碳点在金属防腐领域中的研究进展

doi:10.11902/1005.4537.2022.351

中国腐蚀与防护学报

2023, Vol. 43

Issue (6): 1237-1246 CSTR: 32134.14.1005.4537.2022.351 DOI: 10.11902/1005.4537.2022.351

综合评述

本期目录 | 过刊浏览

碳点在金属防腐领域中的研究进展

凡玉方¹^,²^,³, 张亚飞⁴, 尹刘森¹^,²^,³, 赵聪慧¹^,²^,³, 何艳宾¹^,²^,³, 张传祥¹^,²^,³(

)

^1.河南理工大学化学化工学院焦作 454003
^2.河南省煤炭绿色转化重点实验室焦作 454000
^3.煤炭安全生产与清洁高效利用省部共建协同创新中心焦作 454000
^4.宁波绿动燃料电池有限公司宁波 315300

Research Progress on Carbon Dots in Field of Metal Corrosion and Protection

FAN Yufang¹^,²^,³, ZHANG Yafei⁴, YIN Liusen¹^,²^,³, ZHAO Conghui¹^,²^,³, HE Yanbin¹^,²^,³, ZHANG Chuanxiang¹^,²^,³(

)

^1.School of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
^2.Henan Key Laboratory of Coal Green Conversion, Jiaozuo 454000, China
^3.Collaborative Innovation Center of Coal Safety Production and Clean and Efficient Utilization Jointly Built by the Ministry and the Province, Jiaozuo 454000, China
^4.Ningbo Lvdong Fuel Cell Co., Ltd., Ningbo 315300, China

引用本文:

凡玉方, 张亚飞, 尹刘森, 赵聪慧, 何艳宾, 张传祥. 碳点在金属防腐领域中的研究进展[J]. 中国腐蚀与防护学报, 2023, 43(6): 1237-1246.
Yufang FAN, Yafei ZHANG, Liusen YIN, Conghui ZHAO, Yanbin HE, Chuanxiang ZHANG. Research Progress on Carbon Dots in Field of Metal Corrosion and Protection[J]. Journal of Chinese Society for Corrosion and protection, 2023, 43(6): 1237-1246.

全文: PDF(4847 KB) HTML

摘要:

作为碳家族中新兴的零维纳米新成员，碳点 (CDs) 具有吸附能力强、毒性低、溶解性高、且表面官能团丰富等优点，引起了腐蚀防护领域研究人员的关注。本文系统阐述了碳点用作水相缓蚀剂及涂层填料方面的研究进展。介绍了不同杂原子掺杂CDs (氮掺杂，铈、氮共掺杂以及氮、硫共掺杂CDs) 对不同金属的缓蚀效果，并对缓蚀机理进行了讨论；总结了碳点作为溶剂型和水性涂层填料取得的研究成果和防腐机理。最后，概述了CDs在防腐领域所面临的挑战。

关键词 ：碳点, 缓蚀剂, 涂层填料, 防腐

Abstract：

How to avoid metal corrosion has became a key issure due to the widespread applications of various metals, therefore, it is urgent to develop the low toxicity and high-efficiency anticorrosive materials. Carbon dots (CDs), as a new zero-dimensional member of the carbon family, possesses the advantages of strong adsorption capacity, low toxicity, high solubility, good stability, and abundant surface functional groups, attract extensive attentions of researchers in the field of corrosion and protection of metallic materials. Herein, this work systematically elaborates the research progress of carbon dots especially as water-phase corrosion inhibitors and coating fillers. This review introduces corrosion inhibition effect about different heteroatom-doped carbon dots (nitrogen doped carbon dots, cerium and nitrogen co-doped carbon dots and nitrogen and sulfur co-doped carbon dots) on various metals. The corresponding corrosion inhibition mechanism can be summarized as that the protective film is formed through adsorption of CDs (physical adsorption or chemical adsorption) on surface of metals. Furthermore, we summarize the anti-corrosion mechanisms and research achievements of carbon dots as solvent-based and water-based coating fillers. By virtue of its small size and plentiful of functional groups, CDs can fill into micropores and fix the defects of coating so that to improve the comprehensive anti-corrosion performances of the composite coating. Finally, the challenges that carbon dots face in the field of corrosion and protection are also discussed.

