Preparation, Corrosion- and Wear-resistance of Polymethyl Methacrylate Coating Modified with Particles of Basalt/cerium Oxide Composite

doi:10.11902/1005.4537.2021.186

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (4): 597-604 DOI: 10.11902/1005.4537.2021.186

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Preparation, Corrosion- and Wear-resistance of Polymethyl Methacrylate Coating Modified with Particles of Basalt/cerium Oxide Composite

LEI Yanhua(

), LIU Ningxuan, ZHANG Yuliang, CHANG Xueting, LIU Tao

College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China

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Abstract

A polymethyl methacrylate coating (PMMA) containing particles of basalt/cerium oxide composite was applied on X70 steel, then the effect of the addition amount of basalt/cerium oxide composite on the corrosion- and wear-resistance of the coating was studied. The synthesized basalt/cerium oxide composite material was characterized by X-ray diffractometer. The surface morphology, composition, hydrophilicity, and hydrophobicity of the coating before and after the addition of basalt/cerium oxide particles were assessed comparatively by scanning electron microscope with energy dispersive spectroscope and contact angle tester. At the same time, the anti-corrosion and friction behavior of the modified coating were studied by means of electrochemical impedance spectroscope, polarization curve measurement, friction- and wear-tester. The results show that the modified coating with basalt/cerium oxide composite exhibits much obvious hydrophobicity and better corrosion resistance and friction resistance.

Key words: cerium oxide basalt polymethyl methacrylate coating anti-corrosion friction and wear

Received: 05 August 2021

ZTFLH:

TG178

Fund: National Natural Science Foundation of China(516020195);National Natural Science Foundation of China(41976039)

Corresponding Authors: LEI Yanhua E-mail: yhlei@shmtu.edu.cn

About author: LEI Yanhua, E-mail: yhlei@shmtu.edu.cn

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	Yanhua LEI
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Cite this article:

LEI Yanhua, LIU Ningxuan, ZHANG Yuliang, CHANG Xueting, LIU Tao. Preparation, Corrosion- and Wear-resistance of Polymethyl Methacrylate Coating Modified with Particles of Basalt/cerium Oxide Composite. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 597-604.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.186 OR https://www.jcscp.org/EN/Y2022/V42/I4/597

Fig.1 SEM image of used basalt fine powders (a) and TEM image of CeO₂ nanoparticles (b)

Fig.2 XRD patterns of basalt powders and BA/CeO₂ particles

Fig.3 Water contact angles of various samples with PMMA, BA/CeO₂/PMMA-0.06, BA/CeO₂/PMMA-0.08, BA/CeO₂/PMMA-0.1 and BA/CeO₂/PMMA-0.12 coatings

Fig.4 SEM surface morphologies of various samples with PMMA (a), BA/CeO₂/PMMA-0.06 (b), BA/CeO₂/PMMA-0.08 (c), BA/CeO₂/PMMA-0.1 (d), BA/CeO₂/PMMA-0.12 coatings (e) and cross-sectional image of BA/CeO₂/PMMA-0.1 coating (f)

Fig.5 EDS element mappings of the surfaces of BA/CeO₂/PMMA-0.06 (a1, a2), BA/CeO₂/PMMA-0.08 (b1, b2), BA/CeO₂/PMMA-0.1 (c1, c2) and BA/CeO₂/PMMA-0.12 (d1, d2) coatings

Fig.6 Nyquist (a) and Bode (b) diagrams of various samples with PMMA, BA/CeO₂/PMMA-0.06, BA/CeO₂/PMMA-0.08, BA/CeO₂/PMMA-0.1 and BA/CeO₂/PMMA-0.12 coatings in 3.5%NaCl solution

Fig.7 Equivalent circuit diagram of electrochemical impedance spectroscopy

Table 1 Fitting results of electrochemical impedance spectroscopies of X70 steel samples with PMMA, BA/CeO₂/PMMA-0.06, BA/CeO₂/PMMA-0.08, BA/CeO₂/PMMA-0.1 and BA/CeO₂/PMMA-0.12 coatings in 3.5%NaCl solution

Fig.8 Polarization curves of X70 steel samples with PMMA, BA/CeO₂/PMMA-0.06, BA/CeO₂/PMMA-0.08, BA/CeO₂/PMMA-0.1 and BA/CeO₂/PMMA-0.12 coatings in 3.5%NaCl solution

Table 2 Fitting electrochemical parameters of polarization curves of X70 steel samples with different coatings in 3.5%NaCl solution

Fig.9 Variation of friction coefficient of coated X70 steel with the adding content of basalt / ceria particles in the coating

Fig.10 Wear scar profiles of X70 steel samples with the coatings of PMMA (a), BA/CeO₂/PMMA-0.06 (b), BA/CeO₂/PMMA-0.08 (c), BA/CeO₂/PMMA-0.1 (d) and BA/CeO₂/PMMA-0.12 (e)

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