consumption for the formation of unit-thickness MAO coating on 1050 aluminum alloy at different pulse currents
[1] Lia H X, Rudnev V S, Zheng X H, et al.Characterization of Al2O3 ceramic coatings on 6063 aluminum alloy prepared in borate electrolytes by micro-arc oxidation[J]. J. Alloy. Compd., 2008, 462: 99
[2] Wang C J, Jiang B L, Liu M, et al.Corrosion characterization of micro-arc oxidization composite electrophoretic coating on AZ31B magnesium alloy[J]. J. Alloy. Compd., 2015, 621: 53
[3] Guo P Y, Wang X F, Shao Y.Formation mechanism and corrosion behavior of micro-arc oxidation ceramic layers on 1050 pure aluminum[J]. Corros. Sci. Prot. Technol., 2011, 23: 490(郭平义, 王晓璠, 邵勇. 1050纯铝微弧氧化陶瓷层的生长动力学与腐蚀性能研究[J]. 腐蚀科学与防护技术, 2011, 23: 490)
[4] Gupta P, Tenhundfeld G, Daigle E O, et al.Electrolytic plasma technology: Science and engineering?An overview[J]. Surf. Coat. Technol., 2007, 201: 8746
[5] Jaspard?Mécuson F, Czerwiec T, Henrion G, et al. Tailored aluminum oxide layers by bipolar current adjustment in the plasma electrolytic oxidation (PEO) process[J]. Surf. Coat. Technol., 2007, 201: 8677
[6] Jiang B L, Zhang X F.Growth process and corrosion resistance ofceramic coatings formed by micro-oxidation on magnesium alloy[J]. J. Chin. Soc. Corros. Prot., 2005, 25: 97(蒋百灵, 张先锋. 镁合金微弧氧化陶瓷层的生长过程及其耐蚀性[J]. 中国腐蚀与防护学报, 2005, 25: 97)
[7] Ge Y F, Jiang B L, Shi H Y.Effect of current pulse width on micro-arc oxidation process for aluminum alloy[J]. Trans. Mater. Heat Treat., 2013, 34: 165(葛延峰, 蒋百灵, 时惠英. 电流脉冲宽度对铝合金微弧氧化过程的影响[J]. 材料热处理学报, 2013, 34: 165)
[8] Jiang B L, Liu D J.Scientific aspects of restricting development and application of micro-arc oxidation technology[J]. Chin. J. Nonferrous Met., 2011, 21: 2402(蒋百灵, 刘东杰. 制约微弧氧化技术应用开发的几个科学问题[J]. 中国有色金属学报, 2011, 21: 2402)
[9] Yerokhin A L, Shatrov T A, Samsonov V, et al.Oxide ceramic coatings on aluminium alloys produced by a pulsed bipolar plasma electrolytic oxidation process[J]. Surf. Coat. Technol., 2005, 199: 150
[10] Liu R M, Guo F, Li P F.Effect of voltage on formation of ceramic coating prepared by micro-arc oxidation on aluminum alloy[J]. Trans. Mater. Heat Treat., 2008, 29: 137(刘荣明, 郭锋, 李鹏飞. 电压对铝合金微弧氧化陶瓷层形成的影响[J]. 材料热处理学报, 2008, 29: 137)
[11] Hou W A, Hu J H, Song X J.The influence of power supply modeon the process and performance of coating of micro-arc oxidation[J]. Nonferrous Met.(Extr. Metall.), 2007, (S1): 122(侯伟骜, 胡江辉, 宋希剑. 电源工作模式对微弧氧化过程和膜层性能的影响[J]. 有色金属 (冶炼部分), 2007, (S1): 122)
[12] Yerokhin A L, Snizhko L O, Gurevina N L, et al.Discharge characterization in plasma electrolytic oxidation of aluminium[J]. J. Phys. D: Appl. Phys., 2003, 3: 2110
[13] Cui X J, Wang R, Wei J S, et al.Effect of electrical parameters on micromorphology and corrosion resistance of micro-arc oxidation coating on AZ31B Mg alloy[J]. J. Chin. Soc. Corros. Prot., 2014,34: 495(崔学军, 王荣, 魏劲松等. 电参数对AZ31B 镁合金微弧氧化膜微观形貌及耐蚀性的影响[J]. 中国腐蚀与防护学报, 2014, 34: 495)
[14] Jiang B L, Zhang S F, Wu G J.Study of corrosion resistance on ceramic coatings formed by micro-arc oxidation on magnesium alloys[J]. J. Chin. Soc. Corros. Prot., 2002, 22: 300(蒋百灵, 张淑芬, 吴国建等. 镁合金微弧氧化陶瓷层耐蚀性的研究[J] .中国腐蚀与防护学报, 2002, 22: 300)
[15] Zhao J, Song R G, Li H X, et al.Effects of nano-additive on microstructure and properties of micro-arc oxidation coatings on 6063 aluminum alloy[J]. Trans. Mater. Heat Treat., 2010, 31: 125(赵坚, 宋仁国, 李红霞等. 纳米添加剂对6063铝合金微弧氧化层组织与性能的影响[J]. 材料热处理学报, 2010, 31: 125)
[16] Lv G H, Gu W C, Chen H, et al.Characteristics of ceramic coatings on aluminum formed by plasma electrolytic oxidation in silicate and phosphate electrolyte[J]. Appl. Surf. Sci., 2006, 253: 947
[1] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[2] ZHANG Yuxuan, CHEN Cuiying, LIU Hongwei, LI Weihua. Research Progress on Mildew Induced Corrosion of Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 13-21.
