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中国腐蚀与防护学报  2021, Vol. 41 Issue (5): 697-704    DOI: 10.11902/1005.4537.2020.155
  研究报告 本期目录 | 过刊浏览 |
沿海变电站设备腐蚀状况及其腐蚀机理与防护
夏晓健1, 蔡建宾1, 林德源1, 万芯瑗1, 李扬森2, 张标华3, 陈云翔1, 韩纪层1, 邹智敏4, 姜春海4()
1.国网福建省电力有限公司电力科学研究院 福州 350007
2.国网福建省电力有限公司 福州 350001
3.福建省亿力建设工程有限公司福建电力调试分公司 福州 350007
4.厦门理工学院 福建省功能材料与应用重点实验室 厦门 361024
Corrosion Status, Corrosion Mechanisms and Anti-corrosion Measures in Coastal Substations
XIA Xiaojian1, CAI Jianbin1, LIN Deyuan1, WAN Xinyuan1, LI Yangsen2, ZHANG Biaohua3, CHEN Yunxiang1, HAN Jiceng1, ZOU Zhimin4, JIANG Chunhai4()
1.State Grid Fujian Electric Power Research Institute, Fuzhou 350007, China
2.State Grid Fujian Electric Power Corporation, Fuzhou 350001, China
3.Fujian Power Construction Engineering Co. Ltd. , Fujian Electric Power Commissioning Branch, Fuzhou 350007, China
4.Fujian Key Laboratory of Functional Materials and Applications, Xiamen University of Technology, Xiamen 361024, China
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摘要: 

基于现场勘查与文献调研,介绍了沿海变电站主要设备的腐蚀状况,分析了不同材质金属构件的腐蚀机理,总结了主要金属构件的现有腐蚀防护措施及其有效性。沿海变电站金属设备的腐蚀与大气中含有较高浓度的Cl-、SO2和H2S等气体密切相关。有针对性地联合应用多种防腐蚀技术,包括材料自身改性、表面处理以及涂覆防腐涂料等,可最大限度地提高变电站金属设备的防腐效果。

关键词 沿海变电站金属腐蚀防腐措施大气腐蚀    
Abstract

The atmospheric corrosion status of major metallic equipment used in transformer substations in coastal areas, the relevant corrosion mechanisms and the current anti-corrosion measures are summarized based on on-site inspections and literature survey. It is revealedthat the corrosion of metallic equipment is intimately correlated to the high Cl-, SO2 and H2S concentrations in the atmosphere of coastal areas. The combination of various anti-corrosion technologies, including material modification, surface treatment and anti-corrosion coatings, may maximize the comprehensive anti-corrosion effect.

Key wordssubstations in coastal area    metal corrosion    anti-corrosion measure    atmospheric corrosion
收稿日期: 2020-08-28     
ZTFLH:  TG172  
基金资助:国网福建省电力有限公司科技项目(521304190001)
通讯作者: 姜春海     E-mail: chjiang@xmut.edu.cn
Corresponding author: JIANG Chunhai     E-mail: chjiang@xmut.edu.cn
作者简介: 夏晓健,男,1988年生,博士,高级工程师

引用本文:

夏晓健, 蔡建宾, 林德源, 万芯瑗, 李扬森, 张标华, 陈云翔, 韩纪层, 邹智敏, 姜春海. 沿海变电站设备腐蚀状况及其腐蚀机理与防护[J]. 中国腐蚀与防护学报, 2021, 41(5): 697-704.
Xiaojian XIA, Jianbin CAI, Deyuan LIN, Xinyuan WAN, Yangsen LI, Biaohua ZHANG, Yunxiang CHEN, Jiceng HAN, Zhimin ZOU, Chunhai JIANG. Corrosion Status, Corrosion Mechanisms and Anti-corrosion Measures in Coastal Substations. Journal of Chinese Society for Corrosion and protection, 2021, 41(5): 697-704.