Key words： carbon dots inhibitors filler for coating anticorrosion

收稿日期: 2022-11-14 32134.14.1005.4537.2022.351

ZTFLH:

TG174.4

基金资助:国家自然科学基金(52074109)

通讯作者: 张传祥，E-mail: zcx223@163.com，研究方向为煤基碳材料的制备及其电化学应用

Corresponding author: ZHANG Chuanxiang, E-mail: zcx223@163.com

作者简介: 凡玉方，女，1997年生，硕士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	凡玉方
	张亚飞
	尹刘森
	赵聪慧
	何艳宾
	张传祥
44.8K

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2022.351 或 https://www.jcscp.org/CN/Y2023/V43/I6/1237

图1 N-CDs对碳钢的腐蚀抑制机制图[56]

图2 N-CDs形貌及缓蚀机理图[58]

图3 N-CDs对Cu的腐蚀抑制机制图[69]

图4 Ce@N-CDs 对碳钢的缓蚀实验[61]

表1 CDs的缓蚀效率

图5 N,S-CDs对碳钢、Cu的缓蚀机理图[83,85]

图6 N,S-CDs对Al、Mg的缓蚀机理图[48, 87]

1	Wen Y H. Corrosion and protection analysis of metal materials [J]. World Nonferrous Met., 2021, (12): 192
1	文杨昊. 金属材料的腐蚀与防护分析 [J]. 世界有色金属, 2021, (12): 192
2	Hu Y L. Research progress of waterborne epoxy resin anticorrosion coatings [J]. Guangdong Chem. Ind., 2013, 40(7): 72
2	胡永玲. 水性环氧防腐涂料的研究进展 [J]. 广东化工, 2013, 40(7): 72
3	Mourya P, Banerjee S, Singh M M. Corrosion inhibition of mild steel in acidic solution by Tagetes erecta (Marigold flower) extract as a green inhibitor [J]. Corros. Sci., 2014, 85: 352 doi: 10.1016/j.corsci.2014.04.036
4	Luo W P, Luo X, Shi Y T, et al. Preparation and corrosion inhibition of super hydrophobic adsorption film of lotus leaf extract on mild steel [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 903
4	罗为平, 罗雪, 石悦婷等. Q235钢表面的超疏水吸附层形成与缓蚀研究 [J]. 中国腐蚀与防护学报, 2022, 42: 903 doi: 10.11902/1005.4537.2021.296
5	Li X H, Xu X, Lei R, et al. Synergistic inhibition effect of walnut green husk extract complex inhibitors on steel in phosphoric acid [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 358
5	李向红, 徐昕, 雷然等. 磷酸中核桃青皮复配缓蚀剂对冷轧钢的缓蚀协同效应 [J]. 中国腐蚀与防护学报, 2022, 42: 358 doi: 10.11902/1005.4537.2021.160
6	Lei R, Shi C J, Li X H. Corrosion inhibition of aluminum in HCl solution by flos sophorae immaturus extract [J] J. Chin. Soc. Corros. Prot., 2022, 42: 939
6	雷然, 石成杰, 李向红. 槐米提取物对Al在HCl溶液中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2022, 42: 939
7	Feng L J, Zhang S S, Hao L, et al. Cucumber (Cucumis sativus L.) leaf extract as a green corrosion inhibitor for carbon steel in acidic solution: electrochemical, Functional and Molecular Analysis [J]. Molecules, 2022, 27: 3826 doi: 10.3390/molecules27123826
8	El-Haddad M N. Chitosan as a green inhibitor for copper corrosion in acidic medium [J]. Int. J. Biol. Macromol., 2013, 55: 142 doi: 10.1016/j.ijbiomac.2012.12.044 pmid: 23298849
9	Qiang Y J, Zhang S T, Wang L P, et al. Understanding the adsorption and anticorrosive mechanism of DNA inhibitor for copper in sulfuric acid [J]. Appl. Surf. Sci., 2019, 492: 228 doi: 10.1016/j.apsusc.2019.06.190
10	Luan H, Meng F D, Liu L, et al. Preparation and anticorrosion performance of M-phenylenediamine-graphene oxide/organic coating [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 161
10	栾浩, 孟凡帝, 刘莉等. 间苯二胺-氧化石墨烯/有机涂层的制备及防腐性能研究 [J]. 中国腐蚀与防护学报, 2021, 41: 161
11	Jiang F W, Zhao W J, Wu Y M, et al. Anti-corrosion behaviors of epoxy composite coatings enhanced via graphene oxide with different aspect ratios [J]. Prog. Org. Coat., 2019, 127: 70
12	Pourhashem S, Vaezi M R, Rashidi A, et al. Exploring corrosion protection properties of solvent based epoxy-graphene oxide nanocomposite coatings on mild steel [J]. Corros. Sci., 2017, 115: 78 doi: 10.1016/j.corsci.2016.11.008
13	Ataei S, Khorasani S N, Neisiany R E. Biofriendly vegetable oil healing agents used for developing self-healing coatings: a review [J]. Prog. Org. Coat., 2019, 129: 77
14	Hu X X, Zhang X, Liu J, et al. Development and performance of phosphate-based protective insulation coating for non-oriented electrical steel [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 805
