海洋环境下<strong>TC4</strong>合金的电化学及磨损行为研究

doi:10.11902/1005.4537.2023.390

中国腐蚀与防护学报

2024, Vol. 44

Issue (5): 1243-1254 CSTR: 32134.14.1005.4537.2023.390 DOI: 10.11902/1005.4537.2023.390

研究报告

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海洋环境下TC4合金的电化学及磨损行为研究

冯少宇¹, 周兆辉¹, 杨兰兰¹(

), 乔岩欣¹, 王金龙², 王福会²

1 江苏科技大学材料科学与工程学院镇江 212003
2 东北大学材料科学与工程学院沈阳 110819

Electrochemical and Wear Behavior of TC4 Alloy in Marine Environment

FENG Shaoyu¹, ZHOU Zhaohui¹, YANG Lanlan¹(

), QIAO Yanxin¹, WANG Jinlong², WANG Fuhui²

1 School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China
2 School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China

引用本文:

冯少宇, 周兆辉, 杨兰兰, 乔岩欣, 王金龙, 王福会. 海洋环境下TC4合金的电化学及磨损行为研究[J]. 中国腐蚀与防护学报, 2024, 44(5): 1243-1254.
Shaoyu FENG, Zhaohui ZHOU, Lanlan YANG, Yanxin QIAO, Jinlong WANG, Fuhui WANG. Electrochemical and Wear Behavior of TC4 Alloy in Marine Environment[J]. Journal of Chinese Society for Corrosion and protection, 2024, 44(5): 1243-1254.

全文: PDF(9070 KB) HTML

摘要:

通过研究TC4合金在不同pH模拟海水中的电化学行为，表明合金在中性(pH = 7)模拟海水中耐蚀性能最好，在酸性(pH = 2)模拟海水中的耐蚀性能最差。通过研究TC4合金在模拟海水中的摩擦磨损行为，可见海水介质的存在会降低摩擦系数和减少磨损量，其磨损机理从空气介质中氧化磨损和磨粒磨损转变为腐蚀磨损和疲劳磨损。通过开展了TC4合金在模拟海水中磨损与电化学的交叉实验，表明在海洋介质和循环载荷的共同作用下，TC4合金的表面会同时发生钝化膜的破损与修复。钝化膜的破损剥落速率大于其生成速率，钝化膜失去保护作用，反而加速了合金腐蚀。但循环载荷消失后，合金在模拟海水中再次生成完整钝化膜。

关键词 ： TC4合金, 摩擦磨损, 电化学, 海洋环境

Abstract：

With the rapid development of utilization and exploitation of deep-sea resources, the demand of marine engineering structural materials with lightweight and corrosion-resistant becomes urgent. TC4 alloy has attracted widespread attention for its excellent strength and corrosion resistance in seawater. Herein, the electrochemical behavior and friction-wear performance of TC4 alloy in simulated seawaters with different pH value is studied. The alloy performs better in the neutral simulated seawater (pH = 7) rather than in the acidic ones (pH = 2). After examination of the friction and wear behavior of TC4 alloy in the simulated seawater, it is indicated that the presence of seawater is favorite the reduction of the friction coefficient and wear loss. The existence of the seawater made the wear mechanism changed from the oxidative- and abrasive-wear in air to the corrosive- and fatigue-wear. At the same time, through the experiments by the combination of electrochemical corrosion-wear loading in the simulated seawater, it follows that by the combined action of sea water and the cyclic wear load, the passivation film on the TC4 alloy surface may experience alternating damaging- and repairing-processes. When the damage speed of passivation film exceeds repair speed, its protective effect no longer exists, in other word, the damaged passivation film may accelerate the TC4 alloy corrosion. However, when the cyclic load is removed, the passivation film of TC4 alloy may completely be repaired in the simulated seawater.

Key words： TC4 alloy frictional wear electrochemistry marine environment

收稿日期: 2023-12-16 32134.14.1005.4537.2023.390

ZTFLH:

TG172.5

基金资助:国家自然科学基金(52001142);青年人才托举工程(2022QNRC001)

通讯作者: 杨兰兰，E-mail：lanlanyang@just.edu.cn，研究方向为金属腐蚀与防护

Corresponding author: YANG Lanlan, E-mail: lanlanyang@just.edu.cn

作者简介: 冯少宇，男，2000年生，硕士生

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https://www.jcscp.org/CN/10.11902/1005.4537.2023.390 或 https://www.jcscp.org/CN/Y2024/V44/I5/1243

图1 TC4合金在不同pH模拟海水中电化学阻抗谱图

表1 TC4合金在不同pH值模拟海水中电化学阻抗谱的拟合结果

图2 TC4合金在不同pH模拟海水中动电位极化曲线图

表2 TC4合金在不同pH模拟海水中动电位极化曲线参数

图3 TC4合金在不同pH模拟海水中动电位极化后的表面形貌图

图4 TC4合金在空气和模拟海水中的摩擦系数曲线图

图5 TC4合金在空气和模拟海水中的平均摩擦系数柱状图

图6 TC4合金在空气中磨痕截面曲线图和三维轮廓图

图7 TC4合金在模拟海水中磨痕截面曲线图和三维轮廓图

图8 TC4合金在不同介质中磨痕SEM形貌

图9 TC4合金在摩擦磨损过程中动电位极化曲线图

表3 不同载荷下动电位极化曲线参数

图10 TC4合金在静止-磨损交替实验中开路电位曲线图

图11 Ti-Cl--H2O体系的电位-pH图[44]

图12 TC4合金在空气和模拟海水中磨损量柱状图

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