碳点缓蚀剂的研究进展及展望

doi:10.11902/1005.4537.2025.005

中国腐蚀与防护学报

2025, Vol. 45

Issue (6): 1474-1492 CSTR: 32134.14.1005.4537.2025.005 DOI: 10.11902/1005.4537.2025.005

综合评述

本期目录 | 过刊浏览

碳点缓蚀剂的研究进展及展望

陈宇¹^,², 魏高飞¹^,², 邓书端¹^,², 李向红¹^,²(

)

1 西南林业大学材料与化学工程学院昆明 650224
2 西南林业大学云南省教育厅农林废弃物高值化利用重点实验室昆明 650224

Research Progress and Prospects of Carbon Dots as Corrosion Inhibitors

CHEN Yu¹^,², WEI Gaofei¹^,², DENG Shuduan¹^,², LI Xianghong¹^,²(

)

1 College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China
2 Key Laboratory of Yunnan Provincial Department of Education on Highly-efficient Utilization of Agricultural and Forest Wastes, Southwest Forestry University, Kunming 650224, China

引用本文:

陈宇, 魏高飞, 邓书端, 李向红. 碳点缓蚀剂的研究进展及展望[J]. 中国腐蚀与防护学报, 2025, 45(6): 1474-1492.
Yu CHEN, Gaofei WEI, Shuduan DENG, Xianghong LI. Research Progress and Prospects of Carbon Dots as Corrosion Inhibitors[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(6): 1474-1492.

全文: PDF(10697 KB) HTML

摘要:

碳点(CDs)因其突出的光电性能、来源丰富、富含官能团及杂原子、绿色环保等特性，已成为新型纳米级绿色缓蚀剂的研究热点。本文从CDs结构性质出发，归纳总结目前采用自上而下和自下而上途径合成CDs的具体方法，并简要介绍了理论计算在合成CDs中的指导应用。围绕掺杂型(非金属、金属和共掺杂)、表面修饰型和生物质基为研究热点的3类CDs缓蚀剂，展开分析了不同金属在不同介质中的缓蚀性能，以及在溶液中的作用方式和缓蚀机理模型。综合在金属腐蚀防护领域的研究概况，对未来发展趋势进行了展望。旨在通过对CDs缓蚀剂的分析研究，充分挖掘利用其在金属腐蚀防护领域的优势，优化CDs制备工艺，开发出更先进、高效的腐蚀防护技术，为CDs缓蚀剂在未来的深度研究和实际应用提供一定的参考，推动金属腐蚀防护技术实现高质量发展。

关键词 ：碳点, 缓蚀剂, 金属, 掺杂, 表面修饰, 生物质

Abstract：

Carbon dots (CDs) have become a research hotspot in the research on novel nano-scale green corrosion inhibitors due to their outstanding photoelectric properties, abundant sources, rich functional groups and heteroatoms, as well as their environmentally friendly characteristics. Based on the structural properties of CDs, this paper summarizes the specific methods for synthesizing CDs through top-down and bottom-up approaches at present, and briefly introduces the application of theoretical calculation in the synthesis of CDs. The corrosion inhibition performance of three types of CDs corrosion inhibitors on different metals in various media was analyzed, and their action modes in solutions, and the relevant inhibition mechanism were discussed. They are respectively based on doping (non-metallic, metallic and co-doping), surface modification and biomass as substrate, which are the CD corrosion inhibitors that have attracted much attention so far. Furthermore, the future development trends are prospected. It is expected that this review may provide important references for future the in-depth research and practical application of CDs-based corrosion inhibitors and promote the high-quality development of metal corrosion protection technology.

Key words： carbon dots corrosion inhibitor metal doping surface modification biomass

收稿日期: 2025-01-02 32134.14.1005.4537.2025.005

ZTFLH:

TG174

基金资助:国家自然科学基金(52161016);云南省农业基础研究联合专项重点项目(202101BD070001-017)

通讯作者: 李向红，E-mail：xianghong-li@163.com，研究方向为缓蚀剂

Corresponding author: LI Xianghong, E-mail: xianghong-li@163.com

作者简介: 陈宇，女，1992年生，博士生

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	陈宇
	魏高飞
	邓书端
	李向红
44.8K

链接本文:

https://www.jcscp.org/CN/10.11902/1005.4537.2025.005 或 https://www.jcscp.org/CN/Y2025/V45/I6/1474

图1 碳点的分类、结构模型以及合成路径[21]

图2 掺杂型CDs的合成策略和杂原子掺杂CDs的研究进展[59]

图3 NCDs合成过程示意图和在酸性溶液中的缓蚀机理图及其缓蚀率变化曲线[77]

图4 NCDs对N80钢在1 mol/L HCl溶液和饱和CO2 3.5% (质量分数) NaCl溶液中的缓蚀机理图[89]

图5 N,S-CDs缓蚀机理示意图[90,91]

图6 N,S-CDs对Al、Cu和Mg的缓蚀机理图[19,97,98]

图7 不同浓度的N,S-CDs对Cu在1.0 mol/L HCl溶液中反应不同时间的SEM、EDS图谱和N,S-CDs DFT计算结果[101]

图8 CDs、CeCDs分子模拟计算结果和缓蚀机理图[103]

图9 Ce@N-CDs在酸性溶液中对钢的缓蚀机理图和Cu,N-CDs在酸性溶液中对软钢的缓蚀机理图[105,106]

图10 Me-CDs对Q235碳钢在3.5%NaCl溶液中的缓蚀机理图[107]

图11 Q235电极分别在不同浓度的HCl、NaCl溶液中浸泡24 h后的电流密度分布图和EIS图[133]

图12 CDs、IL-CD分子模拟计算结果和缓蚀机理图[52]

图13 pt-CDs缓蚀机理相关示意图[143]

图14 火龙果皮在不同反应时间下的TEM图谱和Q235钢在不同浓度溶液中的极化曲线[146]

