Please wait a minute...
J Chin Soc Corr Pro  2010, Vol. 30 Issue (3): 177-180    DOI:
Research Articles Current Issue | Archive | Adv Search |
STRUCTURE AND CORROSION RESISTANCE OF ELECTROLESS PLATING Ni-P AND Ni-W-P COATINGS ON AZ91D MAGNESIUM ALLOY
LI Duanyang1, SHEN Bo1, REN Yuping1, PEI Wenli1,YANG Zhongdong1, WANG Jijie2, QIN Gaowu1
1. College of Materials and Metallurgy, Northeastern University,Shenyang 110819
2. School of Materials Science and Engineering, Shenyang University of Aeronauitical and Astronautics, Shenyang 110136
Download:  PDF(795KB) 
Export:  BibTeX | EndNote (RIS)      
Abstract  

Ni-P and Ni-W-P coatings were prepared on AZ91D magnesium alloy by a direct electroless plating processing. The microstructure, phases and corrosion resistance of the prepared and post-annealed coatings were studied by using scanning electron microscopy, X-ray diffraction technique and electrochemical test. The results show that the Ni-P coating is of amorphous structure while the Ni-W-P coating is of nanocrystalline structure with a grain size of about 7 nm, and they have similar corrosion resistance against 3.5%NaCl aqueous solution. The corrosion potential of the Ni-W-P coating after annealing at 250℃ for 50 min positively shifts by 150 mV as compared to that of as-prepared Ni-W-P or Ni-P coating, implying the corrosion resistance of the annealed Ni-W-P coatings has been much improved.

Key words:  AZ91D magnesium alloy      Ni-P coating      Ni-W-P coating      corrosion resistance     
Received:  19 December 2008     
ZTFLH: 

TG174.36

 
Corresponding Authors:  QIN Gaowu     E-mail:  qingw@smm.neu.edu.cn

Cite this article: 

LI Duanyang, SHEN Bo, REN Yuping, PEI Wenli,YANG Zhongdong, WANG Jijie, QIN Gaowu. STRUCTURE AND CORROSION RESISTANCE OF ELECTROLESS PLATING Ni-P AND Ni-W-P COATINGS ON AZ91D MAGNESIUM ALLOY. J Chin Soc Corr Pro, 2010, 30(3): 177-180.

URL: 

