<strong>MOFs</strong>作为防腐蚀材料的研究进展及展望

doi:10.11902/1005.4537.2025.287

中国腐蚀与防护学报

2026, Vol. 46

Issue (4): 971-988 CSTR: 32134.14.1005.4537.2025.287 DOI: 10.11902/1005.4537.2025.287

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MOFs作为防腐蚀材料的研究进展及展望

黄绘, 李树丽, 邓书端, 李向红(

)

西南林业大学材料与化学工程学院西南地区林业生物质资源高效利用国家林业和草原局重点实验室昆明 650224

Research Progress and Prospects of MOFs as Anti-corrosion Material

HUANG Hui, LI Shuli, DENG Shuduan, LI Xianghong(

)

Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

引用本文:

黄绘, 李树丽, 邓书端, 李向红. MOFs作为防腐蚀材料的研究进展及展望[J]. 中国腐蚀与防护学报, 2026, 46(4): 971-988.
Hui HUANG, Shuli LI, Shuduan DENG, Xianghong LI. Research Progress and Prospects of MOFs as Anti-corrosion Material[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(4): 971-988.

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摘要:

金属有机框架材料(MOFs)因其独特的结构和性能，近年来在防腐蚀领域的研究备受关注。然而，MOFs在实际应用中仍面临诸多问题，如稳定性不足、缓蚀机理不明确以及大规模制备困难等。本文综述了近年来MOFs作为防腐蚀材料的研究进展，重点探讨了其在不同环境下的缓蚀性能及制备方法，揭示了影响MOFs在防腐蚀领域使用的关键因素，包括其孔径、表面化学性质以及金属节点的选择等。最后展望了MOFs作为防腐蚀材料在未来的研究方向，为其后续研究提供有益的参考与指引。

关键词 ：金属有机框架材料(MOFs), 金属腐蚀, 缓蚀剂, MOFs结构特性, MOFs合成技术

Abstract：

Metal-organic framework materials (MOFs) have attracted much attention in recent years because of their unique structure and properties for the field of corrosion protection. However, MOFs still face many problems in practical applications, such as insufficient stability, unclear corrosion inhibition mechanism, and difficulty in large-scale preparation. In this paper, the research progress of MOFs as anti-corrosion material in recent years is reviewed, focusing on their corrosion inhibition performance and preparation methods in different environments, and the key influencing factors related to MOFs in the field of corrosion prevention in the field of anti-corrosion are revealed, including their pore size, surface chemical properties and the selection of metal nodes. As anti-corrosion material, MOFs have shown broad application prospects in prolonging the service life of metallic materials, saving resource, reducing environmental pollution, and bringing significant economic and social benefits etc. Finally, the future research direction of MOFs as anti-corrosion material is prospected, which provides useful reference and guidance for the follow-up research.

Key words： MOFs Metal corrosion corrosion inhibitor structural characteristics of MOFs MOFs synthesis technology

收稿日期: 2025-09-11 32134.14.1005.4537.2025.287

ZTFLH:

TG174

基金资助:国家自然科学基金(52161016)

通讯作者: 李向红，E-mail：xianghong-li@163.com，研究方向为缓蚀剂

Corresponding author: LI Xianghong, E-mail: xianghong-li@163.com

作者简介: 黄绘，女，1995年生，博士生

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图1 MOFs的不同合成方法及时间[46]

图2 ZIF-67和ZIF-67@APS纳米材料合成过程[48], ZBT纳米材料合成过程[49], pH响应型HMSN-BTA@ZIF-8合成过程[50]和GO/MOFs纳米容器合成过程[51]的示意图

图3 UIO-66、NH2-UIO和NH2-UIO(GMA@NH2-UIO)Zr-MOF的合成[63]

图4 缓蚀剂掺入的MOF涂层(CTAB-HKUT-1)在铜表面电泳沉积，沉积在铜表面的涂层的表面形态及CTAB@HKUST-1涂层的防腐蚀机理[83]示意图

图5 Cu-MOF的阻抗图、SEM、AFM及机理图[116]

图6 GO@Ce-MOF材料的阻抗及防腐蚀机理[126]

图7 M-ZIF-8/GO防腐蚀机理[132]

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