PHOTOELECTROCHEMICAL INVESTIGATION OF A.V.PASSIVE FILM ON 304 STAINLESS STEEL

J Chin Soc Corr Pro

2005, Vol. 25

Issue (4): 209-212 DOI:

Research Report

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PHOTOELECTROCHEMICAL INVESTIGATION OF A.V.PASSIVE FILM ON 304 STAINLESS STEEL

Licheng Yan;Junxi Zhang;Zengfu Wei;Jianqing Zhang

杭州师范学院

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Abstract A Photoelectrochemical investigation has been carried out on 304 stainless steel alternating voltage (A.V.) passive films in 005mol/L H3BO3+005mol/L Na2B4O7·10H2O solution.The dependences of photocurrent on the measuring potential (E) and the wavelength of incident light have been studied.Results show that the A.V.passive film is a highly disordered amorphous state.The photoelectrochemical behavior of passive film indicates that the passive film is p-type semiconductor.The relationship betweeniph and E is conformity with Poole-Frenkel effect in short potential range,while,it is complicated in the rest potential range owing to the changing of its composition with potential.

Key words: Photoelectrochemical A.V. Passivation Semiconducting Properties Passive Film Stainless Steel

Received: 14 October 2004

ZTFLH:

TG178

Corresponding Authors: Licheng Yan E-mail: yanlicheng@163.com

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Licheng Yan; Junxi Zhang; Zengfu Wei; Jianqing Zhang. PHOTOELECTROCHEMICAL INVESTIGATION OF A.V.PASSIVE FILM ON 304 STAINLESS STEEL. J Chin Soc Corr Pro, 2005, 25(4): 209-212 .

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https://www.jcscp.org/EN/ OR https://www.jcscp.org/EN/Y2005/V25/I4/209

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