磁场对金属腐蚀影响的研究进展

doi:10.11902/1005.4537.2023.381

中国腐蚀与防护学报

2024, Vol. 44

Issue (5): 1117-1124 CSTR: 32134.14.1005.4537.2023.381 DOI: 10.11902/1005.4537.2023.381

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磁场对金属腐蚀影响的研究进展

朱立洋¹^,², 陈俊全², 张欣欣¹, 董泽华¹, 蔡光义²(

)

1 华中科技大学化学与化工学院武汉 430074
2 海军工程大学电磁能技术全国重点实验室武汉 430034

Research Progress of Effect of Magnetic Field on Metal Corrosion

ZHU Liyang¹^,², CHEN Junquan², ZHANG Xinxin¹, DONG Zehua¹, CAI Guangyi²(

)

1 School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
2 Nationa Key Laboratory of Electromagnetic Energy, Naval University of Engineering, Wuhan 430034, China

引用本文:

朱立洋, 陈俊全, 张欣欣, 董泽华, 蔡光义. 磁场对金属腐蚀影响的研究进展[J]. 中国腐蚀与防护学报, 2024, 44(5): 1117-1124.
Liyang ZHU, Junquan CHEN, Xinxin ZHANG, Zehua DONG, Guangyi CAI. Research Progress of Effect of Magnetic Field on Metal Corrosion[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1117-1124.

全文: PDF(6056 KB) HTML

摘要:

随着越来越多的电磁设备应用在腐蚀环境下，磁场对金属腐蚀的影响成为一个不可忽略的因素。已有相关研究表明，磁场对金属腐蚀的促进或者抑制作用取决于具体的工况环境。普遍认为磁场主要通过Lorentz力和磁场梯度力影响电化学过程中的粒子运动来影响金属的电化学腐蚀过程，具体表现在金属腐蚀过程中的传质、界面反应和腐蚀产物这3个方面。本文综述了磁场中Lorentz力和磁场梯度力对金属腐蚀过程的具体影响，指出了磁场对电化学腐蚀影响未来研究和应用的方向。

关键词 ：磁场, 金属腐蚀, Lorentz力, 磁场梯度力, 电化学

Abstract：

With more and more electromagnetic equipment was applied in corrosion environment, the effect of magnetic field on metal corrosion has become a factor that cannot be ignored. It has been found that the promotion or inhibition effect of magnetic field on metal corrosion depends on the specific working environment. It is generally believed that the magnetic field affects the electrochemical process of particle movement mainly through the Lorentz force and magnetic field gradient force, so that to affect the electrochemical corrosion process of metal, specifically in the corrosion of metal in the process of mass transfer, interfacial reaction and corrosion products of these three aspects. This paper summarizes the specific effects of the Lorentz force and magnetic field gradient force on the metal corrosion process in the presence of magnetic fields, and puts forward the direction of the future research and application of the influence of magnetic field on the corrosion process of metallic materials.

Key words： magnetic field metal corrosion Lorentz force magnetic field gradient force electrochemistry

收稿日期: 2023-11-29 32134.14.1005.4537.2023.381

ZTFLH:

TG174

通讯作者: 蔡光义，E-mail：cgy54@sina.cn，研究方向为金属腐蚀与防护

Corresponding author: CAI Guangyi, E-mail: cgy54@sina.cn

作者简介: 朱立洋，男，1997年生，博士生

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表1 磁场对金属腐蚀过程的影响总结

图1 有无磁场条件下海洋大气环境中曝露1 a后铜材表面腐蚀产物XRD谱[42]

图2 Fe在不同磁场条件下0.5 mol·L-1 H2SO4溶液中的阳极极化曲线[43~45]

图3 外加磁场(B = 400 mT)和搅拌对不同电位下I-t曲线的影响[46]

图4 磁场对铁磁电极上人造点蚀坑的影响示意图[13]

图5 铜样品在0 T和0.14 T磁场下暴露36 h后的SEM图像[48]

图6 铍铜在0 T和0.4 T磁场下浸入1%和3.5% NaCl溶液中15 d后的SEM图像和腐蚀产物化学成分[56]

图7 Rs、Rct和RL随预处理磁场强度的变化[29]