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2020.155      或      https://www.jcscp.org/CN/Y2021/V41/I5/697

图1  沿海工业环境GIS等设备腐蚀形貌
图2  绝缘子法兰面表面及密封件腐蚀
图3  某变电站构件腐蚀
1 Wang T P, Li H Q, Sun M C, et al. Corrosion and peeling off behavior of Ag coating on bushing wiring board for 66 kV HGIS in a coastal substation [J]. Corros. Sci. Prot. Technol., 2019, 31: 159
1 王天鹏, 李宏强, 孙明成等. 沿海变电站66 kV HGIS套管接线板镀银层腐蚀剥落原因分析 [J]. 腐蚀科学与防护技术, 2019, 31: 159
2 Fang Y J, Liu S, Wang X W, et al. Study on corrosion status and anti-corrosion measures of substations in coastal areas [J]. Electr. Technol., 2012, 19(12): 97
2 方乙君, 柳松, 王雄文等. 沿海地区变电站腐蚀现状及防腐措施研究 [J]. 电气技术, 2012, 19(12): 97
3 Cui T F, Liu D X, Xu X C, et al. Accelerated test method for high strength aluminum alloy in typical coastal area [J]. Equip. Environ. Eng., 2020, 17(5): 33
3 崔腾飞, 刘道新, 徐星辰等. 高强度铝合金典型沿海地区腐蚀行为加速试验方法研究 [J]. 装备环境工程, 2020, 17(5): 33
4 Zhou G, Lin D Y, Han J C, et al. Failure mechanism of 10 kV aerial insulation line of overhead distribution system in coastal and typhoon environment [J]. Corros. Sci. Prot. Technol., 2019, 31: 643
4 周刚, 林德源, 韩纪层等. 沿海及强台风环境下10 kV配网架空绝缘导线的失效机理分析 [J]. 腐蚀科学与防护技术, 2019, 31: 643
5 Liu Z C. Research on initial corrosion behavior of typical metal materials in costal atmospheric environment [D]. Guangzhou: South China University of Technology, 2016
5 刘争春. 沿海大气环境下典型金属材料初期腐蚀行为研究 [D]. 广州: 华南理工大学, 2016
6 Chen J J, Li M, Wang J, et al. Common style of metallic components corrosion in substation and its solution [J]. Inner Mongolia Electr. Power, 2013, 31(1): 7
6 陈军君, 李明, 王军等. 变电站金属构件的常见腐蚀形式及解决措施 [J]. 内蒙古电力技术, 2013, 31(1): 7
7 Yang D N, Wang C, Wang Z Y, et al. Atmospheric corrosion of common metals used in transformer substation and protection measures [J]. Equip. Environ. Eng., 2016, 13(1): 126
7 杨大宁, 汪川, 王振尧等. 变电站常用金属的大气腐蚀行为及其防护 [J]. 装备环境工程, 2016, 13(1): 126
8 Lu S M. Reasons and antiseptic of transfer station metal corrosion in costal atmospheric environment [D]. Guangzhou: South China University of Technology, 2017
8 卢思敏. 沿海变电站金属材料的腐蚀成因及防腐 [D]. 广州: 华南理工大学, 2017
9 Zhang L, Wang Z Y, Zhao C Y, et al. Study on corrosion behavior of carbon steel and weathering steel in salt spray test [J]. Equip. Environ. Eng., 2014, 11(1): 1
9 张琳, 王振尧, 赵春英等. 碳钢和耐候钢在盐雾环境下的腐蚀行为研究 [J]. 装备环境工程, 2014, 11(1): 1
10 Hœrlé S, Mazaudier F, Dillmann P, et al. Advances in understanding atmospheric corrosion of iron. II. Mechanistic modelling of wet-dry cycles [J]. Corros. Sci., 2004, 46: 1431
11 Cheng L, Ma G, Chen X, et al. Corrosion and protection of steel structures for transmission and distribution projuct [J]. Steel Const., 2014, 29(2): 76
11 程灵, 马光, 陈新等. 输变电工程中钢结构的腐蚀与防护 [J]. 钢结构, 2014, 29(2): 76
