Correlation of Laboratory Simulation Test and Field Exposure Test for Three Stainless Steels in Polluted Marine Atmosphere of Qingdao Coastal Area

doi:10.11902/1005.4537.2024.098

Journal of Chinese Society for Corrosion and protection

2025, Vol. 45

Issue (2): 449-459 DOI: 10.11902/1005.4537.2024.098

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Correlation of Laboratory Simulation Test and Field Exposure Test for Three Stainless Steels in Polluted Marine Atmosphere of Qingdao Coastal Area

MIAO Hao¹, YIN Chenghui¹, WANG Honglun², GAO Yihui³, CHEN Junhang¹, ZHANG Hao¹, LI Bo¹, WU Junsheng¹, XIAO Kui¹(

)

^1.Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
^2.Key Laboratory of Space Launch Site Reliability Technology, Xichang Satellite Launch Center, Haikou 571126, China
^3.Twentieth Research Institute of China Electronics Technology Corporation, Xi'an 710068, China

Cite this article:

MIAO Hao, YIN Chenghui, WANG Honglun, GAO Yihui, CHEN Junhang, ZHANG Hao, LI Bo, WU Junsheng, XIAO Kui. Correlation of Laboratory Simulation Test and Field Exposure Test for Three Stainless Steels in Polluted Marine Atmosphere of Qingdao Coastal Area. Journal of Chinese Society for Corrosion and protection, 2025, 45(2): 449-459.

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Abstract

According to the acquired environmental factors of polluted Marine atmosphere at Qingdao coastal area, an environment spectrum composed of varying ultraviolet irradiation and weekly soaking was designed for laboratory accelerated test. Thereafter, the corrosion behavior of three stainless steels, 430, 316L and 2205 was studied in parallel via lab testing with the proposed spectrum, and further, the correlation of the acquired data was evaluated with the outdoor exposure test results at selected sites in polluted Marine atmospheric environment of Qingdao area. The tested steels were characterized by means of weightlessness method, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), corrosion electrochemistry etc. The results show that after 480 h test of UV irradiation + weekly shocking, 430 stainless steel underwent obvious corrosion, 316L stainless steel showed obvious pitting corrosion, and 2205 stainless steel experienced no obvious corrosion. However, the gray correlation analysis reveals that the laboratory corrosion data for the three stainless steels 430, 316L and 2205 and showed relatively good correlation with those of outdoor exposure test. Accordingly, the following three formulas may be proposed: T₄₃₀ = 50.0114t^0.134351, T_316L = 66.32242t^0.52341 and T₂₂₀₅ = 620.8745t^0.112522, as the corrosion-life prediction model for the corrosion of three stainless steels 430, 316L and 2205 in Qingdao polluted Marine atmospheric environment respectively.

Key words: stainless steel environmental spectrum evaluation pollution of the ocean atmospheric environment correlation corrosion life

Received: 27 March 2024 32134.14.1005.4537.2024.098

TG172.3

Fund: National Key R&D Program of China(2017YFB0304602)

Corresponding Authors: XIAO Kui, E-mail: xiaokui@ustb.edu.cn

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	MIAO Hao
	YIN Chenghui
	WANG Honglun
	GAO Yihui
	CHEN Junhang
	ZHANG Hao
	LI Bo
	WU Junsheng
	XIAO Kui

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https://www.jcscp.org/EN/10.11902/1005.4537.2024.098 OR https://www.jcscp.org/EN/Y2025/V45/I2/449

Table 1 Chemical composition of 430, 316L and 2205 stainless steels

Fig.1 Test methods for simulating industrial marine environments

Fig.2 Mass loss and fitting curves for 430, 316L and 2205 stainless steels after accelerated indoor testing

Table 2 Fitting results of 430, 316L and 2205 stainless steels after accelerated indoor testing

Fig.3 Mass loss rate curves for 430, 316L and 2205 stainless steels after accelerated indoor testing

Fig.4 Surface morphologies of 430 stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.5 SEM images of 430 stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.6 Surface morphologies of 316L stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.7 SEM images of 316L stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.8 Surface morphologies of 2205 stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.9 SEM images of 2205 stainless steel after corrosion for 107 h (a), 214 h (b), 321 h (c) and 428 h (d)

Fig.10 Fe 2p fractional peak fitting spectra of corrosion products of 430 (a, b), 316L (c, d) and 2205 (e, f) stainless steels after corrosion for 428 h

Fig.11 Polarization curves of 430 (a), 316L (b) and 2205 (c) stainless steels after corrosion for different time

Table 3 Fitting results of polarization curves of 430, 316L and 2205 stainless steels

Table 4 Mass loss data from outdoor exposure and UV + weekly immersion tests for three materials

Table 5 Initial treatment results of outdoor exposure and UV + weekly immersion tests data of three materials