1	Liu Y C, Xian H, Zhang C H, et al. Review on corrosion and surface treatment technology of metal materials [J]. Electron. Prod. Reliab. Environ. Test, 2023, 41(4): 7
1	刘妍岑, 鲜行, 张从浩等. 金属材料腐蚀及表面处理技术研究综述 [J]. 电子产品可靠性与环境试验, 2023, 41(4): 7
2	Hou B R. Corrosion cost and economic development [J]. Sci. Technol. Ind. China, 2020, (2): 21
2	侯保荣. 腐蚀成本与经济发展 [J]. 中国科技产业, 2020, (2): 21
3	Wu P P, Gao L X, Lyu Z P, et al. Research progress of carbon quantum dots in metal corrosion protection [J]. Corros. Prot., 2022, 43(11): 83
3	吴盼盼, 高立新, 吕战鹏等. 碳量子点在金属腐蚀防护中的研究进展 [J]. 腐蚀与防护, 2022, 43(11): 83
4	Zhang P, Zhu Q, Su Q, et al. Corrosion behavior of T2 copper in 3.5% sodium chloride solution treated by rotating electromagnetic field [J]. Trans. Nonferrous Met. Soc. China, 2016, 26: 1439
5	Zhang X, Wang Z H, Zhou Z H, et al. Impact of magnetic field on corrosion performance of Al-Mg alloy with different electrode potential phases [J]. Intermetallics, 2021, 129: 107037
6	Li J N, Zhang P, Guo B. Effects of rotating electromagnetic on flow corrosion of copper in seawater [J]. Trans. Nonferrous Met. Soc. China, 2011, 21: s489
7	Chiba A, Kawazu K, Nakano O, et al. The effects of magnetic fields on the corrosion of aluminum foil in sodium chloride solutions [J]. Corros. Sci., 1994, 36: 539
8	Ručinskien≐ A, Bikulčius G, Gudavičiūt≐ L, et al. Magnetic field effect on stainless steel corrosion in FeCl₃ solution [J]. Electrochem. Commun., 2002, 4: 86
9	Jiang X, Qiao J L, Lo I M C, et al. Enhanced paramagnetic Cu²⁺ ions removal by coupling a weak magnetic field with zero valent iron [J]. J. Hazard. Mater., 2015, 283: 880 doi: 10.1016/j.jhazmat.2014.10.044 pmid: 25464332
10	Li H J, Xiong Q, Lu Z P, et al. A magnetic field induced undulated surface and the shift of the active/passivation transition threshold of iron in a sulfuric acid solution [J]. Corros. Sci., 2017, 129: 179
11	Li P F, Chen Y B, Huang H W, et al. Investigation of corrosion behavior of galvanized steel as submarine cable armor in seawater under weak magnetic fields [J]. Int. J. Electrochem. Sci., 2023, 18: 100264
12	Yang Y, Zhang Q B, Zhu W C, et al. Effect of magnetic field on corrosion behavior of X52 pipeline steel in NaCl solution [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 501
12	杨永, 张庆保, 朱万成等. 磁场对NaCl溶液中X52管线钢腐蚀行为的影响 [J]. 中国腐蚀与防护学报, 2022, 42: 501
13	Tang Y C, Davenport A J. Magnetic field effects on the corrosion of artificial pit electrodes and pits in thin films [J]. J. Electrochem. Soc., 2007, 154: C362
14	Zheng B J, Li K J, Liu H F, et al. Effects of magnetic fields on microbiologically influenced corrosion of 304 stainless steel [J]. Ind. Eng. Chem. Res., 2014, 53: 48
15	Zhang L, Hu P H, Zhou Q, et al. Effects of pulsed magnetic field on microstructure, mechanical properties and bio-corrosion behavior of Mg-7Zn alloy [J]. Mater. Lett., 2017, 193: 224
16	Leventis N, Dass A. Demonstration of the elusive concentration-gradient paramagnetic force [J]. J. Am. Chem. Soc., 2005, 127: 4988 pmid: 15810811
17	Zhu C Y, Miao L Y, Xie J H, et al. Magnetic field effects on the corrosion behavior of magnetocaloric alloys LaFe_13.9Si_1.4under paramagnetic states [J]. J. Alloy. Compd., 2023, 968: 171901
18	Perov N S, Sheverdyaeva P M, Inoue M. Investigations of the magnetic field effect on electrochemical processes [J]. J. Magn. Magn. Mater., 2004, 272-276: 2448