[1]	Li X C. Development history and prospect of China's iron and steel industry in the past 70 years [J]. Steel. Plan. Res., 2019, 10: 1
[1]	(李新创. 中国钢铁工业70年发展历程与展望 [J]. 钢铁规划研究, 2019, 10: 1)
[2]	Hou B R, Lu D Z. Corrosion cost and preventive strategies in China [J]. Chin. Acad. Sci., 2018, 33: 601
[2]	(侯保荣, 路东柱. 我国腐蚀成本及其防控策略 [J]. 中国科学院院刊, 2018, 33: 601)
[3]	Xu W C, Zhang R Y, Duan J Z, et al. Corrosion is a global menace to crucial infrastructure—Act to stop the rot now [J]. Nature, 2024, 629: 41
[4]	Hou B R, Zhang D, Wang P. Marine corrosion and protection: Current status and prospect [J]. Bull. Chin. Acad. Sci., 2016, 31: 1326
[4]	(侯保荣, 张盾, 王鹏. 海洋腐蚀防护的现状与未来 [J]. 中国科学院院刊, 2016, 31: 1326)
[5]	Odidika C C, Ajiwe V I E, Eboagu C N, et al. Corrosion inhibition and adsorption properties of Commelina benghalensis leaves extract on mild steel in 1 M H₂SO₄ solution [J]. Sci. J. Anal. Chem., 2020, 8: 86
[6]	Hou R, Xu G, Dai F Q, et al. Corrosion resistance of hot rolled plates with Al-Zn coating [J]. Corros. Prot., 2018, 39: 90
[6]	(侯蓉, 徐光, 戴方钦等. 锌铝镀层热轧板的耐蚀性 [J]. 腐蚀与防护, 2018, 39: 90)
[7]	Yang Y, Yang X J, Jia J H, et al. Effect of Sb and Sn on the corrosion behavior of low alloy steel in simulated polluted marine atmosphere [J]. Surf. Technol., 2021, 50(5): 224
[7]	(杨颖, 杨小佳, 贾静焕等. Sb和Sn微合金化对低合金钢在模拟污染海洋大气中腐蚀行为的影响 [J]. 表面技术, 2021, 50(5): 224)
[8]	He M Q, Guo X R, Huang J Z, et al. Mass production of tunable multicolor graphene quantum dots from an energy resource of coke by a one-step electrochemical exfoliation [J]. Carbon, 2018, 140: 508
[9]	Wei G F, Deng S D, Shao D D, et al. Inhibition action of Machilus yunnanensis leaves extract on corrosion of Al-plate in HCl medium [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 601
[9]	(魏高飞, 邓书端, 邵丹丹等. 滇润楠叶提取物对铝在HCl中的缓蚀性能 [J]. 中国腐蚀与防护学报, 2024, 44: 601)
[10]	de Damborenea J, Conde A, Arenas M A. 3-Corrosion inhibition with rare earth metal compounds in aqueous solutions [A]. Forsyth M, Hinton B. Rare Earth-based Corrosion Inhibitors [C]. New York: Woodhead Publishing, 2014: 84
[11]	Finšgar M, Jackson J. Application of corrosion inhibitors for steels in acidic media for the oil and gas industry: A review [J]. Corros. Sci., 2014, 86: 17
[12]	Cui L, Hang M Y, Huang H H, et al. Experimental study on multi-component corrosion inhibitor for steel bar in chloride environment [J]. Constr. Build. Mater., 2021, 313: 125533
[13]	Aloysius A, Ramanathan R, Christy A, et al. Experimental and theoretical studies on the corrosion inhibition of vitamins-thiamine hydrochloride or biotin in corrosion of mild steel in aqueous chloride environment [J]. Egypt. J. Pet., 2018, 27: 371
[14]	Xu X Y, Ray R, Gu Y L, et al. Electrophoretic analysis and purification of fluorescent single-walled carbon nanotube fragments [J]. J. Am. Chem. Soc., 2004, 126: 12736
[15]	Zhu S J, Song Y B, Shao J R, et al. Non-conjugated polymer dots with crosslink-enhanced emission in the absence of fluorophore units [J]. Angew. Chem. Int. Ed., 2015, 54: 14626
[16]	Wang J K, Wu S H, Chen Z B, et al. Research progress of carbon dots in the field of metal corrosion and protection [J]. Surf. Technol., 2024, 53(3): 75
[16]	(王金科, 吴尚浩, 陈质彬等. 碳点在金属腐蚀防护领域的研究进展 [J]. 表面技术, 2024, 53(3): 75)
[17]	Wang Q H, Wang R Z, Sun X F, et al. Protein-derived carbon dots as green corrosion inhibitors for carbon steel in sulfuric acid solution [J]. Diam. Relat. Mater., 2024, 145: 111135
[18]	Zhang Y, Zhang S T, Tan B C, et al. Solvothermal synthesis of functionalized carbon dots from amino acid as an eco-friendly corrosion inhibitor for copper in sulfuric acid solution [J]. J. Colloid Interface Sci., 2021, 604: 1
[19]	Cen H Y, Zhang X, Zhao L, et al. Carbon dots as effective corrosion inhibitor for 5052 aluminium alloy in 0.1 M HCl solution [J]. Corros. Sci., 2019, 161: 108197
[20]	Li S, Li L, Tu H Y, et al. The development of carbon dots: from the perspective of materials chemistry [J]. Mater. Today, 2021, 51: 188
[21]	Wang B Y, Waterhouse G I N, Lu S Y. Carbon dots: mysterious past, vibrant present, and expansive future [J]. Trends. Chem., 2023, 5: 76
[22]	Verma C, Dubey S, Alfantazi A, et al. Heteroatoms-doped carbon dots: fundamental, properties, coordination bonding and corrosion protection [J]. J. Ind. Eng. Chem., 2024, 133: 90
[23]	Wang J, Wang S Y, Zhang C, et al. Effect of nitrogen doping on corrosion inhibition performance of carbon nanoparticles [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 85
[23]	(王晶, 王斯琰, 张崇等. 氮掺杂对碳纳米颗粒缓蚀性能的影响 [J]. 中国腐蚀与防护学报, 2022, 42: 85)
[24]	Li J N, Zhang D K, Xia J B. The controllable synthesis of multi-color carbon quantum dots modified by polythiophene and their application in fluorescence detection of Au³⁺ and Hg²⁺ [J]. Spectrochim. Acta, 2024, 322A: 124794
