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Journal of Chinese Society for Corrosion and protection  2020, Vol. 40 Issue (1): 75-80    DOI: 10.11902/1005.4537.2019.149
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High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen
XU Xunhu1,HE Cuiqun2,XIANG Junhuai1(),WANG Ling1,ZHANG Honghua1,ZHENG Xiaodong1
1. Jiangxi Key Laboratory of Surface Engineering, Jiangxi Science and Technology Normal University, Nanchang 330013, China
2. School of Mechanical and Electronic Engineering, Nanchang Institute of Technology, Nanchang 330099, China
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Abstract  

The iso-thermal oxidation behavior of Co-20Re-25Cr-1Si alloy in 0.1 MPa pure oxygen at 1000~1100 ℃ for 24 h was investigated. The oxidation kinetics is irregular at both temperatures. The alloys show obvious mass loss due to the evaporation of Re element in the form of ReO3. However, at 1100 ℃ continuous mass gain occurred during the initial 15 min of oxidation, while at 1000 ℃ the alloys remained in a mass loss state during the whole oxidation process. The scales formed at both temperatures are very similar. The outermost layer is composed of CoO, while the subsequent layer is composed of CoO and CoCr2O4. The innermost layer is a thin and protective layer of Cr2O3 with a certain degree of continuity. Moreover, there is an inner oxidation zone of Si beneath the outer scales. Since the Cr2O3 layer formed at 1000 ℃ is more continuous and denser, the alloy exhibits a better oxidation resistance at 1000 ℃.

Key words:  Co-Re-Cr-Si alloy      iso-thermal oxidation      high temperature oxidation resistance      internal oxidation of Si     
Received:  08 September 2019     
ZTFLH:  TG146.418  
Fund: Science and Technology Research Program of Jiangxi Provincial Education Department(GJJ160770);Graduate Innovation Fund of Jiangxi Science and Technology Normal University(YC2018-X01)
Corresponding Authors:  Junhuai XIANG     E-mail:  xiangjunhuai@163.com

Cite this article: 

XU Xunhu,HE Cuiqun,XIANG Junhuai,WANG Ling,ZHANG Honghua,ZHENG Xiaodong. High Temperature Oxidation Behavior of Co-20Re-25Cr-1Si Alloy in 0.1 MPa Pure Oxygen. Journal of Chinese Society for Corrosion and protection, 2020, 40(1): 75-80.

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https://www.jcscp.org/EN/10.11902/1005.4537.2019.149     OR     https://www.jcscp.org/EN/Y2020/V40/I1/75

Fig.1  Microstructure of Co-20Re-25Cr-1Si alloy
PhaseCoReCrSi
Co-rich58.4216.1323.851.60
Re-rich36.7935.7027.51---
Table 1  Elemental compositions of Co- and Re-rich phases in Co-20Re-25Cr-1Si alloy (atomic fraction / %)
Fig.2  Oxidation kinetics (a) and corresponding parabolic plots (b) of Co-20Re-20Cr-1Si alloy during oxidat-ion at 1000 and 1100 ℃ in 0.1 MPa O2 for 24 h
Fig.3  Oxidation kinetics of Co-20Re-25Cr-1Si alloy during oxidation at 1000 and 1100 °C at the initial stage of 36 min
Fig.4  Surface morphologies of Co-20Re-25Cr-1Si alloy after oxidation at 1000 ℃ (a) and 1100 ℃ (b) for 24 h
Fig.5  SEM images of cross sections of Co-20Re-25Cr-1Si alloy after oxidation at 1000 ℃ (a) and 1100 ℃ (b) for 24 h
Fig.6  Element mappings in the cross sections of Co-20Re-25Cr-1Si alloy samples oxidized at 1000 ℃ (a) and 1100 ℃ (b) for 24 h
Fig.7  XRD patterns of Co-20Re-25Cr-1Si alloy oxidized at 1000 and 1100 ℃ for 24 h
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