Influence of Cr Content on Corrosion Resistance of Composite Ni/Ni-Cr/Ni-Cr-Al-Si Films on Cu

doi:10.11902/1005.4537.2021.173

Journal of Chinese Society for Corrosion and protection

2022, Vol. 42

Issue (4): 638-646 DOI: 10.11902/1005.4537.2021.173

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Influence of Cr Content on Corrosion Resistance of Composite Ni/Ni-Cr/Ni-Cr-Al-Si Films on Cu

WEN Jiayuan¹, SONG Guihong¹(

), WEI Xiaoyuan², ZHAO Xin¹, WU Yusheng¹, DU Hao²(

), HE Chunlin³

^1.School of Material Science and Technology, Shenyang University of Technology, Shenyang 110870, China
^2.Institute of Corrosion Science and Technology, Guangzhou 510530, China
^3.Liaoning Province Key Laboratory of Advanced Materials, Shenyang University, Shenyang 110044, China

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Abstract

In order to enhance the corrosion resistance of Cu alloy to meet the requirements for their application in marine engineering equipment and facilities, a gradient composite coatings Ni/Ni-Cr/Ni-Cr-Al-Si were prepared on Cu plate by step-wise processes, i.e. firstly electrodeposited Ni film and then magnetron sputtered Ni-Cr alloy films and Ni-Cr-Al-Si alloy films in sequence. The structure and corrosion characteristics of the Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite coatings with different Cr contents were characterized by means of X-ray diffractometer and electrochemical impedance spectroscope (EIS). The results show that among others, the gradient composite coating (S2 sample) with Cr content of 43.05% has the highest corrosion resistance, namely the highest low frequency impedance, capacitance arc radius, maximum phase angle, charge transfer resistance R_f and corrosion potential. The higher the atomic ratio of Al/Cr in the deposited Ni-Cr-Al-Si films is, the better the corrosive resistance of the deposited composite coating is. The corrosion process of the deposited gradient composite coating is mainly pitting corrosion, and the interface of the clusters on the surface of the films is the center of pitting corrosion. The Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite coating with appropriate Cr content has good corrosion resistance in seawater and thermal conductivity, thus it is suitable as a protective coating for heat exchangers made of Cu alloys used in seawater.

Key words: Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite film corrosion resistance Cr content electrochemical impedance spectrum anodic polarization curve

Received: 19 July 2021

ZTFLH:

TQ150.6

Fund: National Natural Science Foundation of China(51772193);Liaoning Revitalization Talents Program(XLYC2008014)

Corresponding Authors: SONG Guihong,DU Hao E-mail: songgh@sut.edu.cn;hdu@icost.ac.cn

About author: DU Hao, E-mail: hdu@icost.ac.cn
SONG Guihong, E-mail: songgh@sut.edu.cn

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Cite this article:

WEN Jiayuan, SONG Guihong, WEI Xiaoyuan, ZHAO Xin, WU Yusheng, DU Hao, HE Chunlin. Influence of Cr Content on Corrosion Resistance of Composite Ni/Ni-Cr/Ni-Cr-Al-Si Films on Cu. Journal of Chinese Society for Corrosion and protection, 2022, 42(4): 638-646.

URL:

https://www.jcscp.org/EN/10.11902/1005.4537.2021.173 OR https://www.jcscp.org/EN/Y2022/V42/I4/638

Table 1 Composition of deposited Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite films (atomic fraction / %)

Fig.1 SEM-EDS map scan of S2 sample: (a) SEM image, (b) EDS color elemental mapping; (c-f) Cr, Ni, Al and Si elemental mapping, respectively

Fig.2 XRD patterns of Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite film with different Cr content (a), local XRD patterns of Ni/Ni-Cr/Ni-Cr-Al-Si composite film with different Cr content (diffraction angle is 43°-46°) (b) and relationship between lattice constant and Cr content (c)

Fig.3 Surface morphologies of Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite film with 39.24%Cr (a), 43.05%Cr (b), 47.05%Cr (c), 49.64%Cr (d)

Fig.4 Cross-sectional morphologies of Ni/Ni-Cr/Ni-Cr-Al-Si gradient composite film with 39.24%Cr (a), 43.05%Cr (b), 47.05%Cr (c), 49.64%Cr (d)

Fig.5 AC impedance spectra of the gradient composite films (a) and relationship between the maxi-mum impedance value and the Cr content (b)

Fig.6 Nyquist (a) and Bode (b) plots and relationship between maximum phase angle and Cr content (c) of the gradient composite films

Fig.7 Equivalent circuit of the gradient composite films to simulate the corrosion reaction

Table 2 EIS data corresponding equivalent circuit and standard parameters of the composite films

Fig.8 Anodic polarization curves of the composite films

Fig.9 Surface morphology after corrosion of the composite films with 39.24%Cr (a), 43.05%Cr (b, c), 47.05%Cr (d, e), 49.64%Cr (f)

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