[25]	Ge G L, Li L, Wang D, et al. Carbon dots: Synthesis, properties and biomedical applications [J]. J. Mater. Chem. B, 2021, 9: 6553
[26]	Sun Y P, Zhou B, Lin Y, et al. Quantum-sized carbon dots for bright and colorful photoluminescence [J]. J. Am. Chem. Soc., 2006, 128: 7756
[27]	Peng H, Travas-Sejdic J. Simple aqueous solution route to luminescent carbogenic dots from carbohydrates [J]. Chem. Mater., 2009, 21: 5563
[28]	Kang C, Huang Y, Yang H, et al. A review of carbon dots produced from biomass wastes [J]. Nanomaterials, 2020, 10: 2316
[29]	Youh M J, Chung M C, Tai H C, et al. Fabrication of carbon quantum dots via ball milling and their application to bioimaging [J]. Mendeleev Commun., 2021, 31: 647
[30]	Wang L, Chen X, Lu Y L, et al. Carbon quantum dots displaying dual-wavelength photoluminescence and electrochemiluminescence prepared by high-energy ball milling [J]. Carbon, 2015, 94: 472
[31]	Xiang T F, Wang J Q, Liang Y L, et al. Carbon dots for anti-corrosion [J]. Adv. Funct. Mater., 2024, 34: 2411456
[32]	Zhu H, Wang X L, Li Y L, et al. Microwave synthesis of fluorescent carbon nanoparticles with electrochemiluminescence properties [J]. Chem. Commun., 2009, (34): 5118
[33]	Chernyak S, Podgornova A, Dorofeev S, et al. Synthesis and modification of pristine and nitrogen-doped carbon dots by combining template pyrolysis and oxidation [J]. Appl. Surf. Sci., 2020, 507: 145027
[34]	Hou H S, Banks C E, Jing M J, et al. Carbon quantum dots and their derivative 3D porous carbon frameworks for sodium-ion batteries with ultralong cycle life [J]. Adv. Mater., 2015, 27: 7861
[35]	Zhu Z J, Cheng R, Ling L T, et al. Rapid and large-scale production of multi-fluorescence carbon dots by a magnetic hyperthermia method [J]. Angew. Chem. Int. Ed., 2020, 59: 3099
[36]	Jiang H Q, Chen F, Lagally M G, et al. New strategy for synthesis and functionalization of carbon nanoparticles [J]. Langmuir, 2010, 26: 1991
[37]	Li C X, Yu C, Wang C F, et al. Facile plasma-induced fabrication of fluorescent carbon dots toward high-performance white LEDs [J]. J. Mater. Sci., 2013, 48: 6307
[38]	Lu Y, Zhang L, Lin H W. The use of a microreactor for rapid screening of the reaction conditions and investigation of the photoluminescence mechanism of carbon dots [J]. Chem. Eur. J., 2014, 20: 4246
[39]	Yan X, Cui X, Li L S. Synthesis of large, stable colloidal graphene quantum dots with tunable size [J]. J. Am. Chem. Soc., 2010, 132: 5944
[40]	Mocci F, De Villiers Engelbrecht L, Olla C, et al. Carbon nanodots from an in silico perspective [J]. Chem. Rev., 2022, 122: 13709
[41]	Hong Q, Wang X Y, Gao Y T, et al. Customized carbon dots with predictable optical properties synthesized at room temperature guided by machine learning [J]. Chem. Mater., 2022, 34: 998
[42]	Han Y, Tang B J, Wang L, et al. Machine-learning-driven synthesis of carbon dots with enhanced quantum yields [J]. ACS Nano, 2020, 14: 14761
[43]	Yu J K, Yong X, Tang Z Y, et al. Theoretical understanding of structure-property relationships in luminescence of carbon dots [J]. J. Phys. Chem. Lett., 2021, 12: 7671
[44]	He H J, E S, Ai L, et al. Exploiting machine learning for controlled synthesis of carbon dots-based corrosion inhibitors [J]. J. Clean. Prod., 2023, 419: 138210
[45]	Tao S Y, Zhu S J, Yang B. A new kinds of carbon-based luminous nanomaterials-carbon dots: its progresses and prospects [J]. Sci. Foc., 2019, 14(6): 35
[45]	(陶淞源, 朱守俊, 杨柏. 新型碳基发光纳米材料—碳点: 研究进展及展望 [J]. 科学观察, 2019, 14(6): 35)
[46]	Tang W W, Wang B G, Li J T, et al. Facile pyrolysis synthesis of ionic liquid capped carbon dots and subsequent application as the water-based lubricant additives [J]. J. Mater. Sci., 2019, 54: 1171
[47]	Ye Y W, Yang D P, Chen H, et al. A high-efficiency corrosion inhibitor of N-doped citric acid-based carbon dots for mild steel in hydrochloric acid environment [J]. J. Hazard. Mater., 2020, 381: 121019
[48]	Zhu M Y, He Z Y, Guo L, et al. Corrosion inhibition of eco-friendly nitrogen-doped carbon dots for carbon steel in acidic media: Performance and mechanism investigation [J]. J. Mol. Liq., 2021, 342: 117583
[49]	Liu Z, Jia R N, Jian Y, et al. N-doped carbon dots as a multifunctional platform for real-time corrosion monitoring and inhibition [J]. Colloid. Surf., 2022, 650A: 129499
[50]	Wang Y R, Sun Y Q, Zhao Y, et al. Microwave-assisted fast preparation of functionalized carbon dots: the impact of ionic liquid precursor on corrosion inhibition [J]. Colloid. Surf., 2024, 694A: 134130
[51]	Anindita F, Darmawan N, Mas'ud Z A. Fluorescence carbon dots from durian as an eco-friendly inhibitor for copper corrosion [J]. AIP Conf. Proc., 2018, 2014: 020008
[52]	Li F T, Wang Z K, Zhou Y, et al. Improvement of carbon dots corrosion inhibition by ionic liquid modification: Experimental and computational investigations [J]. Corros. Sci., 2023, 224: 111541
