Effect of Magnetic Field on Corrosion Behavior of L360 Pipeline Steel and Welded Joints in 3.5%NaCl Solution

doi:10.11902/1005.4537.2023.170

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (2): 471-479 DOI: 10.11902/1005.4537.2023.170

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Effect of Magnetic Field on Corrosion Behavior of L360 Pipeline Steel and Welded Joints in 3.5%NaCl Solution

DENG Zhibin¹^,², HU Xiao¹^,³, LIU Yingyan¹, YUE Hang⁴, ZHANG Qian¹, TANG Haiping¹^,², LU Rui³(

)

^1.College of Civil Aviation Safety Engineering, Civil Aviation Flight University of China, Guanghan 618307, China
^2.Civil Aircraft Fire Science and Safety Engineering Key Laboratory of Sichuan Province, Guanghan 618307, China
^3.Aviation Fuel Management Division, Civil Aviation Flight University of China, Guanghan 618307, China
^4.PetroChina Yunnan Marketing Company, Kunming 650000, China

Cite this article:

DENG Zhibin, HU Xiao, LIU Yingyan, YUE Hang, ZHANG Qian, TANG Haiping, LU Rui. Effect of Magnetic Field on Corrosion Behavior of L360 Pipeline Steel and Welded Joints in 3.5%NaCl Solution. Journal of Chinese Society for Corrosion and protection, 2024, 44(2): 471-479.

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Abstract

To clarify the influence of magnetic fields on the corrosion behavior of oil pipelines of L360 steel in service, the corrosion behavior of L360 pipeline steel and its welded joints in 3.5%NaCl solution by applied magnetic field of various intensities was studied via electrochemical tests and corrosion morphology characterization. The results indicate that as the magnetic field intensity increases, the charge transfer resistance of L360 pipeline steel and its welded joints initially increases and then decreases, while the corrosion current density initially decreases and then increases. Corrosion is inhibited by a lower intensity magnetic field (60 mT), while it is accelerated by a higher intensity magnetic field (120 mT). Moreover, by the same applied magnetic field intensity, the corrosion rate of the welded joints is higher than that of the base metal. It is proposed that the existed gradient magnetic field force may be favor the adsorption of metal ions at the electrode interface, resulting in the formation of a corrosion product film that hinders the corrosion process. Under the influence of a high-intensity magnetic field, the Lorentz force can disrupt the corrosion product film, accelerating ion diffusion and subsequently accelerating the corrosion of the steel.

Key words: magnetic field L360 pipeline steel welded joint 3.5%NaCl solution corrosion behavior

Received: 22 May 2023 32134.14.1005.4537.2023.170

ZTFLH:

TE988

Fund: Fundamental Research Funds for the Central Universities(J2020-124)

Corresponding Authors: LU Rui, E-mail: 95555846@qq.com

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	DENG Zhibin
	HU Xiao
	LIU Yingyan
	YUE Hang
	ZHANG Qian
	TANG Haiping
	LU Rui

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.170 OR https://www.jcscp.org/EN/Y2024/V44/I2/471

Fig.1 Experimental device diagram

Fig.2 Polarization curves of L360 pipeline steel in 3.5%NaCl solution under 0-120 mT magnetic fields: (a) BM, (b) WJS

Table 1 Fitting parameters of the polarization curves

Fig.3 Corrosion rates of BM and WJS for L360 pipeline steel in 3.5%NaCl solution under different magnetic fields

Fig.4 Nyquist (a, d), impedance module (b, e) and phase angle (c, f) plots of BM (a-c) and WJS (d-f) for L360 pipeline steel under different magnetic fields

Fig.5 Equivalent circuit diagram

Table 2 Fitting parameters of EIS

Fig.6 Macroscopic morphologies of BM (a-c) and WJS (d-f) samples after corrosion under magnetic fields of 0 mT (a, d), 60 mT (b, e) and 120 mT (c, f)

Fig.7 Macroscopic morphologies of BM (a-c) and WJS (d-f) for L360 pipeline steel after removal of corrosion products formed under different magnetic fields of 0 mT (a, d), 60 mT (b, e) and 120 mT (c, f)

Fig.8 Microscopic morphologies of BM (a-c) and WJS (d-f) for L360 pipeline steel after corrosion under magnetic fields of 0 mT (a, d), 60 mT (b, e) and 120 mT (c, f)

Fig.9 Microscopic morphologies of BM (a-c) and WJS (d-f) for L360 pipeline steel after removal of corrosion products formed under magnetic fields of 0 mT(a, d), 60 mT (b, e) and 120 mT (c, f)

Fig.10 EDS analysis results of corrosion product layers formed on BM (a-c) and WJS (d-f) under magnetic fields of 0 mT (a, d), 60 mT (b, e) and 120 mT (c, f)

Fig.11 XPS analysis results of corrosion products formed on BM (a) and WJS (b) under magnetic field of 120 mT

Table 3 EDS results of corrosion product films

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