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中国腐蚀与防护学报  2014, Vol. 34 Issue (5): 410-418    DOI: 10.11092/1005.4537.2014.069
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铝颜料表面改性防腐技术的研究与发展
杜斌(), 周世生, 李敏, 马丽萍
西安理工大学印刷包装工程学院 西安 710048
Progress in Research and Development for Surface Modification of Aluminum Pigments and Related Techniques
DU Bin(), ZHOU Shisheng, LI Min, MA Liping
Faculty of Printing and Packaging Engineering, Xi'an University of Technology, Xi'an 710048, China
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摘要: 

结合国内外学者对铝颜料的改性手段和技术,概括了铝颜料表面改性中常用的多种无机材料和有机材料,介绍了铝颜料表面改性的主要方法,包括溶胶/凝胶法、原位聚合法、乳液聚合法、等离子聚合法和分散聚合法等,最后针对改性铝颜料的性能变化阐述了采用不同的改性材料和改性方法对铝颜料性能改善方面的影响,并指出了铝颜料表面防腐改性的未来研究趋势。
关键词 ： 铝颜料,  表面改性,  防腐,  性能    
Abstract：

A variety of inorganic and organic materials commonly used for surface modification of aluminum pigments was firstly summarized. While the main methods for surface modification of aluminum pigments, including sol-gel encapsulation, in-situ polymerization, emulsion polymerization, plasma polymerization and dispersion polymerization etc. were then introduced. The influence of materials and measures of surface modification on the performance of the modified aluminum pigments was also illustrated. Finally, the development trend in this field was prospected as well.
Key words： aluminum pigment    surface modification    corrosion protection    performance
    
ZTFLH:  TS852  
基金资助:陕西省"13115"科技创新工程项目(2009ZDGC-06)和西安理工大学优秀博士学位论文研究基金项目 (104-211103)资助
作者简介: null

杜斌，男，1983年生，博士生，研究方向防腐蚀及特种油墨
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杜斌
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引用本文:

杜斌, 周世生, 李敏, 马丽萍. 铝颜料表面改性防腐技术的研究与发展[J]. 中国腐蚀与防护学报, 2014, 34(5): 410-418.
Bin DU, Shisheng ZHOU, Min LI, Liping MA. Progress in Research and Development for Surface Modification of Aluminum Pigments and Related Techniques. Journal of Chinese Society for Corrosion and protection, 2014, 34(5): 410-418.

链接本文:

https://www.jcscp.org/CN/10.11092/1005.4537.2014.069      或      https://www.jcscp.org/CN/Y2014/V34/I5/410

Chemical name Molecular formula Abbreviation
Titanium isopropoxide C12H28O4Ti TIP
Tetraethyl orthosilicate C8H20O4Si TEOS
Tetra-n-propoxyzirconium C12H28O4Zr TPOZ
3-Glycidoxypropylt-
imethoxysilane 		C9H20O5Si GPTMS
Tetramethyl orthosilicate C4H12O4Si TMOS
γ-Methacryloxypropy-
ltrimethoxysilane 		C10H20O5Si MAPTS
3-Aminopropyltri
methoxysilane 		C6H17NO3Si APTMS
Methyl triethoxysilane C7H18O3Si MTES
γ-Mercaptopropyltrim-
ethoxysilane 		C6H16O3SiS MPTES
Vinyl trimethoxysilane C8H18O3Si VTMS
Methyl trimethoxysilane C4H12O3Si MTMS
Vinyl triacetoxysilane C8H12O6Si VTAS
Phenyl triethoxysilane C12H20O3Si PTMS
Bis-[3(triethoxysilyl)propyl]
tetrasulfide 		C18H42O6Si2S4 BTESTP
Diethoxydimethylsilane C6H16O2Si DEDMS
Bis [trimethoxysilylpropyl]
ethane 		C14H34O6Si2 BTSE
Bis-[trimethoxysilylpropyl]
amine 		C12H31NO6Si2 Bis-amino silane
表1  铝颜料表面改性防腐技术中常用的偶联剂
Organic-inorganic hybrid system Functional additive agent Substrate Reference
GPTMS, TEOS Copper [32]
GPTMS, TMOS 2-methyl piperidine AZ91D Mg-alloy [33]
BTES AA1050 Al-alloy [34]
TAP, TPOZ, GPTMS TMSP AZ31B Mg-alloy [35]
TEOS, GMA, MAPTS, EGDMA Ce(NO3)3·6H2O AA2024T3 Al-alloy [36]
GPTMS, TIP Ce(NO3)3, 8-hydroxyquinoline ZK30 Mg-alloy [37]
BTESPT AZ31 Mg-alloy [38]
MTEOS Mg(NO3)2 AA2024-T3 Al-alloy [39]
BTSE Cold rolled Al-sheets [40]
BTESPT WE54 Mg-alloy [41]
GPTMS, TEOS Zn(NO3)2 AZ91D Mg-alloy [42]
GPTMS, TEOS AZ91D Mg-alloy [43]
TMOS, DEDMS, ZTB Ce(NO3)3·6H2O AZ91 Mg-alloy [44]
GPTMS, TPOZ AA2024T3 Al-alloy [45]
TEOS Polyaniline AZ31 Mg-alloy [46]
BTSE ZE41 Mg-alloy [47]
MPTMS Copper plates [48]
Zr(OC4H9)4, ZrO(NO3)2 2-mercaptobenzothiazole, Ce(NO3)3 AA2024-T3 Al-alloy [49]
MPTMS Die-cast AZ91 Mg-alloy [50]
TES, TEOS Zirconium and cerium oxide nanoparticles AA-2024-T3 Al-alloy [51]
MTES Ce(NO3)3 AZ91 Mg-alloy [52]
GPTMS, TPOZ Thermally activated hydrotalcite AA2024-T3 Al-alloy [53]
Ce(NO3)3 AA2024,AA3105 Al-alloy and
AZ-91, AZ-31 Mg-alloy 		[54]
GPTMS POSS AA2024 Al-alloy [55]
GPTMS, TEOS, MTES, BPA Ce2(SO4)3 AA2024 Al-alloy [56]
GPTMS, TPOZ Dried and Calcined Red mud particles AA2024-T3 Al-alloy [57]
表2  金属防腐有机无机杂化体系一览表
图1  铝粉改性前后分散性对比[71]
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