珊瑚簇状<strong>SiO<sub>2</sub></strong> 超滑防腐涂层的制备及性能研究

doi:10.11902/1005.4537.2022.398

中国腐蚀与防护学报

2023, Vol. 43

Issue (6): 1319-1328 CSTR: 32134.14.1005.4537.2022.398 DOI: 10.11902/1005.4537.2022.398

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珊瑚簇状SiO₂ 超滑防腐涂层的制备及性能研究

张凯丽¹, 都俐俐¹, 谭军², 刘祥周², 马骥¹, 邱萍¹(

)

^1.中国石油大学 (北京) 新能源与材料学院北京 102249
^2.中国石油天然气股份有限公司长庆油田分公司第三采气厂鄂尔多斯 017300

Preparation and Properties of Slippery Anti-corrosion Coating Based on SiO₂ with Coral Cluster Morphology

ZHANG Kaili¹, DU Lili¹, TAN Jun², LIU Xiangzhou², MA Ji¹, QIU Ping¹(

)

^1.College of New Energy and Materials, China University of Petroleum Beijing, Beijing 102249, China
^2.The Third Gas Production Plant, PetroChina Changqing Oilfield Company, Ordos 017300, China

引用本文:

张凯丽, 都俐俐, 谭军, 刘祥周, 马骥, 邱萍. 珊瑚簇状SiO₂ 超滑防腐涂层的制备及性能研究[J]. 中国腐蚀与防护学报, 2023, 43(6): 1319-1328.
Kaili ZHANG, Lili DU, Jun TAN, Xiangzhou LIU, Ji MA, Ping QIU. Preparation and Properties of Slippery Anti-corrosion Coating Based on SiO₂ with Coral Cluster Morphology[J]. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1319-1328.

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摘要:

利用水油两相法制备了具有多孔珊瑚簇状形貌的SiO₂，通过与丙烯酸聚氨酯树脂共混喷涂的方法构造多孔微纳结构，探究不同SiO₂含量基底层形貌对表面二甲基硅油的贮存能力的影响，分析了所制备超滑涂层的耐机械磨损性、防污着自清洁性以及防腐特性。结果表明，随着珊瑚簇状SiO₂含量的增加，基底粗糙度增加且使得无序的基底形貌分布更均匀，更有利于提高硅油层的稳定性。其中，SiO₂与树脂质量比为25%的涂层 (标记为SiO₂-25) 的滑动角只有5.4°，并经过磨损测试后涂层仍具有优异的疏液性能和防污着自清洁性。由于填料对基底孔隙结构的影响，在经过3.5%NaCl溶液浸泡腐蚀20 d后，SiO₂-25的|Z|_{0.01 Hz}仍高达6.62×10⁹ Ω·cm²。在长期的腐蚀防护中，SiO₂-25在所测试涂层中对碳钢具有最优异防腐蚀性能。

关键词 ：超滑涂层, SiO₂, 耐机械磨损, 防腐, Q235

Abstract：

The work aims to improve the stability and mechanical wear resistance of the lubricating layer of the slippery coating, which are the key problems to be solved for long-term service of the coating. The SiO₂ with coral cluster morphology was prepared by water-oil two-phase method, and then porous micro-nanostructures were constructed by mixing SiO₂ with acrylic polyurethane resin and spraying. Meanwhile the influence of substrate morphology with different SiO₂ content on the storage capacity of dimethyl silicone oil of the coating surface was studied. The mechanical abrasion resistance, self-cleaning and anti-corrosion properties of the slippery coatings were also assessed. The results showed that with the increased of SiO₂ content, the roughness of the substrate increased, and the disordered substrate morphology was more uniform, which was more conducive to improving the stability of the silicon oil layer. The sliding angle of SiO₂-25 was 5.4°. And the SiO₂-25 even had excellent lyophobicity and self-cleaning property after wear test. Due to the influence of fillers on the pore structure of the coating, the |Z|_{0.01 Hz} of SiO₂-25 was still as high as 6.62×10⁹ Ω·cm² after 20 d of immersion in 3.5%NaCl solution, higher than SiO₂-30. Among others, the coating of SiO₂-25 has the best corrosion resistance for carbon steel for the long-term.

Key words： slippery coating SiO₂ mechanical abrasion resistance anti-corrosion Q235

收稿日期: 2022-12-15 32134.14.1005.4537.2022.398

ZTFLH:

TG174

基金资助:国家自然科学基金(52071335);国家自然科学基金(2462020YXZZ016);中国石油大学 (北京) 基金(2462015YQ0602)

通讯作者: 邱萍，E-mail: qiuping@cup.edu.cn，研究方向为腐蚀与防护

Corresponding author: QIU Ping, E-mail: qiuping@cup.edu.cn

作者简介: 张凯丽，女，1993年生，博士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2022.398 或 https://www.jcscp.org/CN/Y2023/V43/I6/1319

图1 超滑涂层制备流程图

图2 多孔珊瑚簇状SiO2和SiO2含量不同的中间态涂层表面形貌及其硅油液滴的静态接触角

图3 SiO2含量不同的中间态涂层的激光共聚焦扫描形貌图

图4 不同超滑涂层表面光学图像及静态接触角

表1 涂层在注入硅油前后的表面静态接触角和滑动角

图5 不同磨损周期超滑涂层质量损耗对比图

表2 不同磨损周期超滑涂层的质量损失增量 (mg·cm-2)

图6 不同周期磨损后超滑涂层静态接触角和滑动角对比图

图7 膨润土溶液和土壤溶液在3种超滑涂层上的滑动测试

图8 磨损前后超滑涂层表面咖啡液滴滑动过程

图9 各涂层电化学阻抗Bode图及低频模值 (|Z|0.01 Hz) 对比图

图10 SiO2-25中间态涂层和SiO2-25超滑涂层的电化学阻抗Bode图

图11 盐雾实验后涂层表面腐蚀形貌

表3 不同种类超滑涂层的耐蚀性能对比

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