14	胡雄鑫, 张弦, 刘静等. 无取向电工钢用磷酸盐系绝缘环保涂层的研制及性能研究 [J]. 中国腐蚀与防护学报, 2022, 42: 805 doi: 10.11902/1005.4537.2021.250
15	Zhang C, Wang H R, Zhou Q X. Preparation and characterization of microcapsules based self-healing coatings containing epoxy ester as healing agent [J]. Prog. Org. Coat., 2018, 125: 403
16	Zhang Z Y, Guo Z X, Zhou X, et al. Preparation and performance of epoxy resin coating with benzotriazole inhibitor charged nano-halloysite tubes [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 705
16	张正阳, 郭子新, 周欣等. 纳米埃洛石装载苯并三氮唑自修复涂层研究 [J]. 中国腐蚀与防护学报, 2022, 42: 705 doi: 10.11902/1005.4537.2021.127
17	Yan S K, Song G L, Li Z X, et al. A state-of-the-art review on passivation and biofouling of Ti and its alloys in marine environments [J]. J. Mater. Sci. Technol., 2018, 34: 421 doi: 10.1016/j.jmst.2017.11.021
18	Ding Y K, Chen G M, Ni Z F, et al. Corrosion resistance of silane film modified by hexagonal boron nitride [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 864
18	丁玉康, 陈国美, 倪自丰等. 六方氮化硼改性硅烷膜耐蚀性能研究 [J]. 中国腐蚀与防护学报, 2021, 41: 864 doi: 10.11902/1005.4537.2020.176
19	Mujib S B, Mukherjee S, Ren Z K, et al. Assessing corrosion resistance of two-dimensional nanomaterial-based coatings on stainless steel substrates [J]. Roy. Soc. Open Sci., 2020, 7: 200214
20	Zhai Y. The preparation and modification of Ti particles and its influence on the property of the epoxy coating [D]. Harbin: Harbin Engineering University, 2012
20	翟阳. 纳米钛粉制备与改性及其对环氧涂层性能影响 [D]. 哈尔滨: 哈尔滨工程大学, 2012
21	Zhu J J, Zhu M Y, Zhang R H, et al. Corrosion inhibition behavior of electrochemically synthesized carbon dots on Q235 carbon steel [J]. J. Adhes. Sci. Technol., 2023, 37(13): 1997 doi: 10.1080/01694243.2022.2108271
22	Wang T X, Cao S Y, Sun Y Q, et al. Ionic liquid-assisted preparation of N, S-rich carbon dots as efficient corrosion inhibitors [J]. J. Mol. Liq., 2022, 356: 118943 doi: 10.1016/j.molliq.2022.118943
23	Hao J, Li L Y, Zhao W W, et al. Synthesis and application of CCQDs as a novel type of environmentally friendly scale inhibitor [J]. ACS Appl. Mater. Interfaces, 2019, 11: 9277 doi: 10.1021/acsami.8b19015
24	Zhang H D, Chen A Y, Gan B, et al. Corrosion protection investigations of carbon dots and polydopamine composite coating on magnesium alloy [J]. J. Magnes. Alloy., 2022, 10: 1358 doi: 10.1016/j.jma.2020.11.021
25	Li H T, He X D, Kang Z H, et al. Water-soluble fluorescent carbon quantum dots and photocatalyst design [J]. Angew. Chem. Int. Ed., 2010, 49: 4430 doi: 10.1002/anie.200906154 pmid: 20461744
26	Guo X, Wang C F, Yu Z Y, et al. Facile access to versatile fluorescent carbon dots toward light-emitting diodes [J]. Chem. Commun., 2012, 48: 2692 doi: 10.1039/c2cc17769b
27	Dong Y Q, Lin J P, Chen Y M, et al. Graphene quantum dots, graphene oxide, carbon quantum dots and graphite nanocrystals in coals [J]. Nanoscale, 2014, 6: 7410 doi: 10.1039/c4nr01482k pmid: 24875280
28	He M Q, Guo X R, Huang J Z, et al. Mass production of tunable multicolor graphene quantum dots from an energy resource of coke by a one-step electrochemical exfoliation [J]. Carbon, 2018, 140: 508 doi: 10.1016/j.carbon.2018.08.067
29	Kang S, Kim K M, Son Y, et al. Graphene oxide quantum dots derived from coal for bioimaging: facile and green approach [J]. Sci. Rep., 2019, 9: 4101 doi: 10.1038/s41598-018-37479-6 pmid: 30858383
30	Zhang Y T, Li K K, Ren S Z, et al. Coal-derived graphene quantum dots produced by ultrasonic physical tailoring and their capacity for Cu(II) detection [J]. ACS Sustain. Chem. Eng., 2019, 7: 9793 doi: 10.1021/acssuschemeng.8b06792
31	Zhou X J, Zhang Y, Wang C, et al. Photo-Fenton reaction of graphene oxide: a new strategy to prepare graphene quantum dots for DNA cleavage [J]. ACS Nano, 2012, 6: 6592 doi: 10.1021/nn301629v pmid: 22813062