[53]	Berdimurodov E, Verma D K, Kholikov A, et al. The recent development of carbon dots as powerful green corrosion inhibitors: a prospective review [J]. J. Mol. Liq., 2022, 349: 118124
[54]	Zhao H J, Chen Z H, Zhou H, et al. Green and environment-friendly nano carbon dot corrosion inhibitor as well as preparation method and application thereof [P]. Chin Pat, CN202410899401. 9, 2024
[54]	(赵会军, 陈子恒, 周昊等. 一种绿色环保纳米碳点缓蚀剂及其制备方法和应用 [P]. 中国专利, CN202410899401.9, 2024))
[55]	Liao B K, Zeng Y X, Wu Y, et al. Citric acid-based functionalized carbon dot corrosion inhibitor and preparation method and application thereof [P]. Chin Pat, CN202010466872.2, 2022
[55]	(廖伯凯, 曾远娴, 吴颖等. 一种柠檬酸基功能化碳点缓蚀剂及其制备方法与应用 [P]. 中国专利, CN202010466872.2, 2022))
[56]	Liao B K, Chen H K, Wan S, et al. Functionalized glucosyl carbon dot corrosion inhibitor and preparation method and application thereof [P]. Chin Pat, CN202110505438.5, 2022
[56]	(廖伯凯, 陈汇凯, 万闪等. 一种功能化葡萄糖基碳点缓蚀剂及其制备方法与应用 [P]. 中国专利, CN202110505438.5, 2022))
[57]	Cen H Y, Chen Z Y, Guo X P. Corrosion inhibition performance and mechanism of carbon dots as corrosion inhibitors [J]. Surf. Technol., 2020, 49(11): 13
[57]	(岑宏宇, 陈振宇, 郭兴蓬. 碳量子点缓蚀剂的缓蚀行为与机理研究 [J]. 表面技术, 2020, 49(11): 13)
[58]	Wang C F, Wu X, Li X P, et al. Upconversion fluorescent carbon nanodots enriched with nitrogen for light harvesting [J]. J. Mater. Chem., 2012, 22: 15522
[59]	Miao S H, Liang K, Zhu J J, et al. Hetero-atom-doped carbon dots: doping strategies, properties and applications [J]. Nano Today, 2020, 33: 100879
[60]	Kartsonakis I A, Stanciu S G, Matei A A, et al. Evaluation of the protective ability of typical corrosion inhibitors for magnesium alloys towards the Mg ZK30 variant [J]. Corros. Sci., 2015, 100: 194
[61]	Wang J H, Liu D, Cao S Y, et al. Inhibition effect of monomeric/polymerized imidazole zwitterions as corrosion inhibitors for carbon steel in acid medium [J]. J. Mol. Liq., 2020, 312: 113436
[62]	Hasanov R, Bilge S, Bilgiç S, et al. Experimental and theoretical calculations on corrosion inhibition of steel in 1 M H₂SO₄ by crown type polyethers [J]. Corros. Sci., 2010, 52: 984
[63]	Li S L, Deng S D, Li X H. Research progress and prospects of plant corrosion inhibitors for aluminum [J]. J. Chin. Soc. Corros. Prot., 2023, 43: 929
[63]	(李树丽, 邓书端, 李向红. 铝植物缓蚀剂的研究进展与展望 [J]. 中国腐蚀与防护学报, 2023, 43: 929)
[64]	Bouayed M, Rabaa H, Srhiri A, et al. Experimental and theoretical study of organic corrosion inhibitors on iron in acidic medium [J]. Corros. Sci., 1998, 41: 501
[65]	Tejwan N, Saini A K, Sharma A, et al. Metal-doped and hybrid carbon dots: a comprehensive review on their synthesis and biomedical applications [J]. J. Control. Release., 2021, 330: 132
[66]	Gallareta-Olivares G, Rivas-Sanchez A, Cruz-Cruz A, et al. Metal-doped carbon dots as robust nanomaterials for the monitoring and degradation of water pollutants [J]. Chemosphere, 2023, 312: 137190
[67]	Li X C, Fu Y Z, Zhao S J, et al. Metal ions-doped carbon dots: synthesis, properties, and applications [J]. Chem. Eng. J., 2022, 430: 133101
[68]	Lin L P, Luo Y X, Tsai P, et al. Metal ions doped carbon quantum dots: synthesis, physicochemical properties, and their applications [J]. Trends Anal. Chem., 2018, 103: 87
[69]	Verma C, Ebenso E E, Quraishi M A. Corrosion inhibitors for ferrous and non-ferrous metals and alloys in ionic sodium chloride solutions: A review [J]. J. Mol. Liq., 2017, 248: 927
[70]	Sun S Q, Zhou Y, Wang Z K. Preparation of a new type of green rare earth-doped carbon dots corrosion inhibitor and method for modifying it with ionic liquids [P]. Chin Pat, CN115504454B, 2024
[70]	(孙霜青, 周熠, 王志坤. 一种新型绿色稀土掺杂的碳点缓蚀剂的制备及离子液体对其进行改性的方法 [P]. 中国专利, CN115504454B, 2024))
[71]	Cui M J, Ren S M, Xue Q J, et al. Carbon dots as new eco-friendly and effective corrosion inhibitor [J]. J. Alloy. Compd., 2017, 726: 680
[72]	Cui M J, Ren S M, Zhao H C, et al. Novel nitrogen doped carbon dots for corrosion inhibition of carbon steel in 1 M HCl solution [J]. Appl. Surf. Sci., 2018, 443: 145
[73]	Zhang T T, Zhang D Q, Wu P P, et al. Corrosion inhibition of high-nitrogen-doped CDs for copper in 3wt%NaCl solution [J]. J. Taiwan Inst. Chem. Eng., 2022, 138: 104462
[74]	Li X M, Rui M C, Song J Z, et al. Carbon and graphene quantum dots for optoelectronic and energy devices: A review [J]. Adv. Funct. Mater., 2015, 25: 4929
[75]	John V L, Nair Y, Vinod T P. Doping and surface modification of carbon quantum dots for enhanced functionalities and related applications [J]. Part. Part. Syst. Charact., 2021, 38: 2100170
[76]	Xu X M, Gu L H, Liu R T, et al. Preparation and corrosion performance of nitrogen-doped carbon quantum dots as corrosion inhibitors based on quantum chemical calculation [J]. Electro. Fin., 2024, 43(1): 98
