Preparation and Performance of Smart Coating Doped with Nanocontainers of BTA@MSNs-SO3H-PDDA for Anti-corrosion of Carbon Steel

doi:10.11902/1005.4537.2021.039

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (2): 309-316 DOI: 10.11902/1005.4537.2021.039

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Preparation and Performance of Smart Coating Doped with Nanocontainers of BTA@MSNs-SO₃H-PDDA for Anti-corrosion of Carbon Steel

WEN Jiaxin¹(

), ZHANG Xin¹, LIU Yunxia¹, ZHOU Yongfu², LIU Kejian²

^1.School of Civil Engineering, Chongqing Industry Polytechnic College, Chongqing 401120, China
^2.School of Chemistry and Pharmaceutical Engineering, Chongqing Industry Polytechnic College, Chongqing 401120, China

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Abstract

Organic coatings are commonly used as an effective strategy for protecting carbon steel from corrosion, but the traditional organic coatings are susceptible to generate micron cracks or defects during service, resulting in the premature failure. In view of this problem, a novel benzotriazole containing nanocontainers, namely BTA@MSNs-SO₃H-PDDA with pH-sensitivity was prepared firstly, then a BTA@MSNs-SO₃H-PDDA doped smart organic coating was fabricated for application on carbon steel. The structure and performance of BTA@MSNs-SO₃H-PDDA were characterized by scanning electron microscopy (SEM), dynamic light scattering analysis (DLS), X-ray diffraction analysis (XRD), infrared spectroscopy (FT-IR), thermogravimetry (TGA) and ultraviolet-visible spectroscopy (UV-Vis). The protective performance of the smart coatings for carbon steel was evaluated by electrochemical impedance spectroscopy and salt spray accelerated tests. The results showed that the particles of BTA@MSNs-SO₃H-PDDA are near-spherical in shape, with an average diameter of 718 nm. The amount of BTA loaded in BTA@MSNs-SO₃H-PDDA is about 13.37%. The releasing rate of BTA from BTA@MSNs-SO₃H- PDDA can be accelerated via the sensitive response of the pH changes. The prepared smart coating based on BTA@MSNs-SO₃H-PDDA presents remarkable anti-corrosion performance for carbon steel.

Key words: carbon steel smart coating nanocontainers corrosion protection pH-sensitivity

Received: 04 March 2021

ZTFLH:

TG174.42

Fund: General Projects of Chongqing Natural Science Foundation(cstc2020jcyj-msxmX1067);Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202103202)

Corresponding Authors: WEN Jiaxin E-mail: 18523976826@163.com

About author: WEN Jiaxin, E-mail: 18523976826@163.com

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Cite this article:

WEN Jiaxin, ZHANG Xin, LIU Yunxia, ZHOU Yongfu, LIU Kejian. Preparation and Performance of Smart Coating Doped with Nanocontainers of BTA@MSNs-SO₃H-PDDA for Anti-corrosion of Carbon Steel. Journal of Chinese Society for Corrosion and protection, 2022, 42(2): 309-316.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.039 OR https://www.jcscp.org/EN/Y2022/V42/I2/309

Fig.1 SEM images of MSNs (a, b) and BTA@MSNs-SO₃H-PDDA (c, d)

Fig.2 DLS size distribution (a) and XRD patterns (b) of MSNs, MSNs-SO₃H and BTA@MSNs-SO₃H-PDDA

Fig.3 TGA curves of MSNs, MSNs-NH₂, MSNs-SO₃H, MSNs-SO₃H-PDDA and BTA@MSNs-SO₃H-PDDA

Fig.4 FT-IR spectra of MSNs, MSNs-NH₂, MSNs-SO₃H， MSNs-SO₃H-PDDA and BTA@MSNs-SO₃H-PDDA

Fig.5 Releasing curves of BTA@MSNs-SO₃H-PDDA at different pH

Fig.6 Nyquist (a, c, e, g) and Bode (b, d, f, h) plots of the electrode coated by epoxy coatings doped with 0% (a, b), 4.0% (c, d), 8.0% (e, f), 12.0% (g, h) BTA@MSNs-SO₃H-PDDA after certain hours in 3.5%NaCl solution

Fig.7 Electrochemical equivalent circuits used to fit the impedance data: (a) only one time constant impedance plots, (b) two time constants impedance plots

Fig.8 Variations of R_c (a) and R_ct (b) of the smart coatings doped with different amounts of BTA@MSNs-SO₃H-PDDA with immersion time

Fig.9 Optical photographs of the different coated samples after 240 h of exposure in the salt spray tester: (a) epoxy coating, the epoxy coating doped with (b) 8.0%MSNs-SO₃H-PDDA, the smart coating doped with (c) 4.0%, (d) 8.0% and (e) 12.0% BTA@MSNs-SO₃H-PDDA

