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STRUCTURE AND CORROSION RESISTANCE OF ELECTROLESS PLATING Ni-P AND Ni-W-P COATINGS ON AZ91D MAGNESIUM ALLOY |
LI Duanyang1, SHEN Bo1, REN Yuping1, PEI Wenli1,YANG Zhongdong1, WANG Jijie2, QIN Gaowu1 |
1. College of Materials and Metallurgy, Northeastern University,Shenyang 110819
2. School of Materials Science and Engineering, Shenyang University of Aeronauitical and Astronautics, Shenyang 110136 |
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Abstract Ni-P and Ni-W-P coatings were prepared on AZ91D magnesium alloy by a direct electroless plating processing. The microstructure, phases and corrosion resistance of the prepared and post-annealed coatings were studied by using scanning electron microscopy, X-ray diffraction technique and electrochemical test. The results show that the Ni-P coating is of amorphous structure while the Ni-W-P coating is of nanocrystalline structure with a grain size of about 7 nm, and they have similar corrosion resistance against 3.5%NaCl aqueous solution. The corrosion potential of the Ni-W-P coating after annealing at 250℃ for 50 min positively shifts by 150 mV as compared to that of as-prepared Ni-W-P or Ni-P coating, implying the corrosion resistance of the annealed Ni-W-P coatings has been much improved.
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Received: 19 December 2008
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Corresponding Authors:
QIN Gaowu
E-mail: qingw@smm.neu.edu.cn
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[1] |
Song G L. The Corrosion and Protection of Mg Alloy[M]. Beijing:Chemical Industry Press, 2006,14-15 |
[2] |
(宋光玲. 镁合金腐蚀与防护[M].北京: 化学工业出 版社, 2006, 14-15) |
[3] |
Chen J L, Yu G, Hu B N. A zinc transition layer in electroless nickel plating [J]. Surf. Coat.Technol, 2006, 201:686-690 |
[4] |
Dwain M. A global review of magnesium parts in automobile [J]. Light Met. Age., 1996, 8: 60-65 |
[5] |
Song G L. Recent progress in corrosion and protection of magnesium alloys [J]. Adv. Eng. Mater, 2005, 7(7):563-586 |
[6] |
Zhou L L, Yi D Q, Deng S H, et al. A new environment-friendly anodizing process for magnesium alloys [J]. J. Chin. Soc. Corros. Prot., 2006,26(3): 176-179 |
[7] |
(周玲伶,易丹青,邓姝皓等. 镁合金环保型氧极氧化工艺研究[J]. 中国腐蚀与防护学报. 2006, 26(3): 176-179) |
[8] |
Li J Z, Shao Z C, Hao J J, et al. Two-steps electroless nickel plating of magnesium alloys [J]. J. Northeastern Univ., 2005, 26(3): 1-3 |
|
(李建中,邵忠财,郝建军等. “两步”法镁合金化学镀镍的研究 [J].东北大学学报, 2005, 26(3): 1-3) |
[9] |
Guo H F, An M Z. Electroplating and electroless plating on magnesium and its alloys [J]. Electroplat.Poll. Contr., 2004, 24(2):1-5 |
[10] |
(郭鸿飞,安茂忠.镁及镁合金电镀与化学镀[J].电镀与环保. 2004, 24(2): 1-5) |
[11] |
Umehara H, Takaya M,Terauchi S. Chrome-free surface treatment for magnesium alloy [J]. Surf. Coat. Technol, 2003, 169:666-669 |
[12] |
Zhao M, Wu S S,An P, et al. Investigation on chromium-free conversion coating on AZ91D magnesium alloy [J]. J. Chin. Soc. Corros. Prot., 2007, 27(1):17-22 |
|
赵明,吴树森,安萍等. AZ91D镁合金表面无铬转化 膜的研究[J]. 中国腐蚀与防护学报, 2007, 27(1):17-22 浏览 |
[13] |
Zhang Y C, Hu R N, Xiang R. The Handbook of Electroplate [M]. Beijing: National Defence Press, 2007, 547-548 |
[14] |
(张允诚,胡如南,向荣. 电镀手册[M]. 北京:国防工业出版社, 2007, 547-548) |
[15] |
Huo H W, Li Y, W F H. Electroless nickel plating on AZ91D magnesium alloy [J]. J. Chin. Soc. Corros.Prot., 2002, 22(1): 14-16 |
|
霍宏伟,李瑛,王福会. AZ91D镁合金化学镀镍 [J]. 中国腐蚀与防护学报, 2002, 22(1):14-16 浏览 |
[16] |
Balaraju J N, Jahan S M, Jain A. Structure and phase transformation behavior of electroless Ni-P alloys containing tin and tungsten [J]. J. Alloys Compd, 2007, 436:319-321 |
[17] |
Liu Z M, Gao W. Electroless nickel plating on AZ91 Mg alloy substrate [J]. Surf.Coat. Technol, 2006, 200:5087-5093 |
[18] |
Wu F B, Tian S K, Chen W Y. Microstructure evaluation and strengthening mechanism of Ni-P-W alloy coatings [J]. Surf. Coat. Technol, 2004, 177-178:312-314 |
[19] |
Tien S K, Duh J G, Chen Y I. Structure, thermal stability and mechanical properties of electroless Ni-P-W alloy coatings during cycle test [J]. Surf. Coat. Technol, 2004, 177-178:532-540 |
[20] |
Zhang W X, Huang N, He J G. Electroless deposition of Ni-W-P coating on AZ91D magnesium alloy [J]. Appl. Surf. Sci, 2007, 253(11):5116-5121 |
[21] |
Gao Y, Zheng Z J, Zhu M. Corrosion resistance of electroless deposited Ni-P and Ni-W-P alloys with various structures [J]. Mater. Sci. Eng., 2004, A381: 98-103 |
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