Research Progress on Application of Halloysite Nanotubes for Modification of Smart Anti-corrosion Coating

doi:10.11902/1005.4537.2021.194

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (4): 523-530 DOI: 10.11902/1005.4537.2021.194

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Research Progress on Application of Halloysite Nanotubes for Modification of Smart Anti-corrosion Coating

LIU Ling, SHAO Ziya, JIA Tianyue, LIU Guoqiang, LEI Bing(

), MENG Guozhe

School of Chemical Engineering and Technology, Sun Yat-sen University, Zhuhai 519000, China

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Abstract

Halloysite nanotubes (HNTs) are natural aluminosilicate nanomaterials with unique hollow tubular structure, large specific surface area and high reactivity. They exhibit more and more significant application value as a nano-carrier in the field of intelligent anti-corrosion coatings. In this paper, the structure, and properties of HNTs are briefly described, the feasibility of application of HNTs for intelligent coatings is analyzed, the mechanism of surface modification of HNTs and the factors affecting the carrying capacity of corrosion inhibitor are described, the application research progress of the modified HNTs as self-repairing unit for intelligent anticorrosion coating is also analyzed. Simultaneously, the functional improvement of HNTs modified intelligent coating is prospected.

Key words: Halloysite nanotubes load modification self-repairing coating

Received: 12 August 2021

ZTFLH:

TG172

Fund: Science and Technology Projects of Guangzhou(202102020468);Joint Funds of National Natural Science Foundation of China(U20A20233);Fundamental Research Funds for the Central Universities (Sun Yat-sen University, 2021qntd13)

Corresponding Authors: LEI Bing E-mail: leibing@mail.sysu.edu.cn

About author: LEI Bing, E-mail: leibing@mail.sysu.edu.cn

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	Guozhe MENG

Cite this article:

LIU Ling, SHAO Ziya, JIA Tianyue, LIU Guoqiang, LEI Bing, MENG Guozhe. Research Progress on Application of Halloysite Nanotubes for Modification of Smart Anti-corrosion Coating. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 523-530.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.194 OR https://www.jcscp.org/EN/Y2022/V42/I4/523

Table 1 Typical characteristic parameters of HNTs^[25]

Fig.1 Schematic illustrations of transformation of HNTs in strong acid (right) and strong alkaline (left) conditions^[27]

Fig.2 Enhancement of the lumen by acid etching of alumina in the inner layer of HNTs^[28]

Table 2 Chemical constructions of silanes used for modification of HNTs

Fig.3 Process steps of loading inhibitor on HNTs in vacuum

Fig.4 Schematic illustrations of layer-by-layer self-assembly on the surface of HNTs (a) and illustration of the formation of end stopper in Cu²⁺ treating process (b)^[23,49]

Fig.5 Production process flow of smart anti-corrosion coating containing corrosion inhibitor-loaded HNTs

Table 3 Summary of typical self-healing coatings containing corrosion inhibitor-loaded HNTs

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