32	Zhu H, Wang X L, Li Y L, et al. Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties [J]. Chem. Commun., 2009, (34): 5118
33	Zhao Q L, Zhang Z L, Huang B H, et al. Facile preparation of low cytotoxicity fluorescent carbon nanocrystals by electrooxidation of graphite [J]. Chem. Commun., 2008, (41): 5116
34	Wang J P, Sahu S, Sonkar S K, et al. Versatility with carbon dots-from overcooked BBQ to brightly fluorescent agents and photocatalysts [J]. RSC Adv., 2013, 3: 15604 doi: 10.1039/c3ra42302f
35	Yang S T, Wang X, Wang H F, et al. Carbon dots as nontoxic and high-performance fluorescence imaging agents [J]. J. Phys. Chem., 2009, 113C: 18110
36	Xu L Q, Yang W J, Neoh K G, et al. Dopamine-induced reduction and functionalization of graphene oxide nanosheets [J]. Macromolecules, 2010, 43: 8336 doi: 10.1021/ma101526k
37	Zhang Z Q. Study on the preparation and application of carbon nano-dots from Chinese cabbage [D]. Changchun: Jilin University, 2022
37	张镇乾. 大白菜制备碳纳米点及其应用研究 [D]. 长春: 吉林大学, 2022
38	Zhao H B, Leng T C, Liu X M, et al. Preparation of kiwifruit biomass carbon dots by microwave method and application of Fe³⁺ detection in honeysuckle [J]. Sci. Technol. Food Ind., 2022, 43(3): 246
38	赵鸿宾, 冷天翠, 刘晓梦等. 微波法制备猕猴桃生物质碳点及应用于金银花中Fe³⁺的检测 [J]. 食品工业科技, 2022, 43(3): 246
39	Liu S H, Liu Z C, Li Q F, et al. Facile synthesis of carbon dots from wheat straw for colorimetric and fluorescent detection of fluoride and cellular imaging [J]. Spectrochim. Acta, 2021, 246A: 118964
40	Hu S L, Wei Z J, Chang Q, et al. A facile and green method towards coal-based fluorescent carbon dots with photocatalytic activity [J]. Appl. Surf. Sci., 2016, 378: 402 doi: 10.1016/j.apsusc.2016.04.038
41	Kovalchuk A, Huang K W, Xiang C S, et al. Luminescent polymer composite films containing coal-derived graphene quantum dots [J]. ACS Appl. Mater. Interfaces, 2015, 7: 26063 doi: 10.1021/acsami.5b06057
42	Thiyagarajan S K, Raghupathy S, Palanivel D, et al. Fluorescent carbon nano dots from lignite: unveiling the impeccable evidence for quantum confinement [J]. Phys. Chem. Chem. Phys., 2016, 18: 12065 doi: 10.1039/c6cp00867d pmid: 27067247
43	Geng B J, Yang D W, Zheng F F, et al. Facile conversion of coal tar to orange fluorescent carbon quantum dots and their composite encapsulated by liposomes for bioimaging [J]. New J. Chem., 2017, 41: 14444 doi: 10.1039/C7NJ03005C
44	Singamaneni S R, van Tol J, Ye R Q, et al. Intrinsic and extrinsic defects in a family of coal-derived graphene quantum dots [J]. Appl. Phys. Lett., 2015, 107: 212402 doi: 10.1063/1.4936204
45	Yang L, Wen J X, Li K J, et al. Carbon quantum dots: comprehensively understanding of the internal quenching mechanism and application for catechol detection [J]. Sens. Actuators, 2021, 333B: 129557
46	Wu X W. Synthesis of carbon dots and their applications in biosensing and pollutant detection [D]. Changchun: Jilin University, 2022
46	母晓玮. 碳点的合成及其在生物传感和污染物检测中的应用 [D]. 长春: 吉林大学, 2022
47	Ma Y, Di H H, Yu Z X, et al. Fabrication of silica-decorated graphene oxide nanohybrids and the properties of composite epoxy coatings research [J]. Appl. Surf. Sci., 2016, 360: 936 doi: 10.1016/j.apsusc.2015.11.088
48	Cen H Y, Zhang X, Zhao L, et al. Carbon dots as effective corrosion inhibitor for 5052 aluminium alloy in 0.1 M HCl solution [J]. Corros. Sci., 2019, 161: 108197 doi: 10.1016/j.corsci.2019.108197
49	Wan S, Chen H K, Liao B K, et al. Adsorption and anticorrosion mechanism of glucose-based functionalized carbon dots for copper in neutral solution [J]. J. Taiwan Inst. Chem. Eng., 2021, 129: 289 doi: 10.1016/j.jtice.2021.10.001