https://www.jcscp.org/EN/     OR     https://www.jcscp.org/EN/Y2010/V30/I3/177

[1] Song G L. The Corrosion and Protection of Mg Alloy[M]. Beijing:Chemical Industry Press, 2006,14-15
[2] (宋光玲. 镁合金腐蚀与防护[M].北京: 化学工业出 版社, 2006, 14-15)
[3] Chen J L, Yu G, Hu B N. A zinc transition layer in electroless nickel plating [J]. Surf. Coat.Technol, 2006, 201:686-690
[4] Dwain M. A global review of magnesium parts in automobile [J]. Light Met. Age., 1996, 8: 60-65
[5] Song G L. Recent progress in corrosion and protection of magnesium alloys [J]. Adv. Eng. Mater, 2005, 7(7):563-586
[6] Zhou L L, Yi D Q, Deng S H, et al. A new environment-friendly anodizing process for magnesium alloys [J]. J. Chin. Soc. Corros. Prot., 2006,26(3): 176-179
[7] (周玲伶,易丹青,邓姝皓等. 镁合金环保型氧极氧化工艺研究[J]. 中国腐蚀与防护学报. 2006, 26(3): 176-179)
[8] Li J Z, Shao Z C, Hao J J, et al. Two-steps electroless nickel plating of magnesium alloys [J]. J. Northeastern Univ., 2005, 26(3): 1-3
  (李建中,邵忠财,郝建军等. “两步”法镁合金化学镀镍的研究 [J].东北大学学报, 2005, 26(3): 1-3)
[9] Guo H F, An M Z. Electroplating and electroless plating on magnesium and its alloys [J]. Electroplat.Poll. Contr., 2004, 24(2):1-5
[10] (郭鸿飞,安茂忠.镁及镁合金电镀与化学镀[J].电镀与环保. 2004, 24(2): 1-5)
[11] Umehara H, Takaya M,Terauchi S. Chrome-free surface treatment for magnesium alloy [J]. Surf. Coat. Technol, 2003, 169:666-669
[12] Zhao M, Wu S S,An P, et al. Investigation on chromium-free conversion coating on AZ91D magnesium alloy [J]. J. Chin. Soc. Corros. Prot., 2007, 27(1):17-22
  赵明,吴树森,安萍等. AZ91D镁合金表面无铬转化 膜的研究[J]. 中国腐蚀与防护学报, 2007, 27(1):17-22  浏览
[13] Zhang Y C, Hu R N, Xiang R. The Handbook of Electroplate [M]. Beijing: National Defence Press, 2007, 547-548
[14] (张允诚,胡如南,向荣. 电镀手册[M]. 北京:国防工业出版社, 2007, 547-548)
[15] Huo H W, Li Y, W F H. Electroless nickel plating on AZ91D magnesium alloy [J]. J. Chin. Soc. Corros.Prot., 2002, 22(1): 14-16
  霍宏伟,李瑛,王福会. AZ91D镁合金化学镀镍 [J]. 中国腐蚀与防护学报, 2002, 22(1):14-16  浏览
[16] Balaraju J N, Jahan S M, Jain A. Structure and phase transformation behavior of electroless Ni-P alloys containing tin and tungsten [J]. J. Alloys Compd, 2007, 436:319-321
[17] Liu Z M, Gao W. Electroless nickel plating on AZ91 Mg alloy substrate [J]. Surf.Coat. Technol, 2006, 200:5087-5093
[18] Wu F B, Tian S K, Chen W Y. Microstructure evaluation and strengthening mechanism of Ni-P-W alloy coatings [J]. Surf. Coat. Technol, 2004, 177-178:312-314
[19] Tien S K, Duh J G, Chen Y I. Structure, thermal stability and mechanical properties of electroless Ni-P-W alloy coatings during cycle test [J]. Surf. Coat. Technol, 2004, 177-178:532-540
[20] Zhang W X, Huang N, He J G. Electroless deposition of Ni-W-P coating on AZ91D magnesium alloy [J]. Appl. Surf. Sci, 2007, 253(11):5116-5121
[21] Gao Y, Zheng Z J, Zhu M. Corrosion resistance of electroless deposited Ni-P and Ni-W-P alloys with various structures [J]. Mater. Sci. Eng., 2004, A381: 98-103
[1] HAN Yuetong, ZHANG Pengchao, SHI Jiefu, LI Ting, SUN Juncai. Surface Modification of TA1 Bipolar Plate for Proton Exchange Membrane Fuel Cell[J]. 中国腐蚀与防护学报, 2021, 41(1): 125-130.
[2] SHI Kunyu, WU Weijin, ZHANG Yi, WAN Yi, YU Chuanhao. Electrochemical Properties of Nb Coating on TC4 Substrate in Simulated Body Solution[J]. 中国腐蚀与防护学报, 2021, 41(1): 71-79.
[3] BAO Ren, ZHOU Genshu, LI Hongwei. Preparation of High-tin Bronze Corrosion-resistant Coating by Potentiostatic Pulse Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(6): 585-591.
[4] LIU Haixia, HUANG Feng, YUAN Wei, HU Qian, LIU Jing. Corrosion Behavior of 690 MPa Grade High Strength Bainite Steel in a Simulated Rural Atmosphere[J]. 中国腐蚀与防护学报, 2020, 40(5): 416-424.
[5] LI Congwei, DU Shuangming, ZENG Zhilin, LIU Eryong, WANG Feihu, MA Fuliang. Effect of Current Density on Microstructure, Wear and Corrosion Resistance of Electrodeposited Ni-Co-B Coating[J]. 中国腐蚀与防护学报, 2020, 40(5): 439-447.
[6] CAO Jingyi, FANG Zhigang, CHEN Jinhui, CHEN Zhixiong, YIN Wenchang, YANG Yange, ZHANG Wei. Preparation and Properties of Micro-arc Oxide Film with Single Dense Layer on Surface of 5083 Aluminum Alloy[J]. 中国腐蚀与防护学报, 2020, 40(3): 251-258.
[7] WANG Le,YI Danqing,LIU Huiqun,JIANG Long,FENG Chun. Effect of Ru on Corrosion Behavior of Ti-6Al-4V Alloy and Its Mechanism[J]. 中国腐蚀与防护学报, 2020, 40(1): 25-30.
[8] SHI Chao,SHAO Yawei,XIONG Yi,LIU Guangming,YU Yuelong,YANG Zhiguang,XU Chuanqin. Influence of Silane Coupling Agent Modified Zinc Phosphate on Anticorrosion Property of Epoxy Coating[J]. 中国腐蚀与防护学报, 2020, 40(1): 38-44.
[9] WU Dongcai,HAN Peide. Effects of Moderate Temperature Aging Treatment on Corrosion Resistance of SAF2304 DuplexStainless Steel[J]. 中国腐蚀与防护学报, 2020, 40(1): 51-56.
[10] YANG Yinchu,FU Xiuqing,LIU Lin,MA Wenke,SHEN Moqi. Electrochemical Corrosion of Ni-P-BN(h)-Al2O3 Composite Coating Deposited by Spray Electrodeposition[J]. 中国腐蚀与防护学报, 2020, 40(1): 57-62.
[11] XIAO Jintao,CHEN Yan,XING Mingxiu,JU Pengfei,MENG Yingen,WANG Fang. Effect of Process Parameters on Corrosion Resistance of Anodizing Film on 2195 Al-Li Alloy[J]. 中国腐蚀与防护学报, 2019, 39(5): 431-438.
[12] SHI Kunyu,ZHANG Jinzhong,ZHANG Yi,WAN Yi. Preparation and Corrosion Resistance of Nb2N Coating on TC4 Ti-alloy[J]. 中国腐蚀与防护学报, 2019, 39(4): 313-318.
[13] SUN Xiaoguang,HAN Xiaohui,ZHANG Xingshuang,ZHANG Zhiyi,LI Gangqing,DONG Chaofang. Corrosion Resistance and Environmentally-friendly Chemical Passivation of Welded Joints for Ultra-low Carbon Austenitic Stainless Steel[J]. 中国腐蚀与防护学报, 2019, 39(4): 345-352.
[14] Duoyun CHENG,Jinbin ZHAO,Bo LIU,Cheng JIANG,Xiaoqian FU,Xuequn CHENG. Corrosion Behavior of High Nickel and Conventional Weathering Steels Exposed to a Harsh Marine Atmospheric Environment at Maldives[J]. 中国腐蚀与防护学报, 2019, 39(1): 29-35.
[15] Delin LAI,Gang KONG,Chunshan CHE. Effect of Sodium Silicate Sealing on Corrosion Resistance of TiO2Conversion Film on Hot-dip Galvanized[J]. 中国腐蚀与防护学报, 2018, 38(6): 607-614.
No Suggested Reading articles found!