扫描振动电极技术<strong>(SVET)</strong>在缓蚀剂研究中的应用

doi:10.11902/1005.4537.2025.277

中国腐蚀与防护学报

2026, Vol. 46

Issue (4): 989-1000 CSTR: 32134.14.1005.4537.2025.277 DOI: 10.11902/1005.4537.2025.277

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扫描振动电极技术(SVET)在缓蚀剂研究中的应用

黎敏, 魏高飞, 邓书端, 李向红(

)

西南林业大学材料与化学工程学院西南地区林业生物质资源高效利用国家林业和草原局重点实验室昆明 650224

Application of Scanning Vibration Electrode Technology (SVET) in Research of Corrosion Inhibitors

LI Min, WEI Gaofei, DENG Shuduan, LI Xianghong(

)

Key Laboratory of State Forestry and Grassland Administration on Highly-Efficient Utilization of Forestry Biomass Resources in Southwest China, College of Materials and Chemical Engineering, Southwest Forestry University, Kunming 650224, China

引用本文:

黎敏, 魏高飞, 邓书端, 李向红. 扫描振动电极技术(SVET)在缓蚀剂研究中的应用[J]. 中国腐蚀与防护学报, 2026, 46(4): 989-1000.
Min LI, Gaofei WEI, Shuduan DENG, Xianghong LI. Application of Scanning Vibration Electrode Technology (SVET) in Research of Corrosion Inhibitors[J]. Journal of Chinese Society for Corrosion and protection, 2026, 46(4): 989-1000.

全文: PDF(8610 KB) HTML

摘要:

聚焦于扫描振动电极技术(SVET)在缓蚀剂研究领域的应用，阐述了SVET的基本原理，梳理了SVET在缓蚀剂作用机制探究、性能评估及新型缓蚀剂开发等方面的应用进展。在作用机制探究方面，SVET能够实时监测缓蚀剂作用下金属表面的离子电流分布与变化，直观展现缓蚀剂对腐蚀电化学反应的抑制过程，为深入理解缓蚀机理提供关键数据支持。在性能评估方面，SVET可量化缓蚀效率，精准对比不同缓蚀剂效果。在新型缓蚀剂研发方面，SVET测试有助于筛选缓蚀剂有效成分、优化配方。并对SVET未来发展方向和应用前景进行了展望。

关键词 ：扫描振动电极技术, 缓蚀剂, 腐蚀防护, 应用进展

Abstract：

This paper focuses on the application of scanning vibration electrode technology (SVET) in the field of corrosion inhibitor research. The basic principle of SVET was expounded, and the progress of SVET application was summarized in aspects such as revealing the mechanism related with the action of corrosion inhibitors, assessing their performance and the developing of new corrosion inhibitors etc. In terms of exploring the mechanism of action, SVET can monitor in real time the ion current distribution and changes on the metal surface under the action of corrosion inhibitors, intuitively demonstrating the inhibition process of corrosion inhibitors on the electrochemical reaction of corrosion. Therefore, it can provide key data support for a deeper understanding of the corrosion inhibition mechanism. In terms of performance evaluation, SVET can quantify corrosion inhibition efficiency and precisely compare the effect of different corrosion inhibitors. In the research and development of new corrosion inhibitors, SVET testing is helpful for screening the effective components of corrosion inhibitors and optimizing their formula. In addition, this paper looks forward to the future development direction and application prospects of SVET, aiming to promote SVET to play a greater role in the research of corrosion inhibitors and further facilitate the innovative development of corrosion protection technologies.

Key words： scanning vibration electrode technology corrosion inhibitor corrosion protection application progress

收稿日期: 2025-09-06 32134.14.1005.4537.2025.277

ZTFLH:

TG174

基金资助:国家自然科学基金(52161016);云南省基础研究计划杰出青年基金(202001AV070008);云南省万人计划青年拔尖人才专项(51900109)

通讯作者: 李向红，E-mail：xianghong-li@163.com，研究方向为缓蚀剂

Corresponding author: LI Xianghong, E-mail: xianghong-li@163.com

作者简介: 黎敏，男，1989年生，博士生

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图1 SVET原理图[35]

图2 DMC-NL制备流程示意图，不同添加量DMC-NL对碳钢在盐酸溶液中浸泡1、2、4和6 h实时原位SVET图和DMC-NL在HCl溶液中对碳钢缓蚀机理示意图与缓蚀效率对比图[38]

图3 SLS制备流程图，SLS在1 mol·L-1 HCl中分散的SEM图及密度泛函化计算，碳钢在1 mol·L-1 HCl中不同浸泡时间后的电位差分布及SLS对Q235碳钢盐酸溶液中缓蚀机理示意图[43]

图4 高压氧腐蚀后α-Fe2O3涂层和(2) OV-Fe2O3涂层的外观与基板状态，以及对基板表面的表征结果

图5 在不含和含有磷酸盐的0.01 mol/L NaCl中浸泡不同时间后，离子电流密度(μA·cm-2)在切割边缘的分布[48]

图6 AA2024-T3、LDH-NO3和LDH-VOx的SVET图中最高阳极电流密度的分布图(最大峰值高度)以及图中的平均电流密度[50]

图7 纯铁暴露于0.1 mol/L NaCl下的离子电流图[54]

图8 GO-CeMOF-P/M复合材料制备示意图及SEM图像，引入划痕后EP和GO-CeMOF-P/M-EP涂层浸泡24 h的SVET电流密度图及盐雾结果[58]

图9 PEO-LDH(BTA)样品的SEM-EDX图、SVET图及腐蚀机制示意图[59]

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