19	Yuan B Y, Zhang J L, Gao G F, et al. Dynamic observation of the diffusion layer in anodic processes of the Fe/H₂SO₄ system with digital holography [J]. Electrochem. Commun., 2013, 27: 116
20	Ragsdale S R, Grant K M, White H S. Electrochemically generated magnetic forces. Enhanced transport of a paramagnetic redox species in large, nonuniform magnetic fields [J]. J. Am. Chem. Soc., 1998, 120: 13461
21	Aaboubi O, Chopart J P, Douglade J, et al. Magnetic field effects on mass transport [J]. J. Electrochem. Soc., 1990, 137: 1796
22	Li J X, Qin H J, Zhang W X, et al. Enhanced Cr(VI) removal by zero-valent iron coupled with weak magnetic field: role of magnetic gradient force [J]. Sep. Purif. Technol., 2017, 176: 40
23	Sueptitz R, Tschulik K, Uhlemann M, et al. Effect of magnetization state on the corrosion behaviour of NdFeB permanent magnets [J]. Corros. Sci., 2011, 53: 2843
24	Weier T, Eckert K, Mühlenhoff S, et al. Confinement of paramagnetic ions under magnetic field influence: lorentz versus concentration gradient force based explanations [J]. Electrochem. Commun., 2007, 9: 2479
25	Zhao S L. Magnetic field effects on the corrosion and stress corrosion cracking of Fe-Ga alloy [D]. Beijing: University of Science and Technology Beijing, 2021
25	赵素丽. 磁场作用下Fe-Ga合金腐蚀及应力腐蚀行为研究 [D]. 北京: 北京科技大学, 2021
26	Monzon L M A, Coey J M D. Magnetic fields in electrochemistry: the lorentz force. A mini-review [J]. Electrochem. Commun., 2014, 42: 38
27	Mühlenhoff S, Mutschke G, Koschichow D, et al. Lorentz-force-driven convection during copper magnetoelectrolysis in the presence of a supporting buoyancy force [J]. Electrochim. Acta, 2012, 69: 209
28	Sueptitz R, Tschulik K, Uhlemann M, et al. Magnetic field effects on the active dissolution of iron [J]. Electrochim. Acta, 2011, 56: 5866
29	Zhao S Z, Wang Y X, Zhao Y X, et al. The effect of magnetic field pretreatment on the corrosion behavior of carbon steel in static seawater [J]. RSC Adv., 2020, 10: 2060 doi: 10.1039/c9ra09079g pmid: 35494611
30	Sueptitz R, Tschulik K, Uhlemann M, et al. Retarding the corrosion of iron by inhomogeneous magnetic fields [J]. Mater. Corros., 2014, 65: 803
31	Zhao S L, You Z F, Zhang X W, et al. Magnetic field effects on the corrosion and electrochemical corrosion of Fe₈₃Ga₁₇ alloy [J]. Mater. Charact., 2021, 174: 110994
32	Lyu Z P, Huang D L, Yang W, et al. Effects of an applied magnetic field on the dissolution and passivation of iron in sulphuric acid [J]. Corros. Sci., 2003, 45: 2233
33	Sueptitz R, Koza J, Uhlemann M, et al. Magnetic field effect on the anodic behaviour of a ferromagnetic electrode in acidic solutions [J]. Electrochim. Acta, 2009, 54: 2229
34	Pullins M D, Grant K M, White H S. Microscale confinement of paramagnetic molecules in magnetic field gradients surrounding ferromagnetic microelectrodes [J]. J. Phys. Chem., 2001, 105B: 8989
35	Grant K M, Hemmert J W, White H S. Magnetic focusing of redox molecules at ferromagnetic microelectrodes [J]. Electrochem. Commun., 1999, 1: 319
36	Li X J. Study of effects of magnetic field on electrodissolution of metallic materials by the digital holography [D]. Xuzhou: Jiangsu Normal University, 2017
36	李希娇. 基于数字全息术研究磁场作用下金属的阳极溶解过程 [D]. 徐州: 江苏师范大学, 2017
37	Xu N. Corrosion behavior of oilfield sewage pipelines under magnetic field [D]. Xi’an: Northwestern Polytechnical University, 2005
37	徐楠. 磁场作用下油田污水管线腐蚀行为的研究 [D]. 西安: 西北工业大学, 2005
