污染海洋大气环境下不锈钢加速腐蚀试验环境谱评价及相关性

doi:10.11902/1005.4537.2024.098

中国腐蚀与防护学报

2025, Vol. 45

Issue (2): 449-459 CSTR: 32134.14.1005.4537.2024.098 DOI: 10.11902/1005.4537.2024.098

研究报告

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污染海洋大气环境下不锈钢加速腐蚀试验环境谱评价及相关性

缪浩¹, 尹程辉¹, 王洪伦², 高逸晖³, 陈俊航¹, 张昊¹, 李波¹, 吴俊升¹, 肖葵¹(

)

^1.北京科技大学新材料技术研究院北京 100083
^2.西昌卫星发射中心航天发射场可靠性技术重点实验室海口 571126
^3.中国电子科技集团公司第二十研究所西安 710068

Correlation of Laboratory Simulation Test and Field Exposure Test for Three Stainless Steels in Polluted Marine Atmosphere of Qingdao Coastal Area

MIAO Hao¹, YIN Chenghui¹, WANG Honglun², GAO Yihui³, CHEN Junhang¹, ZHANG Hao¹, LI Bo¹, WU Junsheng¹, XIAO Kui¹(

)

^1.Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China
^2.Key Laboratory of Space Launch Site Reliability Technology, Xichang Satellite Launch Center, Haikou 571126, China
^3.Twentieth Research Institute of China Electronics Technology Corporation, Xi'an 710068, China

引用本文:

缪浩, 尹程辉, 王洪伦, 高逸晖, 陈俊航, 张昊, 李波, 吴俊升, 肖葵. 污染海洋大气环境下不锈钢加速腐蚀试验环境谱评价及相关性[J]. 中国腐蚀与防护学报, 2025, 45(2): 449-459.
Hao MIAO, Chenghui YIN, Honglun WANG, Yihui GAO, Junhang CHEN, Hao ZHANG, Bo LI, Junsheng WU, Kui XIAO. Correlation of Laboratory Simulation Test and Field Exposure Test for Three Stainless Steels in Polluted Marine Atmosphere of Qingdao Coastal Area[J]. Journal of Chinese Society for Corrosion and protection, 2025, 45(2): 449-459.

全文: PDF(20103 KB) HTML

摘要:

依据污染海洋大气环境因素设计紫外+周浸的环境谱加速试验方法，开展了430、316L、2205不锈钢的腐蚀行为和相关性研究。采用失重法、X射线光电子能谱分析仪(XPS)、扫描电子显微镜(SEM)、腐蚀电化学等方法对模拟污染海洋大气环境谱加速试验不同周期下3种不锈钢的腐蚀行为进行了研究，采用灰色关联度分析法研究了室内加速试验与青岛污染海洋大气环境下室外暴露试验的相关性。结果表明：紫外+周浸试验480 h后，430不锈钢发生明显的腐蚀，316L不锈钢出现明显的点蚀，2205不锈钢没有明显的腐蚀现象。灰色关联度分析3种不锈钢与户外暴露试验结果具有较好的相关性，3种不锈钢在污染海洋大气环境下的腐蚀寿命预测模型分别为T₄₃₀ = 50.0114t^0.134351、T_316L = 66.32242t^0.52341和T₂₂₀₅ = 620.8745t^0.112522。

关键词 ：不锈钢, 环境谱评价, 污染海洋大气环境, 相关性, 腐蚀寿命

Abstract：

According to the acquired environmental factors of polluted Marine atmosphere at Qingdao coastal area, an environment spectrum composed of varying ultraviolet irradiation and weekly soaking was designed for laboratory accelerated test. Thereafter, the corrosion behavior of three stainless steels, 430, 316L and 2205 was studied in parallel via lab testing with the proposed spectrum, and further, the correlation of the acquired data was evaluated with the outdoor exposure test results at selected sites in polluted Marine atmospheric environment of Qingdao area. The tested steels were characterized by means of weightlessness method, X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), corrosion electrochemistry etc. The results show that after 480 h test of UV irradiation + weekly shocking, 430 stainless steel underwent obvious corrosion, 316L stainless steel showed obvious pitting corrosion, and 2205 stainless steel experienced no obvious corrosion. However, the gray correlation analysis reveals that the laboratory corrosion data for the three stainless steels 430, 316L and 2205 and showed relatively good correlation with those of outdoor exposure test. Accordingly, the following three formulas may be proposed: T₄₃₀ = 50.0114t^0.134351, T_316L = 66.32242t^0.52341 and T₂₂₀₅ = 620.8745t^0.112522, as the corrosion-life prediction model for the corrosion of three stainless steels 430, 316L and 2205 in Qingdao polluted Marine atmospheric environment respectively.

Key words： stainless steel environmental spectrum evaluation pollution of the ocean atmospheric environment correlation corrosion life

收稿日期: 2024-03-27 32134.14.1005.4537.2024.098

ZTFLH:

TG172.3

基金资助:国家重点研发计划(2017YFB0304602)

通讯作者: 肖葵，E-mail：xiaokui@ustb.edu.cn，研究方向为金属材料大气腐蚀行为与机理研究、材料服役环境损伤机理和环境腐蚀评价、电子材料环境损伤行为与防护工艺研究、金属材料微生物腐蚀行为与机理、材料环境腐蚀数据库设计与建设

Corresponding author: XIAO Kui, E-mail: xiaokui@ustb.edu.cn

作者简介: 缪浩，男，2001年生，硕士生

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表1 430、316L、2205不锈钢的化学成分 (mass fraction / %)

图1 模拟工业海洋环境的试验方法

图2 430、316L和2205不锈钢室内加速试验后的失重和拟合曲线

表2 430、316L和2205不锈钢室内加速试验后的拟合结果

图3 430、316L和2205不锈钢室内加速试验后的失重速率曲线

图4 430不锈钢试验不同时间后的表面腐蚀形貌

图5 430不锈钢试验不同时间后的SEM图

图6 316L不锈钢试验不同时间后的表面腐蚀形貌

图7 316L不锈钢试验不同时间后的SEM图

图8 2205不锈钢试验不同时间后的表面腐蚀形貌

图9 2205不锈钢试验不同时间后的SEM图

图10 试验428 h后的430、316L和2205不锈钢腐蚀产物的Fe2p分峰拟合图谱

图11 430、316L和2205不锈钢试验不同时间后的极化曲线

表3 430、316L和2205不锈钢极化曲线的拟合结果

表4 3种不锈钢户外暴露与紫外+周浸试验失重数据

表5 3种不锈钢户外暴露与紫外+周浸试验数据初值化处理结果

表6 3种不锈钢的绝对差序列

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