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High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen |
XU Xunhu1,HE Cuiqun2,XIANG Junhuai1( ),WANG Ling1,ZHANG Honghua1,ZHENG Xiaodong1 |
1. Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China 2. School of Mechanical and Electronic Engineering, Nanchang Institute of Technology, Nanchang 330099, China |
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Abstract The iso-thermal oxidation behavior of Co-20Re-25Cr-1Si alloy in 0.1 MPa pure oxygen at 1000~1100 ℃ for 24 h was investigated. The oxidation kinetics is irregular at both temperatures. The alloys show obvious mass loss due to the evaporation of Re element in the form of ReO3. However, at 1100 ℃ continuous mass gain occurred during the initial 15 min of oxidation, while at 1000 ℃ the alloys remained in a mass loss state during the whole oxidation process. The scales formed at both temperatures are very similar. The outermost layer is composed of CoO, while the subsequent layer is composed of CoO and CoCr2O4. The innermost layer is a thin and protective layer of Cr2O3 with a certain degree of continuity. Moreover, there is an inner oxidation zone of Si beneath the outer scales. Since the Cr2O3 layer formed at 1000 ℃ is more continuous and denser, the alloy exhibits a better oxidation resistance at 1000 ℃.
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Received: 08 September 2019
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Fund: Science and Technology Research Program of Jiangxi Provincial Education Department(GJJ160770);Graduate Innovation Fund of Jiangxi Science and Technology Normal University(YC2018-X01) |
Corresponding Authors:
Junhuai XIANG
E-mail: xiangjunhuai@163.com
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[1] | Xiang J H, Gesmundo F, Niu Y. The oxidation of two ternary Ni-Cu-10 at.% Al alloys in 1 atm of pure O2 at 800-900 ℃ [J]. Corros. Sci., 2004, 46: 2025 | [2] | Zhao Z, Li J Y, Dong J X, et al. Oxidation behavior during high temperature homo-genization treatment of cast Ni-Fe based corrosion resistant 925 alloy [J]. J. Chin. Soc. Corros. Prot., 2017, 37: 1 | [2] | (赵展, 李景阳, 董建新等. 925镍铁基耐蚀合金均匀化及高温氧化行为 [J]. 中国腐蚀与防护学报, 2017, 37: 1) | [3] | Huang J P, Yang B, Wang H. Effect of Multiple Addition of Y, La and Ce on Oxidation Behavior of Ni-10Cr-5Al Alloy at 1000 ℃ in Air [J]. J. Chin. Soc. Corros. Prot., 2016, 36: 489 | [3] | (黄嘉鹏, 杨斌, 汪航. 稀土 (Y, La, Ce) 复合添加对Ni-10Cr-5Al合金在1000 ℃下高温氧化行为的影响 [J]. 中国腐蚀与防护学报, 2016, 36: 489) | [4] | Perepezko J H. The hotter the engine, the better [J]. Science, 2009, 326: 1068 | [5] | R?sler J, Mukherji D, Baranski T. Co-Re-based alloys: A new class of high temperature materials? [J]. Adv. Eng. Mater., 2007, 9: 876 | [6] | Gorr B, Burk S, Christ H J. The high-temperature oxidation behavior of Co-Re-Cr-based alloys [J]. JOM, 2011, 63: 37 | [7] | Heilmaier M, Krüger M, Saage H, et al. Metallic materials for structural applications beyond nickel-based superalloys [J]. JOM, 2009, 61: 61 | [8] | Adams K D, DuPont J N, Marder A R. The influence of centerline sigma (σ) phase on the through-thickness toughness and tensile properties of alloy AL-6XN [J]. J. Mater. Eng. Perform., 2007, 16: 123 | [9] | Kofstad P K, Hed A Z. Oxidation of Co-25 w/o Cr at high temperatures [J]. J. Electrochem. Soc., 1969, 116: 1542 | [10] | Stringer J, Wright I G. The high-temperature oxidation of cobalt-21 wt.% chromium-3 vol.% Y2O3 alloys [J]. Oxid. Met., 1972, 5: 59 | [11] | Jones D E, Stringer J. The effect of small amounts of silicon on the oxidation of high-purity Co-25 wt.% Cr at elevated temperatures [J]. Oxid. Met., 1975, 9: 409 | [12] | Kumar A, Douglass D L. Modification of the oxidation behavior of high-purity austenitic Fe-14Cr-14Ni by the addition of silicon [J]. Oxid. Met., 1976, 10: 1 | [13] | Wang L, Xiang J H, Zhang H H, et al. High temperature oxidation behavior of three Co-20Re-xCr alloys in 3.04×10-5 Pa oxygen at 1000 and 1100 °C [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 83 | [13] | (王玲, 向军淮, 张洪华等. 3种不同Cr含量Co-20Re-Cr合金在1000和1100 °C的高温氧化行为 [J]. 中国腐蚀与防护学报, 2019, 39: 83) | [14] | Gorr B, Burk S, Trindade V B, et al. High-temperature oxidation behaviour of model Co-Re-Cr alloys at low oxygen partial pressure [J]. Mater. Corros., 2010, 61: 741 | [15] | Gorr B, Burk S, Depka T, et al. Effect of Si addition on the oxidation resistance of Co-Re-Cr-alloys: Recent attainments in the development of novel alloys [J]. Int. J. Mater. Res., 2012, 103: 24 | [16] | Wang L, Zhang T, Zhang H H, et al. Oxidation behavior of ultra-high temperature Co-20Re-25Cr-1Si alloy at 1000-1300 ℃ [J]. Chin. J. Rare Met., 2019, doi: 10.13373/j.cnki.cjrm.XY18100009 | [16] | (王玲, 张涛, 张洪华等. 超高温Co-20Re-25Cr-1Si合金1000-1300 ℃氧化行为研究 [J]. 稀有金属, 2019, doi: 10.13373/j.cnki.cjrm.XY18100009 | [17] | Douglass D L, Armijo J S. The influence of manganese and silicon on the oxidation behavior of Co-20Cr [J]. Oxid. Met., 1971, 3: 185 |
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