38	Li T Y. Effect of magnetic field on the corrosion electrochemical behavior of dissimilar metals under different immersion states [D]. Qingdao: China University of Petroleum (East China), 2023
38	李同跃. 磁场对异种金属在不同浸没状态下的腐蚀电化学行为影响 [D]. 青岛: 中国石油大学(华东), 2023
39	Hinds G, Coey J M D, Lyons M E G. Magnetoelectrolysis of copper [J]. J. Appl. Phys., 1998, 83: 6447
40	Noninski V C. Magnetic field effect on copper electrodeposition in the Tafel potential region [J]. Electrochim. Acta, 1997, 42: 251
41	Wang C, Chen S H. Holographic microphotography study of periodic electrodissolution of iron in a magnetic field [J]. Electrochim. Acta, 1998, 43: 2225
42	Ren P Y, Li R X, Wu X. Corrosion behavior of copper materials in marine atmosphere under action of magnetic fiel [J]. Corros. Prot., 2019, 40: 419
42	任佩云, 李瑞雪, 吴旭. 磁场作用下铜材在海洋大气中的腐蚀行为 [J]. 腐蚀与防护, 2019, 40: 419
43	Lyu Z P, Huang D L, Yang W. Probing into the effects of a magnetic field on the electrode processes of iron in sulphuric acid solutions with dichromate based on the fundamental electrochemistry kinetics [J]. Corros. Sci., 2005, 47: 1471
44	Lyu Z P, Yang W. In situ monitoring the effects of a magnetic field on the open-circuit corrosion states of iron in acidic and neutral solutions [J]. Corros. Sci., 2008, 50: 510
45	Lu Z P, Shoji T, Yang W. Anomalous surface morphology of iron generated after anodic dissolution under magnetic fields [J]. Corros. Sci., 2010, 52: 2680
46	Li L, Wang W J, Wang C, et al. Effects of an applied magnetic field on the anodic dissolution of nickel in HNO₃+Cl^- solution [J]. Electrochem. Commun., 2009, 11: 2109
47	Wang X P, Zhao J J, Hu Y P, et al. Effects of the Lorentz force and the gradient magnetic force on the anodic dissolution of nickel in HNO₃+NaCl solution [J]. Electrochim. Acta, 2014, 117: 113
48	Yu X Y, Wang Z H, Lu Z H. Atmospheric corrosion behavior of copper under static magnetic field environment [J]. Mater. Lett., 2020, 266: 127472.
49	Busch K W, Busch M A, Parker D H, et al. Studies of a water treatment device that uses magnetic fields [J]. Corrosion, 1986, 42: 211
50	Ghabashy M A. Effect of magnetic field on the rate of steel corrosion in aqueous solutions [J]. Anti-Corros. Methods Mater., 1988, 35: 12
51	Huang L P, Zhang X, Xiong Y M, et al. Corrosion behavior of Al-3.0Mg- _x RE/Fe alloys under magnetic field of different intensities [J]. J. Chin. Soc. Corros. Prot., 2022, 42: 833
51	黄连鹏, 张欣, 熊伊铭等. 不同磁场强度下铝镁合金腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2022, 42: 833 doi: 10.11902/1005.4537.2021.247
52	Yang G H, Zhou Z H, Zhang X, et al. Influence of magnetic field on corrosion behavior of Al-Mg alloys with different Mg content [J]. J. Chin. Soc. Corros. Prot., 2021, 41: 633
52	杨光恒, 周泽华, 张欣等. 磁场作用下不同Mg含量Al-Mg合金腐蚀行为研究 [J]. 中国腐蚀与防护学报, 2021, 41: 633 doi: 10.11902/1005.4537.2020.236
53	Zhao S L, Bai J J, You Z F, et al. Effect of a magnetic field on stress corrosion cracking of Fe₈₃Ga₁₇ alloy [J]. Corros. Sci., 2020, 167: 108539
54	Sato A, Ogiwara H, Miwa T, et al. Influence of high magnetic field on the corrosion of carbon steel [J]. IEEE Trans. Appl. Supercond, 2002, 12: 997
55	Li Y J, An B, Wang Y G, et al. Severe corrosion behavior of Fe₇₈Si₉B₁₃ glassy alloy under magnetic field [J]. J. Non-Cryst. Solids, 2014, 392/393: 51
56	Hu J, Dong C F, Li X G, et al. Effects of applied magnetic field on corrosion of beryllium copper in NaCl solution [J]. J. Mater. Sci. Technol., 2010, 26(4): 355

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