Table 6 Absolute difference sequence of three materials

1	Chen H. Research on corrosion behavior of stainless steel in marine atmospheric [D]. Beijing: China Academy of Machinery Science and Technology, 2021
	陈昊. 不锈钢在海洋大气环境中的腐蚀行为研究 [D]. 北京: 机械科学研究总院, 2021
2	Ma H C, Liu Z Y, Du C W, et al. Effect of SO₂ content on corrosion behavior of high-strength steel E690 in polluted marine atmosphere [J]. J. Mech. Eng., 2016, 52(16): 33
	马宏驰, 刘智勇, 杜翠薇等. SO₂质量分数对污染海洋大气环境中高强钢E690腐蚀行为的影响 [J]. 机械工程学报, 2016, 52(16): 33 doi: 10.3901/JME.2016.16.033
3	Zhang D J, Cheng C Q, Yang H, et al. Effect of passivation film integrity on marine atmospheric corrosion of stainless steel and its quality inspection methods [J]. Corros. Prot., 2023, 44(5): 46
	张东玖, 程从前, 杨华等. 钝化膜完整性对不锈钢海洋大气腐蚀的影响及其质检方法 [J]. 腐蚀与防护, 2023, 44(5): 46
4	Song J L, Jiang Z X, Yi P, et al. Corrosion behavior and product evolution of steel for high-speed railway bogie G390NH in simulated marine and industrial atmospheric environment [J]. Acta Metall. Sin., 2023, 59: 1487 doi: 10.11900/0412.1961.2021.00366
	宋嘉良, 江紫雪, 易盼等. 高铁转向架用钢G390NH在模拟海洋和工业大气环境下的腐蚀行为及产物演化规律 [J]. 金属学报, 2023, 59: 1487 doi: 10.11900/0412.1961.2021.00366
5	Gümpel P, Hörtnagl A. Influence of the surface condition on corrosion behavior of stainless steel [J]. Mater. Corros., 2016, 67: 607
6	Guo M X, Tang J R, Pan C, et al. The effect of temperature and UV irradiation on corrosion behavior of 304 stainless steel exposed to a simulated marine atmosphere [J]. Mater. Corros., 2022, 73: 876
7	Almeida E, Morcillo M, Rosales B. Atmospheric corrosion of mild steel. Part Ⅱ-Marine atmospheres [J]. Mater. Corros., 2000, 51: 865
8	Yin C H, Pan J L, Chen J H, et al. Corrosion life assessment of stainless steel in tropical marine atmosphere [J]. Surf. Technol., 2022, 51(4): 183
	尹程辉, 潘吉林, 陈俊航等. 热带海洋大气环境下不锈钢的腐蚀寿命评估 [J]. 表面技术, 2022, 51(4): 183
9	Fujimoto S, Yamada T, Shibata T. Improvement of pitting corrosion resistance of type 304 stainless steel by modification of passive film with ultraviolet light irradiation [J]. J. Electrochem. Soc., 1998, 145: L79
10	Moussa S O, Hocking M G. The photo-inhibition of localized corrosion of 304 stainless steel in sodium chloride environment [J]. Corros. Sci., 2001, 43: 2037
11	MacDonald D D, Heaney D F. Effect of variable intensity ultraviolet radiation on passivity breakdown of AISI Type 304 stainless steel [J]. Corros. Sci., 2000, 42: 1779
12	Lin C, Wang F P, Li X G. The progress of research methods on atmospheric corrosion [J]. J. Chin. Soc. Corros. Prot., 2004, 24(4): 249
	林翠, 王凤平, 李晓刚. 大气腐蚀研究方法进展 [J]. 中国腐蚀与防护学报, 2004, 24(4): 249
13	Bao Z B, Wang Q M, Jiang S M, et al. Influence of salt spray corrosion on subsequent isothermal oxidation behaviours of AIP NiCoCrAlYSiB coatings [J]. Corros. Sci., 2008, 50: 2372
14	Chen J W, Liu J, Wang H B, et al. Experimental study on neutral salt spray accelerated corrosion of metal protective coatings for power-transmission and transformation equipment [J]. Coatings, 2023, 13: 480
15	Ren J H, Chen A Z, Gao R Q, et al. Analysis of corrosion resistance of 445J2 ferrite stainless steel [J]. Phys. Exam. Test., 2023, 41(2): 11
	任娟红, 陈安忠, 高仁强等. 445J2铁素体不锈钢的耐蚀性分析 [J]. 物理测试, 2023, 41(2): 11
16	Chen J H, Bai Z H, Xue W, et al. Corrosion life prediction model of 304 stainless steel in Qingdao polluted marine atmospheric environment [J]. Mater. Prot., 2019, 52(12): 48
	陈俊航, 白子恒, 薛伟等. 304不锈钢在青岛污染海洋大气环境中的腐蚀寿命预测模型 [J]. 材料保护, 2019, 52(12): 48
17	Lyon S B, Thompson G E, Johnson J B, et al. Accelerated atmospheric corrosion testing using a cyclic wet/dry exposure test: aluminum, galvanized steel, and steel [J]. Corrosion, 1987, 43: 719