50	Qiang Y J, Zhang S T, Zhao H C, et al. Enhanced anticorrosion performance of copper by novel N-doped carbon dots [J]. Corros. Sci., 2019, 161: 108193 doi: 10.1016/j.corsci.2019.108193
51	Zhu M Y, Guo L, He Z Y, et al. Insights into the newly synthesized N-doped carbon dots for Q235 steel corrosion retardation in acidizing media: a detailed multidimensional study [J]. J. Colloid Interface Sci., 2022, 608: 2039 doi: 10.1016/j.jcis.2021.10.160
52	Daoud D, Douadi T, Hamani H, et al. Corrosion inhibition of mild steel by two new S-heterocyclic compounds in 1 M HCl: experimental and computational study [J]. Corros. Sci., 2015, 94: 21 doi: 10.1016/j.corsci.2015.01.025
53	Wang J, Wang S Y, Zhang C, et al. Effect of nitrogen doping on corrosion inhibition performance of carbon nanoparticles [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 85
53	王晶, 王斯琰, 张崇等. 氮掺杂对碳纳米颗粒缓蚀性能的影响 [J]. 中国腐蚀与防护学报, 2022, 42: 85
54	Hmamou D B, Salghi R, Zarrouk A, et al. Weight loss, electrochemical, quantum chemical calculation, and molecular dynamics simulation studies on 2-(benzylthio)-1, 4, 5-triphenyl-1H-imidazole as an inhibitor for carbon steel corrosion in hydrochloric acid [J]. Ind. Eng. Chem. Res., 2013, 52: 14315 doi: 10.1021/ie401034h
55	Khan G, Basirun W J, Kazi S N, et al. Electrochemical investigation on the corrosion inhibition of mild steel by Quinazoline Schiff base compounds in hydrochloric acid solution [J]. J. Colloid Interface Sci., 2017, 502: 134 doi: 10.1016/j.jcis.2017.04.061
56	Cui M J, Ren S M, Xue Q J, et al. Carbon dots as new eco-friendly and effective corrosion inhibitor [J]. J. Alloy. Compd., 2017, 726: 680 doi: 10.1016/j.jallcom.2017.08.027
57	Wei J Y. Study on the corrosion inhibition performance of levodopa derivatives [D]. Shenyang: Shenyang University of Chemical Technology, 2021
57	魏佳煜. 左旋多巴衍生物缓蚀性能研究 [D]. 沈阳: 沈阳化工大学, 2021
58	Ye Y W, Yang D P, Chen H, et al. A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment [J]. J. Hazard. Mater., 2020, 381: 121019 doi: 10.1016/j.jhazmat.2019.121019
59	Ye Y W, Jiang Z L, Zou Y J, et al. Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions [J]. J. Mater. Sci. Technol., 2020, 43: 144 doi: 10.1016/j.jmst.2020.01.025
60	Zhu M Y, He Z Y, Guo L, et al. Corrosion inhibition of eco-friendly nitrogen-doped carbon dots for carbon steel in acidic media: performance and mechanism investigation [J]. J. Mol. Liq., 2021, 342: 117583 doi: 10.1016/j.molliq.2021.117583
61	Niu F H, Zhou G G, Zhu J W, et al. Inhibition behavior of nitrogen-doped carbon dots on X80 carbon steel in acidic solution [J]. J. Mol. Liq., 2021, 339: 117171 doi: 10.1016/j.molliq.2021.117171
62	Shi Y Y, Niu F H, Zhu J W, et al. Inhibition behavior of nitrogen-doped carbon dots on X80 carbon steel in acidic solution [A]. Proceedings of 2021 8th Materials and Corrosion Protection Conference & 2021 2nd Reinforced Concrete Durability and Facility Service Safety Conference [C]. Guiyang, 2021: 128
62	史艳艳, 牛翻红, 朱建伟等. 在酸性溶液中氮掺杂碳点对X80碳钢缓蚀行为的实验研究 [A]. 2021第八届海洋材料与腐蚀防护大会暨2021第二届钢筋混凝土耐久性与设施服役安全大会 [C]. 贵阳, 2021: 128
63	Xiao H, Dong S Y, Yuan X J, et al. Corrosion inhibition performance and mechanism of N-doped carbon dots to Q235 steel [J]. J. Funct. Mater., 2021, 52: 8138 doi: 10.3969/j.issn.1001-9731.2021.08.019
63	肖晗, 董社英, 袁小静等. 氮掺杂碳点对Q235钢的缓蚀性能及机理研究 [J]. 功能材料, 2021, 52: 8138
64	Zhang Y, Zhang S T, Tan B C, et al. Solvothermal synthesis of functionalized carbon dots from amino acid as an eco-friendly corrosion inhibitor for copper in sulfuric acid solution [J]. J. Colloid Interface Sci., 2021, 604: 1 doi: 10.1016/j.jcis.2021.07.034
65	Cui M J, Qiang Y J, Wang W, et al. Microwave synthesis of eco-friendly nitrogen doped carbon dots for the corrosion inhibition of Q235 carbon steel in 0.1 M HCl [J]. Int. J. Electrochem. Sci., 2021, 16: 151019 doi: 10.20964/2021.01.47
