Effect of Rare Earth La on High Temperature Oxidation of Cobalt-based Superalloy GH5188 at 1100oC

doi:10.11902/1005.4537.2023.055

Journal of Chinese Society for Corrosion and protection

2024, Vol. 44

Issue (1): 221-228 DOI: 10.11902/1005.4537.2023.055

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Effect of Rare Earth La on High Temperature Oxidation of Cobalt-based Superalloy GH5188 at 1100^oC

WANG Shuang¹^,², WANG Zixing², CHENG Xiaonong¹(

), LUO Rui¹

^1.School of Materials Science and Engineering, Jiangsu University, Zhenjiang 212013, China
^2.Jiangsu Jicui Advanced Metal Materials Research Institute Co., Ltd., Suzhou 215500, China

Cite this article:

WANG Shuang, WANG Zixing, CHENG Xiaonong, LUO Rui. Effect of Rare Earth La on High Temperature Oxidation of Cobalt-based Superalloy GH5188 at 1100^oC. Journal of Chinese Society for Corrosion and protection, 2024, 44(1): 221-228.

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Abstract

The isothermal oxidation behavior of GH5188 superalloy at 1100^oC was studied by means of intermittent weighting, SEM and XRD. The results show that the main components of the formed oxide scale are Cr₂O₃ and MnCr₂O₄. The oxidation behavior can be approximated by parabolic law. The addition of La can help the alloy to form a continuous, compact and stable oxide scale of Cr₂O₃, improve the adhesion between the oxide scale and the alloy matrix, therewith enhance the high temperature oxidation resistance of GH5188 superalloy. However, with the increase of La content, the high temperature oxidation resistance of the alloy will decrease, the high temperature oxidation resistance of GH5188 alloy can be improved effectively only by adding proper amount of La (0.029%-0.060%).

Key words: cobalt base alloy GH5188 high temperature oxidation rare earth element

Received: 01 March 2023 32134.14.1005.4537.2023.055

ZTFLH:

TG132.3

Fund: State Key Lab of Advanced Metals and Materials(2022-Z21)

Corresponding Authors: CHENG Xiaonong, E-mail: Chengxiaonong@hotmail.com

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	WANG Shuang
	WANG Zixing
	CHENG Xiaonong
	LUO Rui

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https://www.jcscp.org/EN/10.11902/1005.4537.2023.055 OR https://www.jcscp.org/EN/Y2024/V44/I1/221

Table 1 Chemical compositions of GH5188 alloy samples with different contents of La

Fig.1 Oxidation kinetics curves of GH5188 alloy samples with different La contents at 1100^oC

Fig.2 ΔW vs. t^1/2 curves of 0# (a), 1# (b), 2# (c) and 3# (d) GH5188 alloy samples with different La contents

Table 2 Oxidation rate constants and fitting correlation coefficients of GH5188 alloy samples with different La contents

Fig.3 XRD patterns of four alloy samples with different La contents after oxidation at 1100^oC for 100 h

Fig.4 Macro morphologies of 0# (a), 1# (b), 2# (c) and 3# (d) alloy samples with different La contents after oxidation at 1100^oC for 100 h

Fig.5 Surface morphologies of 0# (a), 1# (b), 2# (c) and 3# (d) alloy samples with different La contents after 25 h oxidation at 1100^oC

Fig.6 Surface morphologies of 0# (a), 1# (b), 2# (c) and 3# (d) alloy samples with different La contents after 25 h oxidation at 1100^oC

Fig.7 Cross-sectional morphologies and of 0# (a), 1# (b), 2# (c) and 3# (d, e) alloy samples with different La contents after 100 h oxidation at 1100^oC

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