1	Zhang C, Lu Y, Zhao J M. Synergistic inhibition effect of imidazoline ammonium salt and three cationic surfactants in H₂S/CO₂ brine solution [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 237
	张晨, 陆原, 赵景茂. CO₂/H₂S腐蚀体系中咪唑啉季铵盐与3种阳离子表面活性剂间的缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2020, 40: 237
2	Zhang F, Ju P F, Pan M Q, et al. Self-healing mechanisms in smart protective coatings: A review [J]. Corros. Sci., 2018, 144: 74
3	He J, Yang C T, Li Z. Research progress of microbiologically influenced corrosion and protection in building industry [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 151
	何静, 杨纯田, 李中. 建筑行业微生物腐蚀与防护研究进展 [J]. 中国腐蚀与防护学报, 2021, 41: 151
4	Luan H, Meng F D, Liu L, et al. Preparation and anticorrosion performance of m-phenylenediamine-graphene oxide/organic coating [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 161
	栾浩, 孟凡帝, 刘莉等. 间苯二胺—氧化石墨烯/有机涂层的制备及防腐性能研究 [J]. 中国腐蚀与防护学报, 2021, 41: 161
5	Leal D A, Riegel-Vidotti I C, Ferreira M G S, et al. Smart coating based on double stimuli-responsive microcapsules containing linseed oil and benzotriazole for active corrosion protection [J]. Corros. Sci., 2018, 130: 56
6	Siva T, Sathiyanarayanan S. Self-healing coatings containing dual active agent loaded urea formaldehyde (UF) microcapsules [J]. Prog. Org. Coat., 2015, 82: 57
7	Li Z, Qin B Y, Zhang X Y, et al. Self-healing anti-corrosion coatings based on polymers of intrinsic microporosity for the protection of aluminum alloy [J]. RSC Adv., 2015, 5: 104451
8	Wen J X, Lei J L, Chen J L, et al. An intelligent coating based on pH-sensitive hybrid hydrogel for corrosion protection of mild steel [J]. Chem. Eng. J., 2020, 392: 123742
9	Yang P P, Gai S L, Lin J. Functionalized mesoporous silica materials for controlled drug delivery [J]. Chem. Soc. Rev., 2012, 41: 3679
10	Khashab N M, Belowich M E, Trabolsi A, et al. pH-Responsive mechanised nanoparticles gated by semirotaxanes [J]. Chem. Commun., 2009, (36): 5371
11	Tang J M, Zhang R T. Research progress on mesoporous silica nanoparticles [J]. Drugs Clin., 2015, 30: 1422
	唐佳民, 张瑞涛. 介孔二氧化硅纳米粒的研究进展 [J]. 现代药物与临床, 2015, 30: 1422
12	Liang Y, Wang M D, Wang C, et al. Facile synthesis of smart nanocontainers as key components for construction of self-healing coating with superhydrophobic surfaces [J]. Nanoscale Res. Lett., 2016, 11: 231
13	Saremi M, Yeganeh M. Application of mesoporous silica nanocontainers as smart host of corrosion inhibitor in polypyrrole coatings [J]. Corros. Sci., 2014, 86: 159
14	Kermannezhad K, Chermahini A N, Momeni M M, et al. Application of amine-functionalized MCM-41 as pH-sensitive nanocontainer for controlled release of 2-mercaptobenzoxazole corrosion inhibitor [J]. Chem. Eng. J., 2016, 306: 849
15	Chen H Y, Zheng D W, Liu J, et al. pH-Sensitive drug delivery system based on modified dextrin coated mesoporous silica nanoparticles [J]. Int. J. Biol. Macromol., 2016, 85: 596
16	Ye X, Li X, Shen Y Q, et al. Self-healing pH-sensitive cytosine- and guanosine-modified hyaluronic acid hydrogels via hydrogen bonding [J]. Polymer, 2017, 108: 348
17	Li G L, Schenderlein M, Men Y J, et al. Monodisperse polymeric core-Shell nanocontainers for organic self-Healing anticorrosion coatings [J]. Adv. Mater. Interfaces, 2014, 1: 1300019
18	Sudarsan S, Franklin D S, Sakthivel M, et al. Non toxic, antibacterial, biodegradable hydrogels with pH-stimuli sensitivity: Investigation of swelling parameters [J]. Carbohydr. Polym., 2016, 148: 206
19	Zhao H, Gao J, Liu R N, et al. Stimulus-responsiveness and methyl violet release behaviors of poly (NIPAAm-co-AA) hydrogels chemically crosslinked with β-cyclodextrin polymer bearing methacrylates [J]. Carbohydr. Res., 2016, 428: 79
20	Xie R H, Ren P G, Hui J, et al. Preparation and properties of graphene oxide-regenerated cellulose/polyvinyl alcohol hydrogel with pH-sensitive behavior [J]. Carbohydr. Polym., 2016, 138: 222
21	Dinodi N, Shetty A N. Alkyl carboxylates as efficient and green inhibitors of magnesium alloy ZE41 corrosion in aqueous salt solution [J]. Corros. Sci., 2014, 85: 411
22	Maile F J, Schauer T, Eisenbach C D. Evaluation of corrosion and protection of coated metals with local ion concentration technique (LICT) [J]. Prog. Org. Coat., 2000, 38: 111

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