66	Liu Q, Zhou T Y. Inhibition behavior of graphene quantum dots for carbon steel in HCl solution [J]. Corros. Prot., 2015, 36: 152
66	刘青, 周桃玉. 盐酸溶液中石墨烯量子点对碳钢的缓蚀性能 [J]. 腐蚀与防护, 2015, 36: 152
67	Wang M. Preparation and corrosion inhibition of graphene oxide quantum dots [D]. Wuhan: Huazhong University of Science & Technology, 2019
67	王梦. 氧化石墨烯量子点的制备及缓蚀性能研究 [D]. 武汉: 华中科技大学, 2019
68	Xu Q J, Ge K, Zhang S T, et al. Understanding the adsorption and inhibitive properties of Nitrogen-Doped Carbon Dots for copper in 0.5 M H₂SO₄ solution [J]. J. Taiwan Inst. Chem. Eng., 2021, 125: 23 doi: 10.1016/j.jtice.2021.05.050
69	Zhou Q Z, Yuan G H, Lin M J, et al. Large-scale electrochemical fabrication of nitrogen-doped carbon quantum dots and their application as corrosion inhibitor for copper [J]. J. Mater. Sci., 2021, 56: 12909 doi: 10.1007/s10853-021-06102-x
70	Lorite I, Romero J J, Fernandez J F. Influence of the nanoparticles agglomeration state in the quantum-confinement effects: experimental evidences [J]. AIP Adv., 2015, 5: 037105
71	Li Y, Liu H, Liu X Q, et al. Free-radical-assisted rapid synthesis of graphene quantum dots and their oxidizability studies [J]. Langmuir, 2016, 32: 8641 doi: 10.1021/acs.langmuir.6b02422 pmid: 27506575
72	Chen J Q, Hou D L, Xiao H, et al. Corrosion inhibition on carbon steel in acidic solution by carbon dots prepared from waste longan shells [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 629
72	陈佳起, 侯道林, 肖晗等. 酸性介质中桂圆壳碳点对碳钢的缓蚀性能研究 [J]. 中国腐蚀与防护学报, 2022, 42: 629 doi: 10.11902/1005.4537.2021.214
73	Qian J H, Li G P. Status of development of rare earth industry in China [J]. Chin. J. Rare Met., 2003, 27: 813
73	钱九红, 李国平. 中国稀土产业的发展现状 [J]. 稀有金属, 2003, 27: 813
74	Liu Z X, Hao X Y, Li Y, et al. Novel Ce@N-CDs as green corrosion inhibitor for metal in acidic environment [J]. J. Mol. Liq., 2022, 349: 118155 doi: 10.1016/j.molliq.2021.118155
75	Saraswat V, Yadav M. Carbon dots as green corrosion inhibitor for mild steel in HCl solution [J]. ChemistrySelect, 2020, 5: 7347 doi: 10.1002/slct.v5.25
76	Cui M J, Ren S M, Zhao H C, et al. Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution [J]. Appl. Surf. Sci., 2018, 443: 145 doi: 10.1016/j.apsusc.2018.02.255
77	Luo J X, Cheng X, Zhong C F, et al. Effect of reaction parameters on the corrosion inhibition behavior of N-doped carbon dots for metal in 1 M HCl solution [J]. J. Mol. Liq., 2021, 338: 116783 doi: 10.1016/j.molliq.2021.116783
78	Ye Y W, Zhang D W, Zou Y J, et al. A feasible method to improve the protection ability of metal by functionalized carbon dots as environment-friendly corrosion inhibitor [J]. J. Cleaner Prod., 2020, 264: 121682 doi: 10.1016/j.jclepro.2020.121682
79	Yang D P, Ye Y W, Su Y, et al. Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel [J]. J. Cleaner Prod., 2019, 229: 180 doi: 10.1016/j.jclepro.2019.05.030
80	Cao S Y, Liu D, Wang T X, et al. Nitrogen-doped carbon dots as high-effective inhibitors for carbon steel in acidic medium [J]. Colloids Surf., 2021, 616A: 126280
81	Liu Z X, Ye Y W, Chen H. Corrosion inhibition behavior and mechanism of N-doped carbon dots for metal in acid environment [J]. J. Cleaner Prod., 2020, 270: 122458 doi: 10.1016/j.jclepro.2020.122458
82	Ye Y W, Zou Y J, Jiang Z L, et al. An effective corrosion inhibitor of N doped carbon dots for Q235 steel in 1 M HCl solution [J]. J. Alloy. Compd., 2020, 815: 152338 doi: 10.1016/j.jallcom.2019.152338
83	Cen H Y, Chen Z Y, Guo X P. N, S co-doped carbon dots as effective corrosion inhibitor for carbon steel in CO₂-saturated 3.5% NaCl solution [J]. J. Taiwan Inst. Chem. Eng., 2019, 99: 224 doi: 10.1016/j.jtice.2019.02.036