12 Yang D N, Zhao S Y, Fu C F, et al. Service conditions of protective coatings of grid substations in Hainan province [J]. Corros. Prot., 2016, 37: 249
12 杨大宁, 赵书彦, 符传福等. 海南电网变电站金属架构防护涂层的使用情况 [J]. 腐蚀与防护, 2016, 37: 249
13 Yin X T, Li W H, Li L, et al. Research status of corrosion behavior and anticorrosion measures of aluminum alloy under different climate in China [J]. Mater. Prot., 2019, 52(3): 111
13 尹学涛, 李文翰, 李丽等. 铝合金在我国不同气候条件下的腐蚀行为及防腐蚀措施的研究现状 [J]. 材料保护, 2019, 52(3): 111
14 Oesch S, Faller M. Environmental effects on materials: The effect of the air pollutants SO2, NO2, NO and O3 on the corrosion of copper, zinc and aluminum: A short literature survey and results of laboratory exposures [J]. Corros. Sci., 1997, 39: 1505
15 Lv W Y, Liu S N, Su W, et al. Corrosion and protection of copper materials in transformer substation under heavy industry circumstance [J]. Clean. World, 2013, 29(11): 9
15 吕旺燕, 刘世念, 苏伟等. 重工业污染下变电站铜构件的腐蚀特征及防治对策 [J]. 清洗世界, 2013, 29(11): 9
16 Ren H T, Yin Z H, Wang P, et al. Study status of H2S influence on copper corrosion in grids [J]. Corros. Prot., 2014, 35: 1074
16 任汉涛, 银朝晖, 王平等. 电网铜材在含H2S大气中的腐蚀研究现状 [J]. 腐蚀与防护, 2014, 35: 1074
17 Li X, Guo J K. Cause and protection of corrosion of copper materials in a 35 kV indoor transformer substation [J]. Corros. Prot., 2004, 25: 133
17 李兴, 郭军科. 35 kV室内变电站铜材腐蚀的原因分析与对策 [J]. 腐蚀与防护, 2004, 25: 133
18 Reid M, Punch J, Ryan C, et al. Microstructural development of copper sulfide on copper exposed to humid H2S [J]. J. Electrochem. Soc., 2007, 154: C209
19 Zhang Z Y, Yue Z W, Jiang B, et al. Application status of hot dip galvanizing in corrosion protection of steel structure [J]. Mater. Prot., 2019, 52(12): 135
19 张振岳, 岳增武, 姜波等. 热浸镀锌产业在钢结构腐蚀防护中的应用现状 [J]. 材料保护, 2019, 52(12): 135
20 Zhao S Y, Tong X H, Liu F C, et al. Corrosion resistance three Zn-rich epoxy coatings [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 563
20 赵书彦, 童鑫红, 刘福春等. 环氧富锌涂层防腐蚀性能研究 [J]. 中国腐蚀与防护学报, 2019, 39: 563
21 Yang F, Liang Y C, Kuang Y J, et al. Corrosion behavior of galvanized steel in Dongguan atmosphere and simulated atmosphere [J]. Corros. Prot., 2017, 38: 767
21 杨帆, 梁永纯, 匡尹杰等. 镀锌钢在东莞大气及模拟大气中的腐蚀行为 [J]. 腐蚀与防护, 2017, 38: 767
22 Xu L. Study of anticorrosion performance and mechanism of cold galvanizing coating on steel Substrate [D]. Hefei: University of Science and Technology of China, 2019
22 徐龙. 钢基材表面冷涂锌涂层的防腐蚀性能和机理研究 [D]. 合肥: 中国科学技术大学, 2019
23 Wang G R, Zheng H P, Cai H Y, et al. Failure process of epoxy coating subjected test of alternating immersion in artificial seawater and dry in air [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 572
23 王贵容, 郑宏鹏, 蔡华洋等. 环氧防腐涂料在模拟海水干湿交替条件下的失效过程 [J]. 中国腐蚀与防护学报, 2019, 39: 572