18	Guo M X, Lu X, Tang J R, et al. Corrosion behavior of 316 stainless steel exposed to a simulated salt lake atmospheric environment under UV illumination [J]. Int. J. Electrochem. Sci., 2021, 16: 210457
19	Guo H C, Wei H H, Li G Q, et al. Experimental research on fatigue performance of butt welds of corroded Q690 high strength steel [J]. J. Constr. Steel Res., 2021, 184: 106801
20	Chang M, Jia J W, Huang C S, et al. An effectiveness analysis for the multi-factor accelerated test of a copper-free self-polishing antifouling coating [J]. Coatings, 2023, 13: 1685
21	Zhao Y T, Ding H L, Qiu K N, et al. Research progress on influencing factors and test methods of atmospheric corrosion of metals [J]. J. Shanghai Univ. Electr. Power, 2022, 38: 527
	赵悦彤, 丁红蕾, 邱凯娜等. 金属大气腐蚀影响因素及实验方法研究综述 [J]. 上海电力大学学报, 2022, 38: 527
22	Liu S G, Cao G, Zheng P H. Study on the corrosion behavior of austenitic stainless steel piping in ships with TIG automatic welding [J]. Mater. Prot., 2024, 57(1): 196
	刘水根, 操戈, 郑鹏华. 船舶奥氏体不锈钢管TIG自动焊腐蚀行为研究 [J]. 材料保护, 2024, 57(1): 196
23	Mu X L, Tian Y E, Wang X H. The relativity of the simulated accelerated test of carbon steel and low alloy steel and atmospheric corrosion test [J]. Environ. Technol., 2001, 19(4): 14
	牟献良, 田月娥, 汪学华. 碳钢和低合金钢模拟加速试验与大气腐蚀试验的相关性 [J]. 环境技术, 2001, 19(4): 14
24	Ding D D, Feng Y, Huang X C, et al. Correlativity on indoor accelerated corrosion and atmospheric exposure of 430 stainless steel [J]. Surf. Technol., 2016, 45(7): 56
	丁冬冬, 凤仪, 黄晓晨等. 430不锈钢室内加速腐蚀与大气暴露的相关性研究 [J]. 表面技术, 2016, 45(7): 56
25	Dong C F, Luo H, Xiao K, et al. Evaluation of corrosion behaviour of 316L stainless steel exposed in marine atmosphere of Xisha islands [J]. J. Sichuan Univ. (Eng. Sci. Ed.), 2012, 44(3): 179
	董超芳, 骆鸿, 肖葵等. 316L不锈钢在西沙海洋大气环境下的腐蚀行为评估 [J]. 四川大学学报(工程科学版), 2012, 44(3): 179
26	Du J, Yu M Y, Liu P L, et al. Corrosion behavior of 2205 duplex stainless steel in acidizing stimulation solution for oil and gas wells at 200 ^oC [J]. Anti-Corros. Methods Mater., 2022, 69: 149
27	Yao Q, Chen J H, Song Y H, et al. Corrosion failure of stainless steel bellows in marine atmosphere [J]. Equip. Environ. Eng., 2020, 17(12): 86
	姚琼, 陈俊航, 宋玉红等. 不锈钢波纹管在海洋大气环境下的腐蚀失效分析 [J]. 装备环境工程, 2020, 17(12): 86
28	Li X G, Dong C F, Xiao K, et al. Initial Behavior and Mechanism of Atmospheric Corrosion of Metals [M]. Beijing: Science Press, 2009
	李晓刚, 董超芳, 肖葵等. 金属大气腐蚀初期行为与机理 [M]. 北京: 科学出版社, 2009
29	Arunnellaiappan T, Krishna L R, Anoop S, et al. Fabrication of multifunctional black PEO coatings on AA7075 for spacecraft applications [J]. Surf. Coat. Technol., 2016, 307: 735
30	Hu Y T, Dong P F, Jiang L, et al. Corrosion behavior of riveted joints of TC4 Ti-alloy and 316L stainless steel in simulated marine atmosphere [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 167
	胡玉婷, 董鹏飞, 蒋立等. 海洋大气环境下TC4钛合金与316L不锈钢铆接件腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2020, 40: 167 doi: 10.11902/1005.4537.2018.183
31	Jiang Q T, Yang L H, Lu D Z, et al. The galvanic corrosion of high-strength AZ80 Mg alloys in typical marine environment [J]. Oceanol. Limnol. Sin., 2020, 51: 899
	蒋全通, 杨黎晖, 路东柱等. 典型海洋大气环境中AZ80镁合金电偶腐蚀行为研究 [J]. 海洋与湖沼, 2020, 51: 899
32	Li H R. Study on corrosion rate prediction method of oil and gas pipeline [D]. Jingzhou: Yangtze University, 2021
	李昊燃. 油气管道腐蚀速率预测方法研究 [D]. 荆州: 长江大学, 2021
33	Evans U R, King C V. The corrosion and oxidation of metals [J]. J. Electrochem. Soc., 1961, 108: 94C
34	Tang R M, Zhu Y C, Liu G M, et al. Gray correlative degree analysis of Q235 steel/conductive concrete corrosion in three typical soil environments [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 110
	唐荣茂, 朱亦晨, 刘光明等. Q235钢/导电混凝土在3种典型土壤环境中腐蚀的灰色关联度分析 [J]. 中国腐蚀与防护学报, 2021, 41: 110 doi: 10.11902/1005.4537.2020.039

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