84	Luo J X, Cheng X, Chen X H, et al. The effect of N and S ratios in N, S co-doped carbon dot inhibitor on metal protection in 1 M HCl solution [J]. J. Taiwan Inst. Chem. Eng., 2021, 127: 387 doi: 10.1016/j.jtice.2021.08.023
85	Zhang Y, Tan B C, Zhang X, et al. Synthesized carbon dots with high N and S content as excellent corrosion inhibitors for copper in sulfuric acid solution [J]. J. Mol. Liq., 2021, 338: 116702 doi: 10.1016/j.molliq.2021.116702
86	Liu T T. Systhesis and application of heteroatom doped carbon dots based on Chinese herbal medicines [D]. Xinxiang: Henan Normal University, 2020
86	刘甜甜. 基于中草药材合成杂原子掺杂碳点及其应用 [D]. 新乡: 河南师范大学, 2020
87	Liang P, Li G X, Wang Z Y, et al. Nitrogen/sulfur co‐doped carbon dots for enhancing anti‐corrosion performance of Mg alloy in NaCl solution [J]. ChemistrySelect, 2021, 6(41): 11337 doi: 10.1002/slct.v6.41
88	Liu J, Wang D P, Gao L X, et al. Synergism between cerium nitrate and sodium dodecylbenzenesulfonate on corrosion of AA5052 aluminium alloy in 3 wt.% NaCl solution [J]. Appl. Surf. Sci., 2016, 389: 369 doi: 10.1016/j.apsusc.2016.07.107
89	Shi H W, Han E H, Liu F C. Corrosion protection of aluminium alloy 2024-T3 in 0.05 M NaCl by cerium cinnamate [J]. Corros. Sci., 2011, 53: 2374 doi: 10.1016/j.corsci.2011.03.012
90	Abdallah M, Sobhi M, Altass H M. Corrosion inhibition of aluminum in hydrochloric acid by pyrazinamide derivatives [J]. J. Mol. Liq., 2016, 223: 1143 doi: 10.1016/j.molliq.2016.09.006
91	Moattari R M, Rahimi S, Rajabi L, et al. Statistical investigation of lead removal with various functionalized carboxylate ferroxane nanoparticles [J]. J. Hazard. Mater., 2015, 283: 276 doi: 10.1016/j.jhazmat.2014.08.025 pmid: 25285999
92	Shen G X, Chen Y C, Lin L, et al. Study on a hydrophobic nano-TiO₂ coating and its properties for corrosion protection of metals [J]. Electrochim. Acta, 2005, 50: 5083 doi: 10.1016/j.electacta.2005.04.048
93	Zhu C, Fu Y J, Liu C G, et al. Carbon dots as fillers inducing healing/self‐healing and anticorrosion properties in polymers [J]. Adv. Mater., 2017, 29: 1701399 doi: 10.1002/adma.v29.32
94	Du F F. Anti-corrosion performance of novel epoxy composite coatings filled with N-doped carbon nanodots [D]. Qingdao: Qingdao University of Science & Technology, 2022
94	杜非凡. 新型氮掺杂碳纳米点环氧复合涂层防腐性能研究 [D]. 青岛: 青岛科技大学, 2022
95	Pourhashem S, Ghasemy E, Rashidi A, et al. Corrosion protection properties of novel epoxy nanocomposite coatings containing silane functionalized graphene quantum dots [J]. J. Alloy. Compd., 2018, 731: 1112 doi: 10.1016/j.jallcom.2017.10.150
96	Pourhashem S, Rashidi A, Vaezi M R. Comparing the corrosion protection performance of graphene nanosheets and graphene quantum dots as nanofiller in epoxy coatings [J]. Ind. Lubr. Tribol., 2019, 71: 653 doi: 10.1108/ILT-05-2018-0186
97	Ramezanzadeh B, Karimi B, Ramezanzadeh M, et al. Synthesis and characterization of polyaniline tailored graphene oxide quantum dot as an advance and highly crystalline carbon-based luminescent nanomaterial for fabrication of an effective anti-corrosion epoxy system on mild steel [J]. J. Taiwan Inst. Chem. Eng., 2019, 95: 369 doi: 10.1016/j.jtice.2018.07.041
98	Ren S M, Cui M J, Zhao H C, et al. Effect of nitrogen-doped carbon dots on the anticorrosion properties of waterborne epoxy coatings [J]. Surf. Topogr.: Metrol. Prop., 2018, 6: 024003
99	Wang J, Du P, Zhao H C, et al. Novel nitrogen doped carbon dots enhancing the anticorrosive performance of waterborne epoxy coatings [J]. Nanoscale Adv., 2019, 1: 3443 doi: 10.1039/c9na00155g pmid: 36133544
100	Wan S, Chen H K, Cai G Y, et al. Functionalization of h-BN by the exfoliation and modification of carbon dots for enhancing corrosion resistance of waterborne epoxy coating [J]. Prog. Org. Coat., 2022, 165: 106757