24 Song X. Discussion on some issues of waterborne coatings applied in heavy-duty anticorrosion [J]. Coat. Prot., 2018, 39(9): 46
24 宋笑. 水性涂料重防腐应用若干问题探讨 [J]. 涂层与防护, 2018, 39(9): 46
25 Bai Y F, Zhao Z X, Sun W P, et al. Application status of heavy-duty anticorrosive coatings for coastal power plants [J]. Electroplat. Finish., 2019, 38: 579
25 白玉峰, 赵忠贤, 孙伟鹏等. 沿海电厂重防腐涂料的应用状况 [J]. 电镀与涂饰, 2019, 38: 579
26 Liu R X. Discussion of corrosion inhibitor of coatings [J]. Mod. Paint Finish., 2011, 14(2): 19
26 刘仁新. 试论涂料缓蚀剂 [J]. 现代涂料与涂装, 2011, 14(2): 19
27 Wang X, Ren S F, Zhang D X, et al. Inhibition effect of soybean meal extract on corrosion of Q235 steel in hydrochloric acid medium [J]. J. Chin. Soc. Corros. Prot., 2019, 39: 267
27 王霞, 任帅飞, 张代雄等. 豆粕提取物在盐酸中对Q235钢的缓蚀性能 [J]. 中国腐蚀与防护学报, 2019, 39: 267
28 El-Mahdy G A, Nishikata A, Tsuru T. Electrochemical corrosion monitoring of galvanized steel under cyclic wet-dry conditions [J]. Corros. Sci., 2000, 42: 183
29 Bovard F S. Environmentally induced cracking of an Al-Zn-Mg-Cu alloy [D]. Pittsburgh: University of Pittsburgh, 2005
30 Shi Y J, Pan Q L, Li M J, et al. Effect of Sc and Zr additions on corrosion behaviour of Al-Zn-Mg-Cu alloys [J]. J. Alloys Compd., 2014, 612: 42
31 Zhang Q, Yang S L, Jin D, et al. Study on corrosion behavior of aluminum alloy used in substation equipment in simulated coastal industrial atmosphere [J]. Rare Met. Cemen. Carb., 2018, 46(5): 65
31 张强, 阳慎兰, 靳东等. 变电站设备用铝合金在模拟沿海工业大气环境中的腐蚀行为研究 [J]. 稀有金属与硬质合金, 2018, 46(5): 65
32 Guo Z C, Wang Y F, Wang R M. The development of corrosion protection of aluminum aerospace alloys [J]. Mater. Rev., 2005, 19(9): 71
32 郭增昌, 王云芳, 王汝敏. 航空铝合金防腐保护研究进展 [J]. 材料导报, 2005, 19(9): 71
33 Mu X L, Xie P F, Jin T, et al. Corrosion behavior of nano-coating/aluminum alloy in seawater solution with different pH values [J]. Equip. Envir. Eng., 2020, 17(1): 130
33 慕仙莲, 解鹏飞, 金涛等. 纳米涂层/铝合金在不同pH值的海水溶液中的腐蚀行为研究 [J]. 装备环境工程, 2020, 17(1): 130
34 Zhang X, Ju D Y, Li J H, et al. Preparation and performance of anti-corrosion organic-inorganic hybrid coatings for aluminum alloy by sol-gel method [J]. Mater. Prot., 2019, 52(7): 12
34 张欣, 巨东英, 李建辉等. 溶胶-凝胶法制备铝合金耐蚀有机-无机杂化SiO2涂层及其性能研究 [J]. 材料保护, 2019, 52(7): 12
35 Zhou B T, Wang Y B, Huang Q Y, et al. Effect of hydrothermal pre-treatment on anti-corrosion properties of ZnAl-LDHs prepared on the surface of aluminium alloys [J]. Sur. Technol., 2020, 49(4): 315
35 周秉涛, 王友彬, 黄秋雨等. 水热预处理对铝合金表面ZnAl-LDHs涂层防腐蚀性能的影响 [J]. 表面技术, 2020, 49 (4) : 315
36 Wan H J, Huang H J, Hu J W, et al. Anti-H2S corrosion properties of three copper corrosion inhibitors [J]. Equip. Environ. Eng., 2013, 10(5): 47
36 万红敬, 黄红军, 胡建伟等. 三种铜缓蚀剂抗H2S腐蚀性能研究 [J]. 装备环境工程, 2013, 10(5): 47
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