[76]	(许旭敏, 顾立宏, 刘仁体等. 基于量子化学计算优化的氮掺杂碳量子点缓蚀剂制备及其缓蚀性能 [J]. 电镀与涂饰, 2024, 43(1): 98)
[77]	Wang S Y, Wang J, Wang Z Q, et al. The effect of pyrrolic nitrogen on corrosion inhibition performance of N-doped carbon dots [J]. Surf. Interfaces, 2024, 44: 103740
[78]	Pillar-Little T, Kim D Y. Differentiating the impact of nitrogen chemical states on optical properties of nitrogen-doped graphene quantum dots [J]. RSC Adv., 2017, 7: 48263
[79]	Wang H, Haydel P, Sui N, et al. Wide emission shifts and high quantum yields of solvatochromic carbon dots with rich pyrrolic nitrogen [J]. Nano Res., 2020, 13: 2492
[80]	Liu Z X, Ye Y W, Chen H. Corrosion inhibition behavior and mechanism of N-doped carbon dots for metal in acid environment [J]. J. Clean. Prod., 2020, 270: 122458
[81]	Shahmoradi A R, Ranjbarghanei M, Javidparvar A A, et al. Theoretical and surface/electrochemical investigations of walnut fruit green husk extract as effective inhibitor for mild-steel corrosion in 1M HCl electrolyte [J]. J. Mol. Liq., 2021, 338: 116550
[82]	Cui M J, Qiang Y J, Wang W, et al. Microwave synthesis of eco-friendly nitrogen doped carbon dots for the corrosion inhibition of Q235 carbon steel in 0.1 M HCl [J]. Int. J. Electrochem. Sci., 2021, 16: 151019
[83]	Li J B, Lü J, Fu L P, et al. New ecofriendly nitrogen-doped carbon quantum dots as effective corrosion inhibitor for saturated CO₂ 3% NaCl solution [J]. Russ. J. Appl. Chem., 2020, 93: 380-392
[84]	Qiang Y J, Zhang S T, Zhao H C, et al. Enhanced anticorrosion performance of copper by novel N-doped carbon dots [J]. Corros. Sci., 2019, 161: 108193
[85]	Niu F H, Zhou G G, Zhu J W, et al. Inhibition behavior of nitrogen-doped carbon dots on X80 carbon steel in acidic solution [J]. J. Mol. Liq., 2021, 339: 117171
[86]	Zhu M Y, Guo L, He Z Y, et al. Insights into the newly synthesized N-doped carbon dots for Q235 steel corrosion retardation in acidizing media: a detailed multidimensional study [J]. J. Colloid Interface Sci., 2022, 608: 2039
[87]	Mehta R K, Gupta S K, Yadav M. Synthesized novel carbon dots as green corrosion inhibitor for mild steel in hydrochloric acid: Gravimetric, electrochemical and morphological studies [J]. Diam. Relat. Mater., 2023, 136: 109992
[88]	Ye Y W, Jiang Z L, Zou Y J, et al. Evaluation of the inhibition behavior of carbon dots on carbon steel in HCl and NaCl solutions [J]. J. Mater. Sci. Technol., 2020, 43: 144
[89]	Wu X D, Li J B, Deng C Y, et al. Novel carbon dots as effective corrosion inhibitor for N80 steel in 1 M HCl and CO₂-saturated 3.5wt%NaCl solutions [J]. J. Mol. Struct., 2022, 1250: 131897
[90]	Cen H Y, Chen Z Y, Guo X P. N, S co-doped carbon dots as effective corrosion inhibitor for carbon steel in CO₂-saturated 3.5%NaCl solution [J]. J. Taiwan Inst. Chem. E., 2019, 99: 224
[91]	Ren S M, Cui M J, Chen X Y, et al. Comparative study on corrosion inhibition of N doped and N, S codoped carbon dots for carbon steel in strong acidic solution [J]. J. Colloid Interface Sci., 2022, 628: 384
[92]	Saraswat V, Yadav M. Carbon dots as green corrosion inhibitor for mild steel in HCl solution [J]. ChemistrySelect, 2020, 5: 7347
[93]	Wu P P, Gao L X, Lü Z P, et al. Research progress of carbon quantum dots in metal corrosion protection [J]. Corros. Prot., 2022, 43(11): 83
[93]	(吴盼盼, 高立新, 吕战鹏等. 碳量子点在金属腐蚀防护中的研究进展 [J]. 腐蚀与防护, 2022, 43(11): 83)
[94]	Chang X J, Henderson W M, Bouchard D C. Multiwalled carbon nanotube dispersion methods affect their aggregation, deposition, and biomarker response [J]. Environ. Sci. Technol., 2015, 49: 6645
[95]	Předota M, Machesky M L, Wesolowski D J. Molecular origins of the zeta potential [J]. Langmuir, 2016, 32: 10189
[96]	Lorite I, Romero J J, Fernández J F. Influence of the nanoparticles agglomeration state in the quantum-confinement effects: Experimental evidences [J]. AIP Adv., 2015, 5: 037105
[97]	Zhang Y, Tan B C, Zhang X, et al. Synthesized carbon dots with high N and S content as excellent corrosion inhibitors for copper in sulfuric acid solution [J]. J. Mol. Liq., 2021, 338: 116702
[98]	Pan L, Li G X, Wang Z Y, et al. Nitrogen/Sulfur co-doped carbon dots for enhancing anti-corrosion performance of Mg alloy in NaCl solution [J]. ChemistrySelect, 2021, 6: 11337
[99]	Wareing T C, Gentile P, Phan A N. Biomass-based carbon dots: current development and future perspectives [J]. ACS Nano, 2021, 15: 15471
[100]	Barhoum A, Meftahi A, Sabery M S K, et al. A review on carbon dots as innovative materials for advancing biomedical applications: synthesis, opportunities, and challenges [J]. J. Mater. Sci., 2023, 58: 13531
[101]	Liu Z X, Chu Q K, Chen H, et al. Experimental and molecular simulation studies of N, S-doped carbon dots as an eco-friendly corrosion inhibitor for protecting Cu in HCl environment [J]. Colloid. Surf., 2023, 669A: 131504