[1]	张凯丽, 都俐俐, 谭军, 刘祥周, 马骥, 邱萍. 珊瑚簇状SiO₂ 超滑防腐涂层的制备及性能研究[J]. 中国腐蚀与防护学报, 2023, 43(6): 1319-1328.
[2]	王泉润, 侯进, 侯保荣, 田惠文. 气相缓蚀剂分析方法研究进展[J]. 中国腐蚀与防护学报, 2023, 43(6): 1189-1202.
[3]	吕正平, 李缘, 刘晓航, 崔中雨, 崔洪芝, 王昕, 逄昆, 李燚周. 酸性氯化钠溶液中硝酸钠和硫脲对7075铝合金缝隙腐蚀的协同缓蚀作用[J]. 中国腐蚀与防护学报, 2023, 43(6): 1367-1374.
[4]	董红梅, 李宝毅, 冉博元, 王琦, 牛宇岚, 丁莉峰, 强玉杰. 一种环保型缓蚀剂利拉利汀对紫铜在硫酸中的缓蚀机理研究[J]. 中国腐蚀与防护学报, 2023, 43(5): 1031-1040.
[5]	何静, 于航, 傅梓瑛, 岳鹏辉. 水溶性缓蚀剂对建筑管道用Q235钢腐蚀行为的影响[J]. 中国腐蚀与防护学报, 2023, 43(5): 1041-1048.
[6]	李树丽, 邓书端, 李向红. 铝植物缓蚀剂的研究进展与展望[J]. 中国腐蚀与防护学报, 2023, 43(5): 929-947.
[7]	陈肖寒, 白杨, 王志超, 陈从棕, 张勇, 崔显林, 左娟娟, 王同良. 低表面处理环氧防腐底漆的制备及其耐蚀性研究[J]. 中国腐蚀与防护学报, 2023, 43(5): 1126-1132.
[8]	周浩, 尤世界, 王胜利. 铜质文物在CO₂ 环境中的腐蚀行为及缓蚀剂研究[J]. 中国腐蚀与防护学报, 2023, 43(5): 1049-1056.
[9]	邹文杰, 丁立, 张雪姣, 陈均. 环氧树脂/有机硅氧烷改性阳离子丙烯酸乳液复合涂层的研究[J]. 中国腐蚀与防护学报, 2023, 43(4): 922-928.
[10]	孟凡帝, 高浩东, 刘莉, 崔宇, 刘叡, 王福会. 适用于深海压力-流体耦合环境的玄武岩有机防腐涂层的制备及性能研究[J]. 中国腐蚀与防护学报, 2023, 43(4): 704-712.
[11]	周坤, 柳鑫华, 刘帅. 在酸性介质中脐橙皮提取物对不锈钢的缓蚀作用[J]. 中国腐蚀与防护学报, 2023, 43(3): 619-629.
[12]	黄苗, 王丽姿, 马晓青, 李向红. 核桃青皮提取物与Nd(NO₃)₃对Al在HCl溶液中的缓蚀协同效应[J]. 中国腐蚀与防护学报, 2023, 43(3): 471-480.
[13]	连衍成, 梁富源, 贺建超, 李瑨, 武俊伟, 冷雪松. 超疏水聚四氟乙烯材料制备工艺的研究进展[J]. 中国腐蚀与防护学报, 2023, 43(2): 231-241.
[14]	于芳, 王翔, 张昭. 纳米填料在环氧防腐涂层中的应用研究进展[J]. 中国腐蚀与防护学报, 2023, 43(2): 220-230.
[15]	赵艳亮, 赵景茂. 层状双金属氢氧化物对镁合金的保护作用及自愈性能研究进展[J]. 中国腐蚀与防护学报, 2023, 43(1): 1-5.

Viewed

Full text

Abstract

Cited

Shared

Discussed