[3] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[4] WEI Zheng, MA Baoji, LI Long, LIU Xiaofeng, LI Hui. Effect of Ultrasonic Rolling Pretreatment on Corrosion Resistance of Micro-arc Oxidation Coating of Mg-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 117-124.
[5] YU Hongfei, SHAO Bo, ZHANG Yue, YANG Yange. Preparation and Properties of Zr-based Conversion Coating on 2A12 Al-alloy[J]. 中国腐蚀与防护学报, 2021, 41(1): 101-109.
[6] BAO Ren, ZHOU Genshu, LI Hongwei. Preparation of High-tin Bronze Corrosion-resistant Coating by Potentiostatic Pulse Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(6): 585-591.
[7] LIU Haixia, HUANG Feng, YUAN Wei, HU Qian, LIU Jing. Corrosion Behavior of 690 MPa Grade High Strength Bainite Steel in a Simulated Rural Atmosphere[J]. 中国腐蚀与防护学报, 2020, 40(5): 416-424.
[8] LI Congwei, DU Shuangming, ZENG Zhilin, LIU Eryong, WANG Feihu, MA Fuliang. Effect of Current Density on Microstructure, Wear and Corrosion Resistance of Electrodeposited Ni-Co-B Coating[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[9] DING Qingmiao, QIN Yongxiang, CUI Yanyu. Galvanic Corrosion of Aircraft Components in Atmospheric Environment[J]. 中国腐蚀与防护学报, 2020, 40(5): 455-462.
[10] CAO Jingyi, FANG Zhigang, CHEN Jinhui, CHEN Zhixiong, YIN Wenchang, YANG Yange, ZHANG Wei. Preparation and Properties of Micro-arc Oxide Film with Single Dense Layer on Surface of 5083 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[11] WANG Le,YI Danqing,LIU Huiqun,JIANG Long,FENG Chun. Effect of Ru on Corrosion Behavior of Ti-6Al-4V Alloy and Its Mechanism[J]. 中国腐蚀与防护学报, 2020, 40(1): 25-30.
[12] SHI Chao,SHAO Yawei,XIONG Yi,LIU Guangming,YU Yuelong,YANG Zhiguang,XU Chuanqin. Influence of Silane Coupling Agent Modified Zinc Phosphate on Anticorrosion Property of Epoxy Coating[J]. 中国腐蚀与防护学报, 2020, 40(1): 38-44.
[13] WU Dongcai,HAN Peide. Effects of Moderate Temperature Aging Treatment on Corrosion Resistance of SAF2304 DuplexStainless Steel[J]. 中国腐蚀与防护学报, 2020, 40(1): 51-56.
[14] YANG Yinchu,FU Xiuqing,LIU Lin,MA Wenke,SHEN Moqi. Electrochemical Corrosion of Ni-P-BN(h)-Al2O3 Composite Coating Deposited by Spray Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(1): 57-62.
[15] JIANG Dongxue,FU Ying,ZHANG Junwei,ZHANG Wei,XIN Li,ZHU Shenglong,WANG Fuhui. Preparation and Properties of Alumina Ceramic Film on Ti-alloy Surface[J]. 中国腐蚀与防护学报, 2019, 39(6): 469-476.
No Suggested Reading articles found!