[102]	Kalajahi S T, Rasekh B, Yazdian F, et al. Green mitigation of microbial corrosion by copper nanoparticles doped carbon quantum dots nanohybrid [J]. Environ. Sci. Pollut. Res., 2020, 27: 40537
[103]	Li F T, Zhou Y, Wang Z K, et al. Ce-doped carbon dots enhanced by ionic liquids: A potent corrosion shield for N80 steel in aggressive 1 M HCl environment [J]. Colloid. Surf., 2025, 709A: 136132
[104]	Zeng S Y, Zhang F, Liu Y H, et al. Synthesis of Ce, N co-doped carbon dots as green and effective corrosion inhibitor for copper in acid environment [J]. J. Taiwan Inst. Chem. E., 2022, 141: 104608
[105]	Liu Z X, Hao X Y, Li Y, et al. Novel Ce@N-CDs as green corrosion inhibitor for metal in acidic environment [J]. J. Mol. Liq., 2022, 349: 118155
[106]	Padhan S, Rout T K, Nair U G. N-doped and Cu, N-doped carbon dots as corrosion inhibitor for mild steel corrosion in acid medium [J]. Colloid. Surf., 2022, 653A: 129905
[107]	Zeng Y X, Kang L, Wu Y, et al. Melamine modified carbon dots as high effective corrosion inhibitor for Q235 carbon steel in neutral 3.5wt%NaCl solution [J]. J. Mol. Liq., 2022, 349: 118108
[108]	Li X H, Deng S D, Xu X. Inhibition action of cassava starch ternary graft copolymer on steel in H₂SO₄ solution [J]. J. Chin. Soc. Corros. Prot., 2020, 40: 105
[108]	(李向红, 邓书端, 徐昕. 木薯淀粉三元接枝共聚物对钢在H₂SO₄溶液中的缓蚀性能研究 [J]. 中国腐蚀与防护学报, 2020, 40: 105)
[109]	Shi C J, Lei R, Deng S D, et al. Corrosion inhibition of Erigeron canadensis L. Extract for steel in HCl solution [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 1189
[109]	(石成杰, 雷然, 邓书端等. 小蓬草提取物对钢在HCl介质中的缓蚀作用 [J]. 中国腐蚀与防护学报, 2024, 44: 1189)
[110]	Cao S Y, Liu D, Ding H, et al. Towards understanding corrosion inhibition of sulfonate/carboxylate functionalized ionic liquids: An experimental and theoretical study [J]. J. Colloid Interface Sci., 2020, 579: 315
[111]	Kowsari E, Payami M, Amini R, et al. Task-specific ionic liquid as a new green inhibitor of mild steel corrosion [J]. Appl. Surf. Sci., 2014, 289: 478
[112]	Berdimurodov E, Kholikov A, Akbarov K, et al. New anti-corrosion inhibitor (3ar, 6ar)-3a, 6a-di-p-tolyltetrahydroimidazo [4, 5-d] imidazole-2, 5(1 h, 3 h)-dithione for carbon steel in 1 M HCl medium: gravimetric, electrochemical, surface and quantum chemical analyses [J]. Arab. J. Chem., 2020, 13: 7504
[113]	Ramesh S, Rajeswari S. Corrosion inhibition of mild steel in neutral aqueous solution by new triazole derivatives [J]. Electrochim. Acta, 2004, 49: 811
[114]	Berdimurodov E, Kholikov A, Akbarov K, et al. Inhibition properties of 4, 5-dihydroxy-4, 5-di-p-tolylimidazolidine-2-thione for use on carbon steel in an aggressive alkaline medium with chloride ions: Thermodynamic, electrochemical, surface and theoretical analyses [J]. J. Mol. Liq., 2021, 327: 114813
[115]	Liao J B, Chu Q K, Zhao S M, et al. Recent advances in carbon dots as powerful ecofriendly corrosion inhibitors for copper and its alloy [J]. Mater. Today Sustain., 2024, 26: 100706
[116]	Lozano I, Mazario E, Olivares-Xometl C O, et al. Corrosion behaviour of API 5LX52 steel in HCl and H₂SO₄ media in the presence of 1, 3-dibencilimidazolio acetate and 1, 3-dibencilimidazolio dodecanoate ionic liquids as inhibitors [J]. Mater. Chem. Phys., 2014, 147: 191
[117]	Ahamad I, Prasad R, Quraishi M A. Thermodynamic, electrochemical and quantum chemical investigation of some Schiff bases as corrosion inhibitors for mild steel in hydrochloric acid solutions [J]. Corros. Sci., 2010, 52: 933
[118]	Khan G, Basirun W J, Kazi S N, et al. Electrochemical investigation on the corrosion inhibition of mild steel by Quinazoline Schiff base compounds in hydrochloric acid solution [J]. J. Colloid Interface Sci., 2017, 502: 134
[119]	Li X Q, He C, Yu K K, et al. Facile preparation and characterization of carbon dots with Schiff base structures toward an efficient corrosion inhibitor [J]. Surf. Technol., 2023, 52(10): 229
[119]	(李雪琪, 何闯, 于坷坷等. 含席夫碱结构碳点缓蚀剂的简易可扩展制备及性能研究 [J]. 表面技术, 2023, 52(10): 229)
[120]	Yoo S H, Kim Y W, Chung K, et al. Corrosion inhibition properties of triazine derivatives containing carboxylic acid and amine groups in 1.0 M HCl solution [J]. Ind. Eng. Chem. Res., 2013, 52: 10880
[121]	Chauhan D S, Quraishi M A, Nik W B W, et al. Triazines as a potential class of corrosion inhibitors: present scenario, challenges and future perspectives [J]. J. Mol. Liq., 2021, 321: 114747
[122]	Li Y, Yang H, Wang F Q, et al. Fabrication and anti-corrosion properties of melamine-treated graphene oxide adsorbed on copper [J]. Prog. Org. Coat., 2020, 141: 105564
[123]	Hong S, Chen W, Zhang Y, et al. Investigation of the inhibition effect of trithiocyanuric acid on corrosion of copper in 3.0wt.% NaCl [J]. Corros. Sci., 2013, 66: 308
