Influence of Rolling on Corrosion Behavior of ZM5 Mg-alloy

doi:10.11902/1005.4537.2023.029

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 213-220 DOI: 10.11902/1005.4537.2023.029

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Influence of Rolling on Corrosion Behavior of ZM5 Mg-alloy

SONG Dongdong¹, WAN Hongxia²(

), XU Dong¹, ZHOU Qian¹

^1.Key Laboratory of Power Station Energy Transfer Conversion and System, Ministry of Education, North China Electric Power University, Beijing 102206, China
^2.School of New Energy and Materials, China University of Petroleum, Beijing 102249, China

Cite this article:

SONG Dongdong, WAN Hongxia, XU Dong, ZHOU Qian. Influence of Rolling on Corrosion Behavior of ZM5 Mg-alloy. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 213-220.

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Abstract

The corrosion performance and microstructure of ZM5 Mg-alloy before and after rolling were comparatively studied by hydrogen evolution measurement, mass loss method, electrochemical impedance spectroscopy (EIS), dynamic potential polarization measurement, XRD and SEM. The electron work function of different microstructures was numerically simulated through first principle analysis. The results show that rolling causes an obvious preferred orientation for ZM5 Mg-alloy. The corrosion mass loss and hydrogen evolution of ZM5 Mg-alloy decrease significantly after rolling, while the polarization resistance increases obviously. These all indicated that the corrosion resistance of the rolled ZM5 Mg-alloy is better than that of the cast one. The simulation results show that the rearrangement of α-phase enhances the electronic work function of the Mg-alloy.

Key words: Mg-alloy rolling corrosion behavior first-principles electron work function

Received: 10 February 2023 32134.14.1005.4537.2023.029

ZTFLH:

TG147

Fund: National Natural Science Foundation of China(51701055);National Natural Science Foundation of China(52101112);Fundamental Research Funds for the Central Universities(2023MS011)

Corresponding Authors: WAN Hongxia, E-mail: wanhongxia88@163.com

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	SONG Dongdong
	WAN Hongxia
	XU Dong
	ZHOU Qian

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.029 OR https://www.jcscp.org/EN/Y2024/V44/I1/213

Fig.1 Morphology of ZM5 Mg-alloy before (a) and after (b) the rolling process

Fig.2 XRD pattern of the cast and rolled ZM5 Mg-alloy

Fig.3 Mass loss (a, c) and the dependence of hydrogen evolution volume (b, d) of the cast (a, b) and rolled (c, d) ZM5 Mg- alloy during immersion in 3.5%NaCl solution

Fig.4 Polarization curves of ZM5 Mg-alloy before and after rolling in 3.5%NaCl solution

Table 1 Fitting data of polarization curves

Fig.5 Phase angle (a, d, g), impedance module (b, e, h) and Nyquist (c, f, i) plots of the cast and rolled ZM5 Mg-alloy during 0.5 h (a-c), 12 h (d-f) and 168 h (g-i) immersion time in 3.5%NaCl solution

Fig.6 Equivalent circuits of the cast and rolled alloy for different immersion periods

Fig.7 R_p of ZM5 Mg-alloy before and after rolling during various immersion time in 3.5%NaCl solution

Fig.8 The electrostatic energies and calculation models of the of ZM5 Mg-alloy before (a, c) and after rolling (b, d)

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