[124]	Li X, Wang X Y, Nawaz H, et al. The choice of ionic liquid ions to mitigate corrosion impacts: The influence of superbase cations and electron-donating carboxylate anions [J]. Green Chem., 2022, 24: 2114
[125]	Hulsbosch J, De Vos D E, Binnemans K, et al. Biobased ionic liquids: solvents for a green processing industry? [J]. ACS Sustain. Chem. Eng., 2016, 4: 2917
[126]	Yao W H, Wang H Y, Cui G K, et al. Tuning the hydrophilicity and hydrophobicity of the respective cation and anion: Reversible phase transfer of ionic liquids [J]. Angew. Chem. Int. Ed., 2016, 55: 7934
[127]	Zhu S J, Song Y B, Zhao X H, et al. The photoluminescence mechanism in carbon dots (graphene quantum dots, carbon nanodots, and polymer dots): Current state and future perspective [J]. Nano Res., 2015, 8: 355
[128]	Zheng A Q, Guo T T, Guan F L, et al. Ionic liquid mediated carbon dots: Preparations, properties and applications [J]. Trac Trends Anal. Chem., 2019, 119: 115638
[129]	Cao S Y, Liu D, Ding H, et al. Corrosion inhibition effects of a novel ionic liquid with and without potassium iodide for carbon steel in 0. 5 M HCl solution: An experimental study and theoretical calculation [J]. J. Mol. Liq., 2019, 275: 729
[130]	Cao S Y, Liu D, Ding H, et al. Brönsted acid ionic liquid: Electrochemical passivation behavior to mild steel [J]. J. Mol. Liq., 2016, 220: 63
[131]	Sun Y Q, Wang Y R, Liu D, et al. Novel carboxylic functionalized ionic liquid grafted on carbonized polymer dots as highly efficient corrosion inhibitors [J]. J. Mol. Struct., 2025, 1321: 140011
[132]	Luo Q X, Song X D, Ji M, et al. Molecular size-and shape-selective knoevenagel condensation over microporous Cu₃(BTC)₂ mmobilized amino-functionalized basic ionic liquid catalyst [J]. Appl. Catal., 2014, 478A: 81
[133]	Yang D P, Ye Y W, Su Y, et al. Functionalization of citric acid-based carbon dots by imidazole toward novel green corrosion inhibitor for carbon steel [J]. J. Clean. Prod., 2019, 229: 180
[134]	Zhao L H, Wang Y Q, Liu Y H, et al. Corrosion behavior of four steels for landing gear of amphibious aircraft in simulated seawater [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 1263
[134]	(赵连红, 王英芹, 刘元海等. 四种飞机起落架用钢在模拟海水中的腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2024, 44: 1263)
[135]	Wu S H, Wang J K, Liu T, et al. Sulfosalicylic acid modified carbon dots as effective corrosion inhibitor and fluorescent corrosion indicator for carbon steel in HCl solution [J]. Colloid. Surf., 2023, 661A: 130951
[136]	Meng W X, Bai X, Wang B Y, et al. Biomass-derived carbon dots and their applications [J]. Energy Environ. Mater., 2019, 2: 172
[137]	Xu Z X, Gan Y, Zeng J, et al. Green synthesis of functionalized fluorescent carbon dots from biomass and their corrosion inhibition mechanism for copper in sulfuric acid environment [J]. Chem. Eng. J., 2023, 470: 144425
[138]	Xie W W, Chen J Q, Dong S Y. Preparation and corrosion inhibition performance of nitrogen-doped carbon dots based on radix isatidis dregs [J]. Surf. Technol., 2024, 53(2): 130
[138]	(谢微微, 陈佳起, 董社英. 基于板蓝根药渣氮掺杂碳点的制备及缓蚀性能研究 [J]. 表面技术, 2024, 53(2): 130)
[139]	Paiva V M, de Oliveira S M, de Almeida C M D S, et al. Pumpkin (Cucurbita maxima) seed-derived nitrogen, phosphorus, and sulfur carbon quantum dot as an inhibitor of corrosion for mild steel in HCl solution [J]. J. Mater. Res. Technol., 2024, 28: 2504
[140]	Long W J, Li X Q, Yu Y, et al. Green synthesis of biomass-derived carbon dots as an efficient corrosion inhibitor [J]. J. Mol. Liq., 2022, 360: 119522
[141]	Long W J, Tang J, Luo Q L, et al. Corrosion inhibition performance of biomass-derived carbon dots on Q235 steel [J]. J. Chin. Soc. Corros. Prot., 2024, 44: 807
[141]	(龙武剑, 唐杰, 罗启灵等. 生物质碳点对Q235钢的缓蚀性能研究 [J]. 中国腐蚀与防护学报, 2024, 44: 807)
[142]	Chen J Q, Hou D L, Xiao H, et al. Corrosion inhibition on carbon steel in acidic solution by carbon dots prepared from waste longan shells [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 629
[142]	(陈佳起, 侯道林, 肖晗等. 酸性介质中桂圆壳碳点对碳钢的缓蚀性能研究 [J]. 中国腐蚀与防护学报, 2022, 42: 629)
[143]	Chen J Q, Zhao W Y, Yao R C, et al. Synthesis of pistachio shell-based carbon dots and their corrosion inhibition behavior on Q235 carbon steel [J]. CIESC J., 2023, 74: 3446
[143]	(陈佳起, 赵万玉, 姚睿充等. 开心果壳基碳点的合成及其对Q235碳钢的缓蚀行为研究 [J]. 化工学报, 2023, 74: 3446)
[144]	Liu Y, Ren H Q, Gong Z L, et al. Melon seed shell synthesis N,S-carbon quantum dots as ultra-high performance corrosion inhibitors for copper in 0.5 M H₂SO₄ [J]. J. Ind. Eng. Chem., 2024, 137: 593
[145]	Zheng S Y, Feng L, Hu Z Y, et al. Study on the corrosion inhibition of biomass carbon quantum dot self-aggregation on Q235 steel in hydrochloric acid [J]. Arab. J. Chem., 2023, 16: 104605
[146]	Feng L, Zheng S Y, Ma X M, et al. Enhancing corrosion protection in acidic environments through biomass-derived carbon quantum dots [J]. Microchem. J., 2024, 199: 110003

[1]	邬春生, 张天永, 李彬, 苑文英, 张霄鸥, 姜爽, 汪怀远. 三嗪季铵盐基高温高压CO₂ 缓蚀剂及缓蚀性能研究[J]. 中国腐蚀与防护学报, 2025, 45(6): 1639-1648.
[2]	阮智邦, 魏仕轩, 王树鹏, 吕正平, 李格升, 李燚周. 中性氯化钠溶液中咪唑啉磷酸酯对7075铝合金电偶腐蚀抑制行为研究[J]. 中国腐蚀与防护学报, 2025, 45(6): 1734-1740.
[3]	史轩铭, 谭季波, 张兹瑜, 吴欣强. 铅冷快堆候选结构材料液态铅铋共晶环境中疲劳行为研究进展[J]. 中国腐蚀与防护学报, 2025, 45(5): 1187-1195.
[4]	方焕杰, 周鹏, 郁健浩, 王永欣, 于波, 蒲吉斌. Ti80合金与船用金属的电偶腐蚀行为研究[J]. 中国腐蚀与防护学报, 2025, 45(4): 905-915.
[5]	翟亚如, 熊金平, 赵景茂. 3.5%NaCl溶液中硝基巴比妥酸对AZ31B与AZ91D镁合金腐蚀的缓蚀作用及机理研究[J]. 中国腐蚀与防护学报, 2025, 45(4): 916-926.
[6]	郑微, 曲冬阳, 孙中辉, 牛利. 锌离子电池的锌金属负极和电解液的研究进展[J]. 中国腐蚀与防护学报, 2025, 45(3): 548-562.
[7]	侯晓犇, 刘宁, 扈俊颖. 天然气集输倾斜管道腐蚀行为及缓蚀剂分布研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 780-786.
[8]	赵菲, 王东伟, 郭泉忠, 汪川. RGO-CNTs杂化材料改性RuO₂-IrO₂-SnO₂/Ti阳极的性能研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 787-794.
[9]	张洪江, 陈佳起, 谢微微, 刘仲轩, 董社英. 丙烯酸-益母草药渣复合碳点荧光型阻垢剂的设计及性能研究[J]. 中国腐蚀与防护学报, 2025, 45(3): 812-820.
[10]	张晗, 刘轩溱, 黄爱辉, 赵晓峰, 陆杰. 热障涂层金属粘结层制备与研究进展[J]. 中国腐蚀与防护学报, 2025, 45(1): 20-32.
[11]	董子烨, 吴毅恒, 卢翀, 沈朝, 曾小勤. 固体氧化物燃料电池金属连接体研究进展[J]. 中国腐蚀与防护学报, 2025, 45(1): 46-60.
[12]	王承涛, 申冠一, 许少毅, 李威, 王禹桥, 王树臣, 闻东东, 李朋宇. 基于物理场耦合的交流干扰作用下埋地金属管线腐蚀数值仿真[J]. 中国腐蚀与防护学报, 2024, 44(6): 1573-1580.
[13]	赵岩, 粘磊, 王钰, 唐晓. 基于电磁感应红外热成像技术的涂层缺陷检测[J]. 中国腐蚀与防护学报, 2024, 44(6): 1641-1648.
[14]	吴浩天, 张天遂, 李广芳, 刘宏芳. 中性水系锌离子电池负极缓蚀剂研究进展[J]. 中国腐蚀与防护学报, 2024, 44(5): 1089-1099.
[15]	朱立洋, 陈俊全, 张欣欣, 董泽华, 蔡光义. 磁场对金属腐蚀影响的研究进展[J]. 中国腐蚀与防护学报, 2024, 44(5): 1117-1124.

Viewed

Full text

Abstract

Cited

Shared

Discussed